W. H. Tian
,
S.L. Hu and M. Nemoto(Department of Materials Physics
,
University of Science and Technology Beijing
,
Beijing 100083
,
China)(Department of Materials Forming
,
University of Science and Technology Beijing
,
Beijing 100083
,
China)(Department of Materials Science and Engineering
,
Faculty of Engineering
,
Kyushu University
,
Fukuoka 812
,
Japan)
金属学报(英文版)
The Co3 Ti phase hardens appreciably by the fine precipitation of disordered fcc Co-rich phase upon aging after quenching from solution annealing temperature. Transmission electron microscope (TEM)observations revealed that the precipitates are platelet in shape, lying nearly parallel to the {100} planes of the L12-ordered matrix, and perfectly coherent with the matrix lattice at the beginning of aging. The high temperature strength increases appreciably with the fine precipitation of disondered Co-rich phase over the whole temperature range investigated. TEM observations of the deformed alloys after underaging revealed that saperdislocations are pinned by precipitates indicating an attractive interaction between dislocations and precipitates.
关键词:
Co_3 Ti
,
null
,
null
,
null
,
null
W.H. Tian
,
S.L. Hu and M. Nemoto(1) Department of Materials Physics
,
University of Science and Technology Beijing
,
Beijing 100083
,
China 2) Department of Materials Forming
,
University of Science and Technology Beijing
,
Beijing 100083
,
China 3) Department of Materials Science and Engineering
,
Faculty of Engineering
,
Kyushu University
,
Fukuoka 812
,
Japan)Manuscript received in revised form 12 October 1998
金属学报(英文版)
The effect of Cr addition on the microstructures and mechanical properties of NiAl inermetallic alloys containing 4 to 8 mol% Cr has been characterized. It is shown that Cr is not only an efficient soild solution strengthener in NiAl, it is also an efficient precipitation Strengthener by fine dispersion of α-Cr particles. Transmission electron microscope observations have revealed that fine spherical particles of α-Cr appeared homogeneously in the NiAl matrix by aging at temperatures around 1073K after solution annealing at 1563K. The aging behavior was investigated by microhardness measurements and the temperature dependence of the yield stress of NiAl containing α-Cr particles was investigated by compression tests over the tempemture range from 298 to 1173K. NiAl alloys happened appreciably by the precipitation of α-Cr particles.Dislocations bypass the particles during deformation and typical Orowan loops were observed surrounding the α-Cr particles after deformation. Although the dispersion Of α-Cr particles increases the yield strength of NiAl at intermediate temperutre, the strength decreases appreciably at higher temperatures.
关键词:
NiAl
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null
,
null
,
null
,
null
L.Li 1)
,
Z. P.Wang. 2)
,
Z.K.Qu 1)
,
D.M.Jia 3) and Z.Jiang 4) 1) Mechanical Engineering College
,
Shenyang University
,
Shengyang 110044
,
China 2) Harbin Research Institute of Welding
,
Harbin 150080
,
China 3) Information Engineering Collage
,
Shenyang University
,
Shengyang 110044
,
China 4) Materials Engineering College
,
University of Science and Technology Beijing
,
Beijing 100083
,
China
金属学报(英文版)
A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent shortcoming and controversy. The interface bond strength obtained by the test method is completely the inherent property of the interface and depends only on coating material properties, spray conditions, and technique of depositing the coating. By extensive tests, it is shown that the test tesults are very tepeatable and reliable. Furthermore, from this test, the critical coating thickness under which the coating spall can not emerge is also obtained.
关键词:
coating
,
null
,
null
,
null
B.H Liu
,
Y Zhang
,
S.X. Ouyang
,
and H.C. Gu (Research Institute of Technical Chemical Physics
,
East China University of Science and Technology
,
Shanghai 200237
,
China)(Department of Materials Physics
,
University of Science and Technology Beijing
,
Beijing 100083
,
China)(State Key Laboratory for Synthesis and Processing of Advanced Materials
,
Wuhan University of Technology
,
Wuhan 430070
,
China)
金属学报(英文版)
Titanium nitride powder was synthesized by microwave carbothermal reduction of titanium oxide. The mechanism and thermal dynamics of the reaction process were studied. The results show that the microwave carbothermal reduction technology has unique advantages over the conventional reduction methods. It can not only lower the reaction temperature, shorten the synthesis cycle, but also refine the product particles,as well as improving the reactivity of the powder.
关键词:
TiN microwave
,
null
Y.F. Gao
,
J.Tan
,
G.D. Liu
,
C.L.Zhang
,
T.Liuand R.Z Ma (Rapidly Quenched Materials Research and Development Centre
,
Central Iron & Steel Research Institute
,
Beijing 100081
,
China)(Metal Physics Department
,
University of Science and Technology Beijing
,
Beijing 100083
,
China)
金属学报(英文版)
A mostly single bcc phase with grain sizes of 15-20 nm was prepared by crystallization of amorphous Fe-P-C-Mo-Cu-Si alloys.The Bs value (H=10000 Oe) reaches 1.595 T for Fe(79.5) P(12)C6Cu(0.5)Mo(0.5)Si(1.5) alloys. The low core loss of 0.14 w/kg at 1.3 T and 50 Hz was confirmed for the bcc Fe(79.5)P(12)C6Cu(0.5)Mo(0.5)Si(1.5) alloy.The structures of the alloy annealed at different temperatures have been investigated by means of Xray diffraction and transmission electron microscope. The relationship between the structure and magnetic properties of the alloy is discussed.
关键词:
: amorphous alloy
,
null
,
null
L.F. Zhang
,
K.K. Cai
,
Y. Qu and Y.S. Shen Postdoctoral Fellow of Japan Science Promotion Society Taniguchi Lab.
,
Department of Metallurgy
,
Graduate School of Engineering
,
Tohoku University
,
Sendai980-8579
,
Japan School of Metallurgy
,
University of Science and Technology Beijing
,
Beijing 100083
,
China
金属学报(英文版)
In the present paper, based on the two-phase model (Eulerian model), the two dimensional fluid flow liz air-stirred water systems is simulated, and the effect of interphase lift force on the fluid flow is specially discussed. In the Eulerian two-phase model, gas and liquid phase are considered to be two different continuous fluids interacting with each other through the finite inter-phase areas. The exchange between the phases is represented by source terms in conversation equations. Turbulence is assumed to be a property of the liquid phase, k - ε model is used to describe the behavior of the liquid phase. The dispersion of phases due to turbulence is represented by introducing a diffusion term in mass consecrvation equation. The contribution of bubble movement to the turbulent energy and its dissipation rate is taken into accounted by adding extra volumetric source terms to the equations of turbulent enemy and its dissipation rate. The comparison between the mathematical simulation and experiment data indicates that the interphase lift force has a big effect on the flow behavior, and considering both drug force and lift force as interphase forces is important to accurately simulate the gas-water two-phase fluid flow in air-stirred systems. The interphase lift force makes bubbles move away from the centerline, the gas concentration is decreased near the centerline, and increased near the wall. The lift force is smaller than drug force at the same place, especially far away from the centerline.
关键词:
two-phase Eulerian model
,
null
,
null
,
null
Z. Bian
,
G. He and G.L. Chen (State Key Laboratory for Advanced Metals and Materials
,
University of Science and Technology Beijing
,
Beijing 100083
,
China) J. Lu
,
D.J. Chen
,
G.C. Tu
,
G.J. Chen and X.J. Hu (Shougang Metallurgical Research Institute
,
Beijing 100085
,
China)
金属学报(英文版)
Al80Ni6 Y8 Co4 Cu2 amorphous ribbons were isothermally annealed and a mixed structure consisting of α-Al particle with a size of less than 15nm and Al3Ni compound with a size of about 30nm was obtained. The crystallization kinetics of Al80Ni6 Y8 Co4 Cu2 amorphous alloy shows that the precipitation of α-Al particles is the growth process controlled by diffusion of the solute elements rejected from the growing crystals. By quenching at different cooling rates, a mixed structure consisting of nanoscale α-Al particles and the remaining glass matrix or structure consisting of nanoscale particle (Al phase or Al3Ni compound) with a size of about 100nm was formed. The addition of Co elements and Cu elements to Al-Ni-Y alloy systems increases the glass formation ability of the alloy and the thermal stability of the supercooled liquid region against crystallization, which results from significant difference of atomic size, strong bonding nature among constituent elements and the low diffisivity of the solute elements due to the concentration gradient in the growing front of crystals.
关键词:
a mixed structure
,
null
,
null
,
null
,
null
,
null
,
null
J.M Hu
,
J.X. Wu
,
H.M Meng
,
YR. Zhu
,
D.B. Sun and D.J. Yang(Beijing Corrosion and Protection Center
,
Open Laboratory of Corrosion
,
Erosion and Surface Technology
,
University of Science and Technology Beijing
,
Beijing 100083
,
China)
金属学报(英文版)
Titanium based IrO2 +Ta2O5 oxide anodes with different compositions and pyrolysis temperatures were prepared by termodecompoisition method. By using X-ray diffraction (XRD), the structure and texture coefficient of the coatings, TC(hkl), of IrO2 rutile crystal have been tested. It showed that, the crystallization processes of IrO2 and Ta2O5 in xIrO2 +(100-x) Ta2 O5 (x is in mol%) films affected and confined each other.In the mixed system, IrO2 rutile phase existed as a solid solution with Ta, and attained the maximum solubility when x=70mol%, i.e. for the coating of 70% IrO2 +Ta2O5.For the coatings of low iridium content or at low preparing tem pemture, (110) and (101) pwtered orientations were dominant. However, preferred growth of IrO2 weakened with increasing either iridium content or temperature. Three typical surface morphologies were observed by using scanning electron tnicroscopy(SEM). The crystallite size of the mixed oxide coatings were finest for the the film of 70%IrO2 +30%Ta2O5,and decreased with the pyrolysis tempemture. As the results of the finest crystallite segregating on sudece and the maxitnum solid solubility of Ir and Ta component in deposits, the coatings with the composition of 70%IrO2 +Ta2O5 prepared at 450℃ presented the mdrimutn electrocatalgtic activitg for O2 evolution in 0. 5M H2SO4 solution.UP to 550℃, Ti base suffered to oxidation resulting in decreasing anode conductivity,therefore, coatings performed a low activity.
关键词:
titanium based coating anode
,
null
,
null
,
null
,
null
,
null
T.H Xi
,
Z.X. Yuan and Z.S. Yu (Research Institute of Wuhan Iron & Steel (Group) Company
,
Wuhan 430080
,
China)(Department of Materials
,
Wuhan Yejin University of Science and Technology
,
Wuhan 430081
,
China)(Department of Materials Physics
,
Beijing University of Science and Technology
,
Beijing 100083
,
China)
金属学报(英文版)
The effect of Ce on the oxidation behaviour of undoped and B-doped Ni3 Al has been studied. Ce can refine Al2O3 grains produced in the course of oxidation of polycrystalline Ni3Al, accelerate the diffusion of oxygen along Al2O3 grain boundaries,and promote the growth of Al2O3 grains. As a result, the quantity of less-protective NiO decreases. The oxidation resistance of 0.011% Ce-doped alloy is the best of all Ce-doped Ni3Al alloys. Because B is benefitial to the formation of Al2O3 and Ce can refine Al2O3 grains, the oxidation resistance of the alloy containing both B and Ce is the best.
关键词:
Ni_3Al
,
null
,
null
Z. Li
,
Y.L. Yand
,
J.K Xi
,
J.X. Qu and H. S. Shao (Department of Materials Engineering
,
Luoyang institute of Technology
,
Luoyang 471039
,
China)(Beijing Graduate School
,
China University of Mining and Technology
,
Beijing 100083
,
China)
金属学报(英文版)
Annealing treatment has a strong effect on mechanical Properties of cold worked tungsten-nickel-iron heavy alloys. A 93W-4.5Ni-2.5Fe alloy swaged 15% was annealed from 500 to 1350℃ to investigate the changes in microstructure and their effects on mechanical properties. Recrystallization of W particles takes place during annealing treatments above 800℃ and the microhardnesses reduces rapidly. High density of dislocations in the, matrix phase after annealing treatment at 1350℃ suggests that recrystallization of the matrix phase has not taken place. A small decrease in microhardness of the matrix phase is caused by recovery during the annealing treatments.The changes in mechanical properties of swaged and annealed 93W-4.5 Ni-2.SFe alloy are mainly due to the changes in microstructure of W particles because of their recrystallization.
关键词:
: 93 W-4.5 Ni-2. 5 Fe alloy
,
null
,
null
