B. Yang
,
YQ. Wang
,
J. Zhang and B.L. Zhou (Institute of Metal Research
,
Chinese Academy of Sciellces
,
Shenyang 110015
,
China Nanchang University
,
Nanchang 330029
,
China International Center for Materials Physics
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
Some TiAl3 whiskers are found to be produced simultaneously during the formation process of TiB2 Particulates fabricated by in situ reaction in molten aluminum. The thec t of temperature of molten aluminum on the morphologies of the TiAl3 whiskers and the growth mechanism of the whiskers are studied in this paper. The results show that the aspect rutio of the TiAl3 whiskers decreases with the increase of the temperoture. The growth of the whiskers is proved to be controlled by a Vapor-LiquidSoltd (VLS) mechanism. The titanium and aluminum atoms in the catalytic droplet,however, have been coofrmed to react with each othen which is dtherent from other whlskcrs growing by a VLS mcchanism where the compostion in the catalytic droplet is a constant.
关键词:
in situ reaction
,
null
,
null
,
null
Xiangcheng SUN
,
Feng YE
,
Xaoping SONG
,
Mngchuan YANG and Xiukui SUN (State Key Lab. for RSA
,
Institute of Metal Research
,
Chinese Academy of Sciellces
,
Shenyang 110015
,
China)
材料科学技术（英文）
Bulk AlN + Al nanocomposite materials were Synthesized by sintering the compacts of AlN and Al nanoparticles, which were produced by an active plasma-metal reaction method. The sudeces of as-prepared nanocomposite was investigated by X-ray photoelectron spectroscopy (XPS).Results show the surfaces are much degraded and the degradation products are alumina(Al2O3),boehmite(AIOOH), bayerite(AI(OH)3) layer. The mechanism of degradation behaviour in moist environment was also discussed
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