Chenlu SONG
,
Wenjian WENG
,
Kui CHENG
,
Haibo QU
,
Piyi DU
,
Ge SHEN
,
Gaorong HAN
,
Juan YANG
,
Jose M.F.Ferreira
材料科学技术（英文）
Fluorapatite/hydroxyapatite solid solution has better biological properties than other apatites, especially used as films or coatings. In this work, sol-gel preparation and in vitro behavior of fluorapatite/hydroxyapatite solid solution films on titanium alloy were investigated. Ca(NO3)2·4H22O and PO(OH)x(OEt)3-x were selected as precursors, and hexafluorophosphoric acid (HPF6) was used as a fluorine containing reagent. The Ca and P precursors were mixed with HPF6 to keep the Ca/P molar ratio 1.67. The mixtures refluxed for 12 h were used as dipping sols for the preparation of the films. The phase of the films obtained at 600°C was apatite. The F contents in the films increased with the concentrations of HPF6 in the dipping sols. The solid solution films were shown to have better stability than hydroxyapatite films, and a reasonably good bioactivity in the in vitro evaluation.
关键词:
Fluorapatite/Hydroxyapatite
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