{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"用失重法、极化曲线法和热力学分析法研究了铝在<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>(<span style=\"color:red\">TCA</span>)中的行为,探讨了<span style=\"color:red\">TCA</span>的浓度和反应温度对铝腐蚀速率的影响,求得了动力学和热力学参数,测得腐蚀体系的极化曲线,并讨论了腐蚀电位和腐蚀电流密度等的变化.结果表明：铝在<span style=\"color:red\">TCA</span>中为匀速腐蚀,受活化控制；腐蚀速率同<span style=\"color:red\">TCA</span>浓度关系遵循Mathur经验式,腐蚀温度和速率符合Arrhenius公式；<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>对铝的腐蚀倾向和腐蚀程度可以同无机强酸相比。极化曲线测量表明铝表面无钝化层产生.铝的腐蚀电位与溶液pH值遵循线性关系,在<span style=\"color:red\">TCA</span>溶液中的腐蚀为阳极溶解控制.","authors":[{"authorName":"赵建国","id":"f7ff023b-d2d2-4234-8014-c84026ca7854","originalAuthorName":"赵建国"},{"authorName":"张云","id":"64ff0321-9073-47af-b8ab-22171148e6d0","originalAuthorName":"张云"}],"categoryName":"|","doi":"","fpage":"184","id":"60ff896a-c2c1-4e19-b0a6-1f2913bd0ea8","issue":"3","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"943499c3-69b9-4943-8632-8320cb9a2bcf","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>(<span style=\"color:red\">TCA</span>)","originalKeyword":"三氯乙酸(TCA)"},{"id":"af7ecaf8-c7cc-4846-b215-b9421869e810","keyword":"corrosion","originalKeyword":"corrosion"},{"id":"c0834010-6edc-4e95-a0ba-7f01b950a253","keyword":"kinetics","originalKeyword":"kinetics"},{"id":"0fd259c5-17c4-4d39-834e-b0799a3e5a34","keyword":"thermodynamics","originalKeyword":"thermodynamics"},{"id":"9b7aaae7-9c6e-41f1-b08b-0985b20e962c","keyword":"polarization curve","originalKeyword":"polarization curve"}],"language":"zh","publisherId":"1002-6495_2010_3_13","title":"金属铝在<span style=\"color:red\">TCA</span>溶液中的腐蚀","volume":"22","year":"2010"},{"abstractinfo":"用失重法、极化曲线法和热力学分析法研究了铝在<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>(<span style=\"color:red\">TCA</span>)中的行为,探讨了<span style=\"color:red\">TCA</span>的浓度和反应温度对铝腐蚀速率的影响,求得了动力学和热力学参数,测得腐蚀体系的极化曲线,并讨论了腐蚀电位和腐蚀电流密度等的变化.结果表明:铝在<span style=\"color:red\">TCA</span>中为匀速腐蚀,受活化控制;腐蚀速率同<span style=\"color:red\">TCA</span>浓度关系遵循Mathur经验式,腐蚀温度和速率符合Arrhenius公式;<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>对铝的腐蚀倾向和腐蚀程度可以同无机强酸相比.极化曲线测量表明铝表面无钝化层产生.铝的腐蚀电位与溶液pH值遵循线性关系,在<span style=\"color:red\">TCA</span>溶液中的腐蚀为阳极溶解控制.","authors":[{"authorName":"赵建国","id":"7c88e870-0d93-459d-bf14-a5223209d072","originalAuthorName":"赵建国"},{"authorName":"张云","id":"b837431e-e593-4b91-9c88-851f8b205dc6","originalAuthorName":"张云"}],"doi":"","fpage":"184","id":"31f14f82-d0f9-4147-89b7-6ada33df9d5b","issue":"3","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"8b2dd4ce-0854-4d94-bf3f-6edeb2cd8a39","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>(<span style=\"color:red\">TCA</span>)","originalKeyword":"三氯乙酸(TCA)"},{"id":"f6fb6fe2-3739-46ac-8d43-b60773c992e0","keyword":"腐蚀","originalKeyword":"腐蚀"},{"id":"284a5a3e-152a-4104-9810-3bed3fc57f73","keyword":"动力学","originalKeyword":"动力学"},{"id":"d6ba5a0a-dfb2-4be4-a81b-999335be253f","keyword":"热力学","originalKeyword":"热力学"},{"id":"1fac68ff-6be5-4d0d-b0eb-77ee4e197068","keyword":"极化曲线","originalKeyword":"极化曲线"}],"language":"zh","publisherId":"fskxyfhjs201003008","title":"金属铝在<span style=\"color:red\">TCA</span>溶液中的腐蚀","volume":"22","year":"2010"},{"abstractinfo":"采用失重法和极化曲线法对锌在<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>(<span style=\"color:red\">TCA</span>)中的腐蚀行为进行实验测定,探讨了<span style=\"color:red\">TCA</span>的浓度、反应温度对锌腐蚀速率的影响,导出了相应的动力学方程,求得反应的动力学参数和热力学参数,测算出锌的自腐蚀电位和腐蚀电流密度.结果表明:锌在<span style=\"color:red\">TCA</span>中为匀速腐蚀,受活化控制;腐蚀温度和速率的关系符合Arrhenius公式,腐蚀速率同<span style=\"color:red\">TCA</span>浓度关系遵循Mathur经验式;锌在<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>中的腐蚀为放热过程,其腐蚀倾向和程度可以同无机强酸相比,由极化曲线分析,阴极反应的活化能大于阳极反应的活化能,腐蚀为阴极控制.","authors":[{"authorName":"赵建国","id":"2a926277-340f-4ddf-b97f-10074dcce64b","originalAuthorName":"赵建国"},{"authorName":"梁作舟","id":"b8548719-9192-4dba-8e16-098d0104752a","originalAuthorName":"梁作舟"}],"doi":"","fpage":"641","id":"94e3498a-996c-47d1-b6f8-d71534eb7387","issue":"9","journal":{"abbrevTitle":"FSYFH","coverImgSrc":"journal/img/cover/FSYFH.jpg","id":"25","issnPpub":"1005-748X","publisherId":"FSYFH","title":"腐蚀与防护"},"keywords":[{"id":"7e629493-1b73-4bf6-b729-b5fd8c1078f3","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>","originalKeyword":"三氯乙酸"},{"id":"d698f8ad-52d0-439d-8578-d461a057b0df","keyword":"腐蚀","originalKeyword":"腐蚀"},{"id":"2512bcb9-53d3-4e79-bb70-3ecce403af09","keyword":"动力学","originalKeyword":"动力学"},{"id":"d5bc76de-4645-4d26-b502-35a14f278b95","keyword":"热力学","originalKeyword":"热力学"},{"id":"067f1960-c297-4c8a-b0e9-82e9f47c7639","keyword":"极化曲线","originalKeyword":"极化曲线"}],"language":"zh","publisherId":"fsyfh200909008","title":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>(<span style=\"color:red\">TCA</span>)中金属锌的腐蚀行为","volume":"30","year":"2009"},{"abstractinfo":"采用失重法、极化曲线法和动力学分析，研究了铝在<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>（<span style=\"color:red\">TCA</span>）中的腐蚀行为，分析了<span style=\"color:red\">TCA</span>的浓度和温度对铝腐蚀速率的影响，导出了相应的动力学方程，求得了有关的动力学参数，测算出腐蚀电流密度和腐蚀电位等电化学参数，探讨了铝在<span style=\"color:red\">TCA</span>中的阳极溶解机理和阴极析氢机理。结果表明，在研究浓度范围内，铝在<span style=\"color:red\">TCA</span>中为匀速腐蚀，受活化控制；腐蚀速率与<span style=\"color:red\">TCA</span>浓度的关系遵循Mathur经验式，腐蚀速率和温度的关系符合Arrhenius公式；阴极和阳极反应动力学方程在理论和试验上一致；极化曲线法和失重法结果相吻合，腐蚀过程中铝表面无钝化层产生。","authors":[{"authorName":"赵建国","id":"72da3f9f-017b-4763-9806-15e56ce9b974","originalAuthorName":"赵建国"},{"authorName":"鲍宇","id":"b890b4af-0faf-4706-9a74-7e66a648f878","originalAuthorName":"鲍宇"},{"authorName":"梁作舟","id":"95d1fd8c-5160-4128-9826-379afd93b93d","originalAuthorName":"梁作舟"}],"doi":"","fpage":"888","id":"80a383f4-4b1e-4372-a30b-cd8933b308df","issue":"11","journal":{"abbrevTitle":"FSYFH","coverImgSrc":"journal/img/cover/FSYFH.jpg","id":"25","issnPpub":"1005-748X","publisherId":"FSYFH","title":"腐蚀与防护"},"keywords":[{"id":"4265bcb3-d911-4a2a-8050-4bd75c760cf3","keyword":"<span style=\"color:red\">TCA</span>(<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>)","originalKeyword":"TCA(三氯乙酸)"},{"id":"0c6e8267-0180-4709-95cf-800541bce5cc","keyword":"腐蚀","originalKeyword":"腐蚀"},{"id":"8162e4fe-9325-4912-b82a-fc50ce3c8df5","keyword":"动力学","originalKeyword":"动力学"},{"id":"f79ea719-4892-4c66-b1f0-875f7688c658","keyword":"机理","originalKeyword":"机理"}],"language":"zh","publisherId":"fsyfh201111011","title":"铝在<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>介质中的腐蚀动力学","volume":"32","year":"2011"},{"abstractinfo":"制备了具有非线性光学特性的标题加合物,以蒸发法培养出无色透明的、晶形完整的单晶,该晶体在1064nm的Nd3+:YAG调Q脉冲激光束照射下,产生绿色的532nm的倍频光,其倍频光强度约是KDP的3～4倍.以X射线衍射法测定了1:1加合物的晶体结构,晶体学数据为:单斜晶系,Pc空间群,a=0.60457(16)nm,b=1.0940(3)nm,c=0.8667(2)nm,β=104.045(4)°,V=0.5561(3)nm3,Z=2,Mr=256.50,Dc=1.532g/cm3,μ=0.797mm-1,F(000)=260,R1=0.0540,wR2=0.1325.<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>与苯胺之间存在着质子的转移,二者通过分子间氢键相连接形成稳定的<span style=\"color:red\">三</span>维氢键网络结构.","authors":[{"authorName":"陈伟","id":"a777e399-5788-4d58-b1bd-a26661d5a05a","originalAuthorName":"陈伟"},{"authorName":"车云霞","id":"febded13-2839-4c84-b2cf-4a9a4334dc04","originalAuthorName":"车云霞"},{"authorName":"郑吉民","id":"37ef960c-f75c-461e-be54-63ac477c5cbb","originalAuthorName":"郑吉民"}],"doi":"10.3969/j.issn.1000-985X.2004.06.029","fpage":"1011","id":"f8286ef3-ab4c-4c3e-bbbe-c113d5918409","issue":"6","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"61a116c1-41c5-4876-84cc-789479be0f77","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>","originalKeyword":"三氯乙酸"},{"id":"a1245ea3-f69d-4ab4-9d76-a6034f21b37c","keyword":"苯胺","originalKeyword":"苯胺"},{"id":"acdc6bde-aef5-46f5-81ac-dc212e0803eb","keyword":"加合物","originalKeyword":"加合物"},{"id":"afc0eac2-7c77-48ac-bf34-dbbb674dff14","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"c57b0208-4115-4f3b-bb4d-9eb2c571ef65","keyword":"非线性光学","originalKeyword":"非线性光学"}],"language":"zh","publisherId":"rgjtxb98200406029","title":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>苯胺加合物的制备和晶体结构","volume":"33","year":"2004"},{"abstractinfo":"<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>与氧化双[<span style=\"color:red\">三</span>(2-甲基-2-苯基)丙基锡]反应,合成了新配合物<span style=\"color:red\">三</span>(2-甲基-2-苯基)丙基锡<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>酯(CCDC:932139),经元素分析、1H NMR和IR等技术手段表征其组成和结构,通过X射线衍射方法测定了化合物的晶体结构.该化合物晶体学参数:单斜晶系,空间群为P21/n,晶胞参数:a=1.1186(4) nm,b=1.8366(7) nm,c=1.6020(6) nm,α=90°,β=91.316(7)°,γ=90°,V=3.2902(19) nm3,Z=4,Dc=1.374 g/cm3,μ(MoKα)=1.046 mm-1,F(000)=1392,R1=0.0589,wR2 =0.1619;中心锡原子呈四配位畸变四面体构型.生物活性测试结果表明,标题配合物对5种肿瘤细胞株系HT-29、HepG-2、MCF-7、KB和A549均具有较好的体外抑制活性,并且具有选择性的抑菌活性.","authors":[{"authorName":"张志坚","id":"3d55114e-50e6-4eab-a4bf-5f6ced96e938","originalAuthorName":"张志坚"},{"authorName":"邝代治","id":"1c9fa633-25f2-46a2-81d6-a78c33742bad","originalAuthorName":"邝代治"},{"authorName":"张复兴","id":"1810c817-5303-43ec-9ee4-65c2c6fcd5c8","originalAuthorName":"张复兴"},{"authorName":"庾江喜","id":"7abcc36c-a3a8-4990-8ef6-6eac4c61fb7c","originalAuthorName":"庾江喜"},{"authorName":"蒋伍玖","id":"18dd4b2e-9ca8-498e-91f7-cd04d80ed643","originalAuthorName":"蒋伍玖"}],"doi":"10.3724/SP.J.1095.2014.30517","fpage":"1058","id":"6dfe1ce3-638b-40f5-a322-be92fb3ab07e","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"011ac2b2-08f5-49ce-9cac-c856faca064a","keyword":"有机锡羧酸酯","originalKeyword":"有机锡羧酸酯"},{"id":"1b875227-3226-42dd-b39c-c5527582ae32","keyword":"合成","originalKeyword":"合成"},{"id":"2fb9e2f2-792a-44bf-8a09-790a0bfce6ee","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"ae2e1215-3029-440d-a025-3c468b288c63","keyword":"体外抗癌活性","originalKeyword":"体外抗癌活性"},{"id":"1a127718-1a0f-420a-9791-7665fc5f86ad","keyword":"抑菌活性","originalKeyword":"抑菌活性"}],"language":"zh","publisherId":"yyhx201409009","title":"<span style=\"color:red\">三</span>(2-甲基-2-苯基)丙基锡(Ⅳ)<span style=\"color:red\">三</span><span style=\"color:red\">氯乙酸</span>酯的合成、结构和生物活性","volume":"31","year":"2014"},{"abstractinfo":"研究了<span style=\"color:red\">氯乙酸</span>/氢氧化钠缓冲体系在分光光度法测定稀土中的应用.以偶氮胂Ⅲ(0.5 g·L-1)为显色剂,比较了<span style=\"color:red\">氯乙酸</span>/氢氧化钠、甲酸/氢氧化钠、<span style=\"color:red\">乙酸</span>/<span style=\"color:red\">乙酸</span>纳缓冲体系灵敏度的差异,考察了pH值、偶氮胂Ⅲ对摩尔吸光系数的影响.并在<span style=\"color:red\">氯乙酸</span>/氢氧化钠体系下确定了测定单一稀土元素的最佳条件(缓冲溶液为<span style=\"color:red\">氯乙酸</span>/氢氧化钠,加入量为2 mL;显色剂为偶氮胂Ⅲ,加入量为2 mL),找到了测定每种稀土元素的最佳pH值.分光光度法与ICP-AES法测试基本吻合,可以简捷快速地测定稀土元素总量.","authors":[{"authorName":"张燕辉","id":"041172b6-c6f5-4e5a-a3b2-f781efcde35d","originalAuthorName":"张燕辉"},{"authorName":"杜若冰","id":"83b94634-fd83-411d-a547-7b770e807a24","originalAuthorName":"杜若冰"},{"authorName":"王振兴","id":"a6573117-00ee-4780-90b0-5132910e8985","originalAuthorName":"王振兴"},{"authorName":"陆人杰","id":"4f81a705-c97c-4615-b91a-0c70d57c720c","originalAuthorName":"陆人杰"},{"authorName":"毛婷婷","id":"7d2420e5-996f-4998-b4d5-8d6b97c3e0c2","originalAuthorName":"毛婷婷"},{"authorName":"肖吉昌","id":"9fb24146-66ec-4512-ac95-ac4ec25e22ef","originalAuthorName":"肖吉昌"}],"doi":"10.11785/S1000-4343.20130515","fpage":"636","id":"0b93637c-f178-4f32-97d9-de44c558ff43","issue":"5","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"17e69a9a-4407-47ce-8731-7b9916c1ac08","keyword":"<span style=\"color:red\">氯乙酸</span>","originalKeyword":"氯乙酸"},{"id":"57a8df49-1a96-4984-99e8-991fe06416b7","keyword":"分光光度法","originalKeyword":"分光光度法"},{"id":"c1415f34-c352-49e7-8389-25fe55d1b35b","keyword":"稀土","originalKeyword":"稀土"}],"language":"zh","publisherId":"zgxtxb201305015","title":"<span style=\"color:red\">氯乙酸</span>缓冲体系在稀土测定中的应用研究","volume":"31","year":"2013"},{"abstractinfo":"以固载杂多酸盐 TiSiW12O40/TiO2 为多相催化剂,通过<span style=\"color:red\">氯乙酸</span>和异戊醇反应合成了<span style=\"color:red\">氯乙酸</span>异戊酯,并探讨了TiSiW12O40/TiO2 对酯化反应的催化活性,较系统地研究了醇酸物质的量比、催化剂用量、反应时间诸因素对产率的影响.实验表明:TiSiW12O40/TiO2 具有良好的催化活性,醇酸物质的量比为 1.4∶1,催化剂用量为反应物料总量的 1.5%,反应时间 1.5 h,反应温度 98～126 ℃时,酯收率可达 92.78 %.\n","authors":[{"authorName":"杨水金","id":"1f21da61-ca1d-4061-a241-1a9e34688901","originalAuthorName":"杨水金"},{"authorName":"余协卿","id":"56b8bdcf-556a-4c77-b9e8-e53ae3dd4788","originalAuthorName":"余协卿"},{"authorName":"梁永光","id":"c077b8ca-8650-485e-9e46-67d44ecaab28","originalAuthorName":"梁永光"},{"authorName":"朱贵军","id":"7df75608-bfbb-4592-8e58-53255c262666","originalAuthorName":"朱贵军"}],"doi":"10.3969/j.issn.0258-7076.2002.04.006","fpage":"262","id":"4c20fdd4-5f92-4bde-a3b9-d085e2144a68","issue":"4","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"a25be023-2f86-4f4d-86b9-12a5978c619f","keyword":"TiSiW12O40/TiO2","originalKeyword":"TiSiW12O40/TiO2"},{"id":"1fb69ce2-0b3c-4446-9267-24fd588db668","keyword":"<span style=\"color:red\">氯乙酸</span>异戊酯","originalKeyword":"氯乙酸异戊酯"},{"id":"da4c70c4-0f05-4956-a08d-a9e0ce81f77d","keyword":"催化","originalKeyword":"催化"},{"id":"dd7c4ef7-853b-41c4-afd4-a015cd642d6a","keyword":"酯化反应","originalKeyword":"酯化反应"}],"language":"zh","publisherId":"xyjs200204006","title":"TiSiW12O40/TiO2 催化合成<span style=\"color:red\">氯乙酸</span>异戊酯","volume":"26","year":"2002"},{"abstractinfo":"通过溶液静电纺丝的方法,将水溶性药物二<span style=\"color:red\">氯乙酸</span>钠(DCA)包裹入油溶性聚乳酸(PLA)中,制备出二<span style=\"color:red\">氯乙酸</span>钠电纺纤维毡.将其应用于宫颈癌的活体实验中,结果表明在为期19 d的治疗下,荷瘤小鼠的肿瘤抑制率达到94％,总体康复率达到38％.同时,DCA电纺纤维毡还极大地抑制了宫颈癌后期复发和转移的趋势,提高了荷瘤小鼠的生存质量,是一种安全且疗效确切的抗癌给药剂型.","authors":[{"authorName":"刘大兴","id":"8b3495b1-c247-497e-b4cf-b4aef4a6e39e","originalAuthorName":"刘大兴"},{"authorName":"王明哲","id":"cd8d66fc-e961-4892-a49c-8a3edbc675eb","originalAuthorName":"王明哲"},{"authorName":"景遐斌","id":"ebaef22c-36d2-4aa7-aa0b-ec0a96291bd3","originalAuthorName":"景遐斌"},{"authorName":"黄宇彬","id":"c41f7e32-1cb6-4c86-9a71-898a0da36d78","originalAuthorName":"黄宇彬"}],"doi":"10.3724/SP.J.1095.2014.30537","fpage":"763","id":"e074d01b-056d-4016-a238-5f19b637994a","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"71189500-e97b-4b7a-bfe0-d32e821849f2","keyword":"宫颈癌","originalKeyword":"宫颈癌"},{"id":"ca36fdb4-2f26-4e58-a151-428c38d3fba2","keyword":"二<span style=\"color:red\">氯乙酸</span>钠","originalKeyword":"二氯乙酸钠"},{"id":"79ad0d87-de8e-404b-a5ba-5836b6171a43","keyword":"静电纺丝","originalKeyword":"静电纺丝"},{"id":"8d32c4e8-75ad-4732-8eef-bdeaaa27f962","keyword":"生存质量","originalKeyword":"生存质量"}],"language":"zh","publisherId":"yyhx201407003","title":"二<span style=\"color:red\">氯乙酸</span>钠电纺纤维毡改善宫颈癌小鼠生存质量","volume":"31","year":"2014"},{"abstractinfo":"为了提高零价铁对氯代有机物还原脱氯的性能,采用还原沉淀法制备了纳米钯/铁双金属颗粒.利用X射线衍射(XRD)、X射线荧光光谱(XRF)、扫描电子显微镜(SEM)、透射电镜(TEM)、以及BET-N_2 比表面积法对纳米钯/铁双金属颗粒进行了表征.结果表明,制备的纳米钯/铁双金属颗粒中Fe主要以α-Fe~0 形式存在.纳米钯/铁双金属颗粒的直径约为30～50 nm,比表面积约51 m~2/g.纳米钯/铁双金属颗粒对一<span style=\"color:red\">氯乙酸</span>还原脱氯的脱氯率是还原铁粉和纳米铁粉对一<span style=\"color:red\">氯乙酸</span>还原脱氯的脱氯率的7.9倍和1.7倍.","authors":[{"authorName":"陈超","id":"fe0e096c-33b5-4920-aecc-fec92e4d5ab3","originalAuthorName":"陈超"},{"authorName":"王向宇","id":"9c52c008-313e-4078-a6b1-1beb29e02d85","originalAuthorName":"王向宇"},{"authorName":"常影","id":"ed1bd204-add2-40e0-ab81-eca257b5ec07","originalAuthorName":"常影"},{"authorName":"刘惠玲","id":"2498a59b-62a4-432a-8607-cfee18011bfe","originalAuthorName":"刘惠玲"}],"doi":"","fpage":"535","id":"ff44bad9-8a4d-4a82-a4d1-921566eea7d0","issue":"4","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"31f2efc2-2994-4910-8b30-bbc20b5f8b8c","keyword":"纳米钯/铁双金属颗粒","originalKeyword":"纳米钯/铁双金属颗粒"},{"id":"9400d6c4-d1fc-451c-9456-d39a31a3611c","keyword":"还原脱氯","originalKeyword":"还原脱氯"},{"id":"08b51173-cf98-4e62-a0a9-6ae3ed44cd10","keyword":"一<span style=\"color:red\">氯乙酸</span>","originalKeyword":"一氯乙酸"}],"language":"zh","publisherId":"clkxygy200904023","title":"纳米钯/铁双金属颗粒对一<span style=\"color:red\">氯乙酸</span>的脱氯","volume":"17","year":"2009"}],"totalpage":2414,"totalrecord":24137}