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CORROSION RESISTANCE OF HOT DIP GALVANIZED STEEL PRETREATED WITH BIS-FUNCTIONAL SILANES MODIFIED WITH NANOALUMINA

F.J. Shan , C.S. Liu , S.H. Wang , G.C. Qi

金属学报(英文版)

The corrosion behavior of hot dip galvanized steel pretreated with bis-[triethoxy-\linebreak\noindent silylpropyl] tetrasulfide (BTESPT) modified with alumina particles was studied. The corrosion resistance of the passiving films was evaluated by Tafel polarization curve and electrochemical impedance spectroscopy. The films formed on the galvanized steel substrate were characterized by Fourier transform infrared spectroscopy and energy dispersive X-ray spectrometry. The surface morphology of the treated hot dip galvanized steel samples was observed by Field Emission Scanning Electron Microscope. The results show that the pretreatments on the basis of silane films modified with nanoalumina particles have reduced both anodic and cathodic current densities, and increased total impedance in the measured frequency, consequently, improving corrosion protection for hot dip galvanized steel during immersion in NaCl solutions compared to chromate films and silane films.

关键词: Bis-sulfursilane , null , null , null , null

Amino-Tris-(Methylenephosphonic Acid) Layers Adsorption On Aa6061 Aluminum Alloy

S.H. Wang , C.S. Liu , F.J.Shan , G.C. Qi

金属学报(英文版)

The amino-tri-(methylenephosphonic acid) layers were adsorbed on the surface of AA6061 aluminum alloy for improving the lacquer adhesion and corrosion inhibition as a substitute for chromate coatings. The surface structure and characteristic of the amino-tri-(methylenephosphonic acid) layers on AA6061 aluminum alloy were investigated by means of XPS and ATR-FTIR analysis. The analyzed results showed that the amino-tri-(methylenephosphonic acid) adsorption layers adsorb on the surface of aluminium alloy $via$ acid-base interaction in a bi-dentate conformation. After the amino-tri-(methylenephosphonic acid) layers were coated with epoxy resin, the layers showed good adhesive strength and favorable corrosion resistance in contrast to chromate coatings.

关键词: Amino-tri-(methylenephosphonic acid)Layer , null , null , null

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