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THERMODYNAMIC PROPERTIES Cu-Ce-S AND Cu-Y-S LIQUID SOLUTIONS

LI Guodong , D U Ting , Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , China LI Guodong , Department No.16 , Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , 100081 , China

金属学报(英文版)

The thermodynamic properties of Cu-Ce-S and Cu-Y-S liquid solutions were studied by the chemical equilibrium technique at 1200℃. The equilibrium constants and the standard free energies of formation of CeS and YS were determined for the reactions: CeS=[Ce]+[S] and YS = [Y]+[S] . For the solution of Ce_(1) and Y_(l) in pure Cu according to the reactions: Ce_(1)= [Ce] and Y_(1)= [Y] , the standard free energies of solutions were obtained. The first order and second order interaction coefficients between solute elements as well as the activity coefficients γ_(Ce)~0 and γ_Y~0 in liquid Cu were also determined.

关键词: Cu-Ce-S system , null , null

PHASE DIAGRAM OF Nd-Fe-B TERNARY SYSTEM——Ⅱ.Two Vertical Sections with Constant Nd and B Respectively,Passing Through Nd_2Fe_(14) B Point

ZHANG Ning , Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , ChinaLUO Yang , San Huan New Material Research and Development Center , Academia Sinica , Beijing , China

金属学报(英文版)

According to the experimental data of phase transition taken from DTA, metallography, SEM and microzone composition, two vertical sections of the ternary phase diagram (B=5.88 at.-%, Nd≤45.41 at.-% andNd_2Fe_(14)BNd_(1.1)Fe_4B_4 , B≤44.56 at.-%) have been drawn in detail. It is verified that the crystallization of both Nd_2Fe_(14)B and Nd_(1.1)Fe_4B_4 phase, during cooling from melt, would take peritectic reaction instead of solid-liquid congruent precipita- tion.

关键词: Nd-Fe-B phase diagram , null

Investigation on the Recrystallization Behaviour of Cold Deformed MP159 Alloy

Guangwei HAN , Di FENG , Ming YIN , Wujun YE and Heli LUO(Dept. of Superalloys , Central Iron and Steel Research Institute , Beijing 100081 , China)

材料科学技术(英文)

The recrystallization behaviour of cold drawn MP159 alloy was investigated by optical and TEM examinations. It is found that the platelet ε phase in the MP alloy inhibits the recrystallization,and this effect makes the MP159 alloy with high recrystallization temperature of about 920℃.This inhibition mainly comes from the increasing of the interfacial energy, which results from the change of the coherent interfaces of (0001)hcp//(111)fcc into the incoherent interfaces when the recrystallizing grain fronts bypass the platelet ε martensite. The increasing of the interfacial energy also causes the dissolution of a few segments on the ε martensite platelets, which decreases the strength of the MP alloy

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THERMODYNAMIC PROPERTIES OF Fe-V-Ce LIQUID SOLUTION

CHANG Heming , DU Ting , YU Jingsheng , Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , China

金属学报(英文版)

Thermodynamic properties of the Fe-V-Ce liquid solutions have been studied in the tempera- ture range of 1550-1650℃. The temperature dependences of the equilibrium constants of re- action Ce_2O_2S = 2[Ce]+2[O]+[S] and the standard free energy of formation of Ce_2O_2S have been obtained. The temperature dependences of the interaction coefficients e_v~(Ce) and e_(Ce)~v have also been determined.

关键词: Fe-V-Ce system , null , null

Investigation on Cracking in the Surfacing Welding Layer of Ni_3Al Based Alloy

Guangwei HAN , Di FENG , and Wujun YE (Dept.5 , Central Iron and Steel Research Institute , Beijing , 100081 , China)(To whom correspondence should be addressed)

材料科学技术(英文)

Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stress within the surfacing welding layer. The results show that cracking in the surfacing welding layer is directly related to the producing of eutectic phase β' (NiAl) in the interdendritic region and high thermal stress within the surfacing welding layer. When the process of electric arc surfacing welding is changed from along straight line to along" Z" pattern, cracking in the surfacing welding layer of Ni3Al based alloy is prevented due to being reduced of both the cooling rate of liquid in the molten pool and the moving speed of the heat source. Reducing the melting volume of the substrate material by lowering the output power of electric arc welding would make the content of iron atoms in the molten pool decrease. and this also can reduce the trend of the eutectic reaction in the interdendfitic region and is helpful to Suppress cracking in the surfacing welding layer.

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Mechanical Model on Brittle Crack Initiation and Propagation

Guangwei HAN , Di FENG , Wujun YE and Heli LUO (Dept. of Superalloy , Central Iron and Steel Research Institute , Beijing 100081 , China)

材料科学技术(英文)

A mechanical model is presented in this paper to describe the initiating and propagating of brittle cracks. Two criteria have been deduced from the model to determine the effects of such factors as local stress state, surface and grain boundary energies as well as local grain boundary orientation on the initiating and propagating of both intergranular and transgranular brittle cracks. By which the role of adding B in Ni3Al base alloys to improve their ductility,temper and hydrogen embrittlements in steels and other alloys as well as the random feature of brittle crack initiation could be explained

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