{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"为了揭示<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>分子为敏化剂的<span style=\"color:red\">染料</span>敏化太阳能电池(DSSCs)的物理机制,采用含时密度泛函理论(TDDFT)方法计算了<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span><span style=\"color:red\">染料</span>分子1、2、3的紫外-可见吸收光谱和能级结构.结果表明,在电子给体和电子受体不变的情况下,改变π桥结构将明显改变<span style=\"color:red\">染料</span>的光谱性质.分子3的紫外-可见吸收光谱比分子1、2的吸收光谱有明显的红移.分子2、3的摩尔吸光系数也明显高于分子1的摩尔吸光系数,因此具有更高的捕获太阳光的能力.计算结果还表明,有机<span style=\"color:red\">染料</span>的合成需要综合考虑<span style=\"color:red\">染料</span>的吸收光谱特性、<span style=\"color:red\">染料</span>能级与半导体电极电位及氧化还原电解液电位的匹配及电子注入等内在因素,从而提高DSSCs的能量转化效率.","authors":[{"authorName":"杨振清","id":"d872b258-1d51-4d63-8bbd-1b25b65119c5","originalAuthorName":"杨振清"},{"authorName":"郑文文","id":"1f691040-15db-4322-8d25-2af62d4a0b3b","originalAuthorName":"郑文文"},{"authorName":"王迪","id":"6a2a6140-b617-4431-8b70-84e5f49dc63a","originalAuthorName":"王迪"},{"authorName":"白晓慧","id":"3433d034-1ef7-4a06-8c12-f385bf5d4357","originalAuthorName":"白晓慧"},{"authorName":"邵长金","id":"89f515e7-4cfe-465f-a257-30953d50eadf","originalAuthorName":"邵长金"},{"authorName":"曹达鹏","id":"02086442-d828-40de-9f0b-3e1be16f8215","originalAuthorName":"曹达鹏"}],"doi":"10.11896/j.issn.1005-023X.2014.16.033","fpage":"139","id":"47a0c17e-6396-4a5b-9a31-96f9e1169280","issue":"16","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"64a4916a-802e-4ff7-9059-ec3d1ce58042","keyword":"密度泛函理论","originalKeyword":"密度泛函理论"},{"id":"4ffe91ff-b037-4a53-ac5e-2c9381528cc0","keyword":"含时密度泛函理论","originalKeyword":"含时密度泛函理论"},{"id":"9e35f5e7-ea16-4a7a-914a-d51ed0a9cd16","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span><span style=\"color:red\">染料</span>","originalKeyword":"三苯胺染料"},{"id":"3fa491d9-d991-493d-9b53-121902066c8c","keyword":"紫外-可见吸收光谱","originalKeyword":"紫外-可见吸收光谱"},{"id":"249f720d-eb2e-45d3-9a09-26b180fb96ed","keyword":"能级","originalKeyword":"能级"}],"language":"zh","publisherId":"cldb201416033","title":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>类<span style=\"color:red\">染料</span>用于<span style=\"color:red\">染料</span>敏化太阳能电池光敏剂的理论研究","volume":"28","year":"2014"},{"abstractinfo":"通过电子扫描显微镜、X射线粉末衍射、红外光谱等测试方法对盐酸和对甲苯磺酸掺杂的聚<span style=\"color:red\">苯胺</span>吸附剂进行了表征.结果表明,酸掺杂的聚<span style=\"color:red\">苯胺</span>吸附剂由粒径为100～300 nm的无定形聚<span style=\"color:red\">苯胺</span>颗粒组成.主要研究了酸掺杂的聚<span style=\"color:red\">苯胺</span>吸附剂对阴离子<span style=\"color:red\">染料</span>选择吸附的性能,以及对阴离子<span style=\"color:red\">染料</span>橙黄的最大吸附量.同时对吸附过程进行动力学模拟,发现其符合二级动力学模型,吸附等温曲线拟合结果显示,吸附剂的吸附过程符合Langmuir方程.","authors":[{"authorName":"尚盼","id":"53163494-b6ee-405d-97fc-37a425568132","originalAuthorName":"尚盼"},{"authorName":"贾永明","id":"1d72afba-2cd5-48c3-8697-836d83db4532","originalAuthorName":"贾永明"},{"authorName":"杨丽","id":"4e76158b-3f2f-4dcc-ab61-2d49bf643dab","originalAuthorName":"杨丽"},{"authorName":"黄毓捷","id":"9d1f6fe7-360e-4fee-bff0-be87c0f0251a","originalAuthorName":"黄毓捷"},{"authorName":"李健","id":"a93f1f39-4a37-4c70-bc5b-7ed71ca7e825","originalAuthorName":"李健"},{"authorName":"安宁","id":"2c0686c1-345f-4a30-badd-ad3053178641","originalAuthorName":"安宁"},{"authorName":"李佳佳","id":"bae81a65-f1fa-47b4-be67-5be11c5f58d6","originalAuthorName":"李佳佳"},{"authorName":"马国富","id":"87454418-0720-4181-86c0-2c97845a9976","originalAuthorName":"马国富"},{"authorName":"王其召","id":"0c162ecf-2fce-4236-a2fb-dfc463562c81","originalAuthorName":"王其召"}],"doi":"","fpage":"71","id":"cde82e8c-f8f6-49bc-8413-f3b81002883c","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"36ec7dbb-3d00-4876-8d78-64c92561c9d8","keyword":"聚<span style=\"color:red\">苯胺</span>","originalKeyword":"聚苯胺"},{"id":"94c3f7a1-d031-4b65-b9c2-a7c8b4a37ba2","keyword":"改性","originalKeyword":"改性"},{"id":"05628469-7188-4c6c-9d62-e140aecc858e","keyword":"阴离子<span style=\"color:red\">染料</span>","originalKeyword":"阴离子染料"},{"id":"c21d3152-f1d0-445a-8686-0b6dbf8a750b","keyword":"吸附","originalKeyword":"吸附"}],"language":"zh","publisherId":"cldb201304019","title":"酸掺杂聚<span style=\"color:red\">苯胺</span>的制备及对阴离子<span style=\"color:red\">染料</span>的选择吸附研究","volume":"27","year":"2013"},{"abstractinfo":"以氧化石墨烯为原料,通过其对酸性蓝74、亚甲基蓝和刚果红的吸附作用,制备<span style=\"color:red\">染料</span>修饰氧化石墨烯,然后采用原位化学聚合法制得3种<span style=\"color:red\">染料</span>修饰氧化石墨烯/聚<span style=\"color:red\">苯胺</span>纳米复合物,即酸性蓝修饰氧化石墨烯/聚<span style=\"color:red\">苯胺</span>(GAP),亚甲基蓝修饰氧化石墨烯/聚<span style=\"color:red\">苯胺</span>(GMP)和刚果红修饰氧化石墨烯/聚<span style=\"color:red\">苯胺</span>(GCP),并将它们作为超级电容器电极材料,研究其电化学性能.结果表明,GAP中聚<span style=\"color:red\">苯胺</span>为直径和长度分别为20～ 30 nm,100～150 nm的纳米棒,且没有团聚现象,而GMP和GCP中聚<span style=\"color:red\">苯胺</span>长度、直径尺寸更大,且部分团聚.当电流密度为0.5 A/g时,GAP、GMP和GCP的比电容分别为419 F/g,401 F/g和399 F/g,比纯聚<span style=\"color:red\">苯胺</span>(381 F/g)有明显提高,其中GAP在5 A/g大电流密度下仍然保持较高的比电容(360F/g).","authors":[{"authorName":"陈果","id":"d1f6c7b9-5889-4931-93e7-3559401e9443","originalAuthorName":"陈果"},{"authorName":"郑积烽","id":"2e69cbce-76ee-4059-b3a6-57083ea1df12","originalAuthorName":"郑积烽"},{"authorName":"吕秋丰","id":"f7b10c5f-b64d-4e3c-9fc4-9b3a8de740c6","originalAuthorName":"吕秋丰"}],"doi":"","fpage":"175","id":"b8f7715d-717b-4d37-a5b1-acbfb5da3672","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"5dce0431-52dc-4ca0-9896-97c0a32cc29c","keyword":"超级电容器","originalKeyword":"超级电容器"},{"id":"35b709b9-3a03-45ce-baa2-b38129d00587","keyword":"<span style=\"color:red\">染料</span>修饰氧化石墨烯","originalKeyword":"染料修饰氧化石墨烯"},{"id":"a77c1797-9c6b-4e98-952a-e54243f7095e","keyword":"聚<span style=\"color:red\">苯胺</span>","originalKeyword":"聚苯胺"},{"id":"ad03c4c9-e4f5-44c9-8295-db38eab1feea","keyword":"电极材料","originalKeyword":"电极材料"}],"language":"zh","publisherId":"gfzclkxygc201510033","title":"<span style=\"color:red\">染料</span>修饰氧化石墨烯/聚<span style=\"color:red\">苯胺</span>复合物的制备及性能","volume":"31","year":"2015"},{"abstractinfo":"对笔者合成的不同结构与性能的聚<span style=\"color:red\">苯胺</span>因电子或极子跃迁而引起的可见-近红外区的吸收特性进行了研究.详细讨论了掺杂聚<span style=\"color:red\">苯胺</span>分子构象对其光学吸收的影响.对该聚合物的<span style=\"color:red\">染料</span>增感作用研究发现,孔雀绿、酞菁铜和分散橙对于该聚合物均有增感作用,可较大幅度地提高其光吸收特性.","authors":[{"authorName":"封伟","id":"e75cc784-0b1f-4835-9e9d-3353a2c27509","originalAuthorName":"封伟"},{"authorName":"韦玮","id":"27d8351d-55b6-46c4-99e3-023d92631a54","originalAuthorName":"韦玮"},{"authorName":"王辉","id":"5bba9e48-da10-4c44-b1f7-07b46e3c60ec","originalAuthorName":"王辉"},{"authorName":"吴洪才","id":"be73231f-283e-4054-9be1-62bedc1edf18","originalAuthorName":"吴洪才"}],"doi":"","fpage":"85","id":"ac950a22-1c52-4257-99f8-b1247fb071d3","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7e21ed27-bfd9-4e00-9c5e-dba03e44d0cc","keyword":"光电导功能高分子","originalKeyword":"光电导功能高分子"},{"id":"4566fcf5-282c-44b5-ac98-5d9e13f69b3c","keyword":"有机<span style=\"color:red\">染料</span>","originalKeyword":"有机染料"},{"id":"a9de1924-3ed5-47a0-a79d-116be2eb7e65","keyword":"增感作用","originalKeyword":"增感作用"}],"language":"zh","publisherId":"gfzclkxygc200005023","title":"聚<span style=\"color:red\">苯胺</span>的光学吸收及其<span style=\"color:red\">染料</span>增感作用研究","volume":"16","year":"2000"},{"abstractinfo":"通过Ullmann反应合成了4-甲氧基<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>(MeO-TPA)和4,4'.二甲氧基<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>(DMeO-TPA)两种具有良好溶解性的甲氧基取代<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>,通过FFIR、'H NMR和元素分析等手段对其进行了表征,并采用循环伏安(CV)结合UV-Vis吸收光谱测试了其能级结构.以甲氧基取代<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>为电荷传输材料,TiOPc为电荷产生材料制备了双层光电导体,测试了其光敏性.结果表明MeO-TPA和DMeO-TPA具有较<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>(TPA)更为优良的空穴传输性能.","authors":[{"authorName":"徐清","id":"682b14aa-cdd0-4251-90d9-3ea085ad331c","originalAuthorName":"徐清"},{"authorName":"陈红征","id":"b673e094-aee2-4393-bfc5-d9dbe5e5e76e","originalAuthorName":"陈红征"},{"authorName":"施敏敏","id":"758381e3-43dc-4258-9d7d-e0c9e91295b2","originalAuthorName":"施敏敏"},{"authorName":"汪茫","id":"af96e53a-4f47-4f74-a2b0-55f175734216","originalAuthorName":"汪茫"}],"doi":"10.3969/j.issn.1673-2812.2007.02.007","fpage":"190","id":"65c4ad43-4bd1-4fd0-a424-8f4d54b94975","issue":"2","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"7a14bd1e-5a7b-4ce6-81f7-cc299bb6f07e","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>","originalKeyword":"三苯胺"},{"id":"5abe6e66-00fe-4083-8ab4-d5f5cbdbafc8","keyword":"甲氧基","originalKeyword":"甲氧基"},{"id":"fb9e238f-0583-471c-b0aa-2b8e46f99f96","keyword":"合成","originalKeyword":"合成"},{"id":"c5f22bb9-ef35-49cc-b8fa-b076f684b96d","keyword":"空穴传输材料","originalKeyword":"空穴传输材料"},{"id":"565cb91f-cf88-4fa8-82e3-6e4385b4701e","keyword":"有机光电导体","originalKeyword":"有机光电导体"}],"language":"zh","publisherId":"clkxygc200702007","title":"甲氧基取代<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>的合成及其性能研究","volume":"25","year":"2007"},{"abstractinfo":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>结构单元中,与氮原子相连的3个苯环具有较高的活性、结构多样性和易裁剪修饰的特性,因此通过在苯环适当的位置外接不同的识别基团,可得到一系列具有特定传感性能的<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>类荧光探针分子.系统总结了<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>衍生物在金属离子、阴离子和小分子检测中的研究进展,并对探针分子的设计思路、合成方法、应用范围等进行了详细的比较分析,同时对其未来的发展趋势进行了展望.","authors":[{"authorName":"杨杨","id":"82f20cc4-8742-40f5-bf83-6c5a1c4a2900","originalAuthorName":"杨杨"},{"authorName":"高超颖","id":"c74bb60c-bcc9-4879-823d-b140f374aa5e","originalAuthorName":"高超颖"},{"authorName":"许良","id":"08dc2b05-2388-4cbc-bc3f-305f461b7235","originalAuthorName":"许良"},{"authorName":"白锁柱","id":"2a84363e-5bbf-4ef7-bdd3-f07fa5db3372","originalAuthorName":"白锁柱"},{"authorName":"陈静","id":"1c70adcc-2818-43ef-91ac-9d84efd27a96","originalAuthorName":"陈静"}],"doi":"10.11896/j.issn.1005-023X.2014.15.011","fpage":"56","id":"934a2f25-a135-4c99-80a4-06d09cabf66b","issue":"15","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"b564f6cc-61a7-4e09-afa3-952035f2258b","keyword":"荧光探针","originalKeyword":"荧光探针"},{"id":"675c35b1-1cd8-4803-b8d1-3843115cf3c4","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>","originalKeyword":"三苯胺"},{"id":"91896fcb-8973-4f87-9186-90a62b6ff0bd","keyword":"选择性","originalKeyword":"选择性"},{"id":"35726a72-32c4-4946-9ae0-c000de5d1643","keyword":"灵敏度","originalKeyword":"灵敏度"},{"id":"ba74412d-1d7c-4155-ad4d-ebbd581d8eb0","keyword":"检测限","originalKeyword":"检测限"}],"language":"zh","publisherId":"cldb201415011","title":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>类荧光探针的研究进展","volume":"28","year":"2014"},{"abstractinfo":"通过钯盐催化的Suzuki偶联反应,将2,2′-二溴螺硅芴与<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>二硼酸共聚得<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>-螺硅芴聚合物. 其中2,2′-二溴螺硅芴是以邻二溴苯为原料,经2步偶联,硝化,还原,取代共5步反应制得;<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>二硼酸是以<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>为原料,经溴化,锂化,再与硼酸<span style=\"color:red\">三</span>甲酯反应制得. 单体和共聚物的结构经核磁共振氢谱、质谱、红外光谱测试技术确证. 凝胶渗透色谱法测得共聚物的分子量Mn=7 014,Mw=9 577,分散度1.36. 螺硅芴的引入提高了共聚物的溶解性和热稳定性. 共聚物的玻璃化转变温度(Tg)为158.22 ℃. 由循环伏安法测得的电化学性质表明,共聚物具有可逆的氧化过程和较低的离子势(-5.47 eV,与<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>接近).","authors":[{"authorName":"肖海波","id":"0a278f2a-dbe2-4b3e-8065-d985a85f8579","originalAuthorName":"肖海波"},{"authorName":"冷冰","id":"9964fc9a-4ab0-4216-a2ca-6a7f3aee2fc0","originalAuthorName":"冷冰"},{"authorName":"田禾","id":"9eca37a6-1963-4b22-81e1-09d5b3af3369","originalAuthorName":"田禾"}],"doi":"10.3969/j.issn.1000-0518.2006.02.006","fpage":"140","id":"2630651c-aa84-46db-bb1d-eccca2e804e2","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"7d224f3d-37a7-49c7-8a22-a490e9448fe1","keyword":"螺硅芴","originalKeyword":"螺硅芴"},{"id":"f46224e0-04d2-4187-91c5-5421b45481ff","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>","originalKeyword":"三苯胺"},{"id":"9f7c45e7-b357-48e2-8d17-6c0f95301b40","keyword":"共聚物","originalKeyword":"共聚物"},{"id":"02843218-be00-410b-bd3b-43f5afd0b0aa","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200602006","title":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>-螺硅芴共聚物的合成","volume":"23","year":"2006"},{"abstractinfo":"以钯催化反应得到的4,4'-二甲氧基<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>为原料,用BBr3/CH2Cl2脱去甲基,得到中间产物4,4 '-二羟基<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>;再以吡咯烷酮为溶剂,在无水碳酸钾的催化下,通过4,4'-二羟基<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>与双(四氟苯基)砜的亲核反应,合成<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>基聚醚醚砜(TPA-PEES)发光材料.其结构通过核磁氢谱、红外谱图、凝胶渗透色谱和X射线衍射(XRD)等方法进行表征,表征结果与目标产物相吻合且聚合物为无定型态,并具有较高的相对分子质量((M)w=3.12×104).利用差示扫描量热(DSC)、热重分析(TG)、紫外-可见光分度计和荧光光谱仪对其性能进行测试,测试结果表明,该聚合物具有较高的玻璃化转变温度(Tg＞ 200℃),良好的热稳定性(Td＞ 400℃).另外,所制备的聚合物在二甲基甲酰胺(DMF)中的UV-vis最大吸收波长为305 nm,最大荧光发射波长为426 nm和523 nm.","authors":[{"authorName":"孙海燕","id":"4aabaa8c-97cc-487b-9bb1-23203850ffb2","originalAuthorName":"孙海燕"},{"authorName":"孙尚飞","id":"e2a8c773-405c-4894-93e5-e823f06d82dd","originalAuthorName":"孙尚飞"},{"authorName":"常冠军","id":"75a366dc-44ab-49e7-82a2-38f74ee09d15","originalAuthorName":"常冠军"},{"authorName":"林润雄","id":"2963c35a-7136-4aff-a895-bbc7d5dd35ea","originalAuthorName":"林润雄"},{"authorName":"张林","id":"452846bc-8956-4976-b389-59f3d4d7fdea","originalAuthorName":"张林"}],"doi":"","fpage":"9","id":"e0322631-3ccc-4909-97c2-eb6856c1df22","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"9703cd56-cde6-486e-b2f5-0d7cb257ef19","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>","originalKeyword":"三苯胺"},{"id":"93ef1702-1674-4832-bab4-ac95a2f9610a","keyword":"亲核反应","originalKeyword":"亲核反应"},{"id":"f6b045bf-a9b3-4c68-8aaf-7514dc469f73","keyword":"聚醚醚砜","originalKeyword":"聚醚醚砜"},{"id":"ced22269-8c3a-4eb8-9256-868627878335","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gfzclkxygc201308003","title":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>基聚醚醚砜的合成与性能","volume":"29","year":"2013"},{"abstractinfo":"选择硫杂芴为π-中心、<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>为\"枝\",合成了新型硫杂芴-<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>树枝形分子-2,8-双-[4-<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>乙烯基-4',4\"-二(<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>乙烯基)]硫杂芴(简称STG2),进行了核磁共振谱和质谱表征.以硫芴-<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>树枝形分子(简称ST-G2)为发光层,制备了结构为ITO/TCTA/ST-G2/BCP/Mg:Ag的3层发光器件,测试了器件的电致发光性能.该器件在6V开启,12V电压下亮度和效率接近1000cd/m2和0.21m/W.","authors":[{"authorName":"周懋怡","id":"b965c390-7450-43b4-b82f-d63aadfb7c28","originalAuthorName":"周懋怡"},{"authorName":"王筱梅","id":"222ec548-7244-4496-a60e-81de2d099f7e","originalAuthorName":"王筱梅"},{"authorName":"蒋宛莉","id":"304cc041-562c-4714-b75f-892d058f0364","originalAuthorName":"蒋宛莉"},{"authorName":"王德强","id":"ddc3a566-1a5e-4df5-bf02-1e3e88936049","originalAuthorName":"王德强"}],"doi":"","fpage":"1420","id":"2a70dbb3-3453-4938-9ce2-82ef8ae7f322","issue":"9","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"93317a12-f146-47ed-b669-64cf2089080e","keyword":"有机电致发光","originalKeyword":"有机电致发光"},{"id":"17382354-4b2d-40a1-bd9c-a911d25cb035","keyword":"硫芴","originalKeyword":"硫芴"},{"id":"376c3a9d-b621-4a85-8e96-725a9b0dff2b","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>树枝形分子","originalKeyword":"三苯胺树枝形分子"}],"language":"zh","publisherId":"gncl200809003","title":"硫杂芴-<span style=\"color:red\">三</span><span style=\"color:red\">苯胺</span>树枝形分子的合成与电致发光特性研究","volume":"39","year":"2008"},{"abstractinfo":"以<span style=\"color:red\">三</span>聚茚基<span style=\"color:red\">三</span>芳胺为给电子单元,以绕单宁-3-乙酸为受电子单元,设计合成了2种<span style=\"color:red\">三</span>聚茚基<span style=\"color:red\">三</span>芳胺<span style=\"color:red\">染料</span>六乙基<span style=\"color:red\">三</span>聚茚胺饶丹宁乙酸( MXD8)和六乙基<span style=\"color:red\">三</span>聚茚胺环氧噻吩饶丹宁乙酸(MXD9).光学测试表明,该类<span style=\"color:red\">染料</span>光谱响应范围宽,摩尔吸光系数高.结合2种<span style=\"color:red\">染料</span>的紫外-可见光谱和循环伏安曲线,确定了<span style=\"color:red\">染料</span>的电子基态和激发态能级位置.结果表明,2种<span style=\"color:red\">染料</span>的能级位置符合<span style=\"color:red\">染料</span>敏化太阳能电池的要求.将它们用作<span style=\"color:red\">染料</span>敏化太阳能电池中的光敏化剂,在AM1.5-100×10-3 W/cm2的光强下,MXD8敏化电池的开路电压(Voc)为614mV,短路电流密度(Jsc)为5.76×10-3 A/cm2,填充因子(FF)为0.66,总光电转换效率为2.33％.尽管    MXD9引入3,4乙撑二氧噻吩作为共轭桥,其光电转换效率却较MXD8低(1.27％).阻抗测试表明,MXD9光电转换效率较低的原因主要是电子更容易复合.该结果表明,电子复合可能与分子共轭体系增大导致极化率增加有关.","authors":[{"authorName":"梁茂","id":"02cb8eaa-cd37-4e91-b531-af48195370ef","originalAuthorName":"梁茂"},{"authorName":"王旭达","id":"5146acff-8fb0-49aa-8e24-8bb1dff4a677","originalAuthorName":"王旭达"},{"authorName":"袁颖","id":"355ef49b-8beb-4087-919f-b3724fc9a6f8","originalAuthorName":"袁颖"},{"authorName":"孙喆","id":"65b85c92-9b50-44fb-81ed-473ecdf00850","originalAuthorName":"孙喆"},{"authorName":"薛松","id":"2aa71fcb-b082-4ae1-8cfb-b263f6fc15f1","originalAuthorName":"薛松"}],"doi":"10.3724/SP.J.1095.2011.00753","fpage":"1387","id":"7a6b966e-a7ef-4a02-a966-85189a287100","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"63065ba6-1aa2-4eb4-ab2d-d8b0cb2c12ff","keyword":"<span style=\"color:red\">染料</span>敏化太阳能电池","originalKeyword":"染料敏化太阳能电池"},{"id":"4911589d-f7c0-43b1-aa0d-9c9f01f63603","keyword":"有机<span style=\"color:red\">染料</span>","originalKeyword":"有机染料"},{"id":"da772877-35be-48e8-b567-93d477199de5","keyword":"光电转换效率","originalKeyword":"光电转换效率"},{"id":"6cec9823-49ca-447e-8fd8-ddeb54deed6f","keyword":"<span style=\"color:red\">三</span>聚茚","originalKeyword":"三聚茚"}],"language":"zh","publisherId":"yyhx201112008","title":"2种<span style=\"color:red\">三</span>聚茚基<span style=\"color:red\">三</span>芳胺<span style=\"color:red\">染料</span>的合成及其光伏性能","volume":"28","year":"2011"}],"totalpage":2456,"totalrecord":24558}