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Regularities of formation of ternary intermetallic compound between transition elements

Lixiu YAO , Jie YANG , Chenzhou YE , Nianyi CHEN

材料科学技术(英文)

Four parameters, phi (electronegativity), n(ws)(1/3) (valence electron density in Wagner-Seitz cell), R (Pauling's metallic radius) and Z (number of valence electrons in atom), and the pattern recognition methods were used to investigate the regularities of formation of ternary intermetallic compounds between three transition elements. The obtained mathematical model expressed by some inequalities can be used as a criterion of ternary compound formation in "unknown" phase diagrams of alloy systems.

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Regularities of formation of ternary intermetallic compounds between one transition element and two non-transition elements

Lixiu YAO , Nianyi CHEN , Jie YANG

材料科学技术(英文)

The pattern recognition methods and a four-parameter model, Eased on extension of Miedema's cellular model of alloy phases, are used to study the regularities of formation of ternary compounds between one transition element (T) and two non-transition elements (N, N') (T-N-N' system). The influences of phi (electronegativity), n(ws)(1/3)(valence electron density in Wagner-Seitz cell), R(Pauling's metallic radii) and Z (number of valence electrons in atom) on the formation of the ternary intermetallic compounds were investigated.

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