Xinguo ZHAO
,
Zhidong ZHANG
,
Zhijun GUO
,
Wei LIU
,
Dianyu GENG
,
Baozhi CUI
材料科学技术（英文）
The alloy with nominal composition Sm-2(Fe0.94Ti0.06)(l7) is prepared by are-melting, hydrogenation and nitrogenation processes. The Sm-2(Fe0.94Ti0.06)(17) alloy has a single phase of Sm-3(Fe, Ti)(29) with the Nd-3(Fe, Ti)(29)-type structure. The corresponding hydride phase with the same phase structure of the parent alloy was formed after a hydrogen decrepitation (HD) process at 300 degrees C. The hydrogenation at 800 degrees C mainly shows a HDDR process. The HD and nitrogenation at 500 degrees C result in increasing the Curie temperature of the alloy by 72 degrees C and by 158 degrees C due to lattice expansions, respectively. The anisotropic and isotropic Sm-3(Fe, Ti)(29)Ny magnets are obtained after HD, HDDR and the consequent nitrogenation, respectively. The optimum magnetic properties of Sm-3(Fe, Ti)(29)Ny powders achieved in the above two processes are: (i) B-r=0.82 T, H-i(c)=4.48 kA/cm, (BH)(max)=54.3 kJ/m(3), (ii) B-r=0.68 T, H-i(c)=8.14 kA/cm, (BH)(max)=66.4 kJ/m(3).
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Zhijun GUO
,
Zhidong ZHANG
,
Xinguo ZHAO
,
Bowen WANG
,
Dianyu GENG
材料科学技术（英文）
Structure and magnetostriction of Dy1-xPrxFe2 (0 less than or equal to x less than or equal to 0.5), Dy0.6Pr0.4(Fe1-yTy)(2) (0 less than or equal to y less than or equal to 0.6), and Tb1-zPrz(Fe0.4Co0.6)(2) (0 less than or equal to z less than or equal to 1.0) alloys (T=Co, Ni) have been investigated. It is found that the matrix of the alloys Dy1-xPrxFe2 is a single phase (Dy, Pr)Fe-2 with MgCu2-type structure and the second phase is (Dy, Pr)Fe-3 when x less than or equal to 0.2. The amount of (Dy, Pr)Fe-3 phase increases with increasing Pr content and becomes the main phase when x=0.4. The matrix of Dy1-xPrxFe2 is found to be the (Dy, Pr)(2)Fe-17 phase with Th2Zn17-type structure when x=0.5. It is found that the amount of the cubic Laves phase (Dy, Pr)(Fe, Co)(2) in the Dy0.6Pr0.4(Fe1-yCoy)(2) increases with increasing Co concentration when 0 less than or equal to y less than or equal to 0.6. The substitution of Ni for Fe is nearly not favorable for the formation of the cubic Laves phase (Dy, Pr)(Fe, Ni)(2) in (Dy1-xPrx)Fe-2. The matrix of (Tb1-zPrz)(Fe0.4Co0.6)(2) is a (Tb, Pr)(Fe, Co)(2) phase with the MgCu2-type cubic Laves structure and a second phase of small amount is (Tb, Pr)(Fe, Co)(3) phase when z less than or equal to 0.2, z=0.5 and 1.0. When 0.2
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