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MICROSTRUCTURE AND FORMATION MECHANISM OF LASER CLAD Ni60ACOATING

C.Z. Chen1 , 2) , T.Q. Lei2) , D.W. Cui1)and J.H. Yu1) 1) College of MaterialScience and Technology , Shandong University of Technology , Jinan 250061 , China2) College of MaterialScience and Technology , Harbin Institute of Technology , Harbin 150001 , China

金属学报(英文版)

The microstructure and formation mechanism of laser clad Ni60 Acoating were studied by meansof XRD, SEM, TEMand EDAXetc. Theresultsshow thatthe microstructureofthe coatingiscontrolled bytheratiooftemperature gradient Gand solidification speed υ( G/υ)atthesolid liquidinterface. Attheinterfaceof molten pool/substrate, G/υisquitelarge,and Ni basedsolid solutionsgrowingintheform oflow speed planar grain boundary form abonding belt. With the advancement of the solid liquid interface, G/υdecreases, and a bonding zone mainly composed ofcomplex cellulareutecticsof Ni+ M23( CB)6 and Ni+ Ni3Bisformed when G/υisstilllargeenough. Further decrease willlead to a clad layerthat exhibitscellular and dendritic Ni basedsolidsolutions,dendriticor discontinuousnetwork M7( CB)3 and complex eutectics( Ni+ M23( CB)6 and Ni+ Ni3 B) between them .

关键词: microstructure , null , null , null

EFFECT OF TH ETHICKNESS OF SPECIMENS ON THERMAL RESIDUAL STRESSES IN SiCw/Al COMPOSITES

Q. Y. Liu1 , 2) W. D. Fei2) and N. G. Liang1) 1) LNM , Institute of Mechanics , The Chinese Academy of Sciences , Beijing 100080 , China 2) Schoolof Materials Science and Engineering , Harbin Institute of Technology , Harbin 150001 , China

金属学报(英文版)

heinteracteach other among three kindsofthermalresidualstresses were analyzed firstly. Theresultsshown thatthe presenceof microstressandthermal mismatch stresshad noinflu enceon the measurement of macrostress, but macrostress can affect the measured value of thermal mismatch stress. Theeffectofthicknessofspecimen on thermalresidualstresses was discussed. Macrostresscan be neglected in thin specimen, thermal mismatch stressincreased with quenchingtemperatureincreasing, andobtainedtheir maximum valuesat400 ℃,then decreased . Forthethickspecimen, thecompressive macrostressatthesurfaceincreased with the quenching temperature increasing. The changing tendency of thermal mismatch stresswith quenchingtemperature wasquite differentcompared withthethinspecimens, which ob tainedtheir minimum valueat400℃.

关键词: thermalresidualstresses , null , null

BOND STRUCTURE OF HYDROGENATED DIAMOND LIKE CARBON FILMS DEPOSITED BY PLASMA BASED ION IMPLANTATION

G.Li , L.F.Xia , X.X.Ma , Y.Sun and Z.J.Zhan Schoolof Materials Science and Engineering , Harbin Institute of Technology , Harbin 150001 , China

金属学报(英文版)

The bondstructureofhydrogenated diamond likecarbon( DLC) filmsdeposited with plasmabased ionimplantation ( PBII) wascharacterized by Raman spectroscopy andcore level band and valenceband spectrum of XPS. Theresultsshow thatthe hydrogenated carbon filmspre pared with lower pulse bias, especially zero bias, display polymer like feature. The DLCfilms deposited with 15 kVpulsebiascontainsthehighestdensityofsp3 bonds. Thecore lev elband ( C1s) spectra of allfilmsshifttowardlow bindingenergy after4kVAr+ ion bom barding. The valenceband spectra of hydrogenated DLCfilmsarequite differentfrom thatof diamond and graphite. However, afterion bombarding, besidetwosingle peaksatabout17 0 eVand 12 5 eV(similarto graphite) ,two new sharp peaksappearatabout21 3 eVand 8 0 eV,respectively. Thepeak at8 0 eVcan beconsidertothecontribution duetothe actingofimplanted argon on C Cbondsand C Hbondsin thefilms.

关键词: hydrogenated DLCfilms , null , null , null , null

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