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Relationship between CO2 Sensor Voltage Response and Phase Equilibrium of Solid Electrolyte Na, K-β/β''-Al2O3

J.H.YANG , H.Nä , fe , F.Aldinger , D.S.YAN

材料科学技术(英文)

A type of CO2 sensor based on oxygen concentration cell was designed as following: Cell I: Pt | Au, O2, CO2| Na2CO3(Au)|NKBA(Au)|YSZ|O2, CO2|Pt or Cell II: Pt | Au, O2, CO2|K2$CO3(Au)|NKBA(Au)|YSZ|O2, CO2|Pt. (Na, K-β/β''-Al2O3 is named by NKBA). The sensor signal is consistent with the Nernstian slope within the region of phase equilibrium for Na, K-β/β''-Al2O3 material. The relationship between CO2 sensor voltage response and phase equilibrium of solid electrolyte Na, K-β/β''-Al2O3 is discussed in this paper.

关键词: CO2 sensor , null , null , null , null

Enthalpy of Mixing of Liquid Al-Cr and Cr-Ni Alloys

P.Saltykov , V.T.Witusiewicz , I.Arpshofen , H.J.Seifert , F.Aldinger

材料科学技术(英文)

The partial and the integral enthalpies of mixing of liquid Al-Cr and Ni-Cr binary alloys have been determined by high temperature isoperibolic calorimetry at 1723± 5 K and 1729±5 K, respectively. The results were analytically described by the thermodynamically adapted power series (TAPS). The enthalpies of mixing values for both binary liquid melts are small and negative and in good agreement with the available literature data. Minima of the mixing enthalpies of liquid Al-Cr and Ni-Cr alloys are -7.0 kJ.mol-1 at 46 at. pct Cr and -3.0 kJ. mol-1 at 37 at. pct Cr, respectively.

关键词: Al-Cr , null , null , null , null

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