{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以Ln(NO3)3·6H2O[Ln=Ce(1),Nd(2)]、间苯二甲酸(m-H2bdc)为原料,用水-DMF溶剂热合成法合成了两个异质同构的新型三维孔洞稀土金属配位聚合物{ Ln2 (m-bdc)3(H2O)2}π[Ln=Ce(1),Nd(2)],晶体结构经X射线单晶衍射仪分析确定,两种配合物的晶系均为单斜晶系,P21/c空间群,配位聚合物1:a=1.35428(11) nm,b=1.45987(11) nm,c=1.67101(10) nm,β=127.750(4)°,V=2.6122(3)nm3,Z=4,Dc=2.056 g·cm-3.配位聚合物2:a=1.34364(3) nm,b=1.45406(3) nm,c=1.66669(5) nm,β=127.382(2)°,V=2.5875(11) nm3,Z=4,Dc=2.097 g·cm-3.对配位聚合物1和2进行了元素分析、热重、红外光谱等表征,同时对标题配位聚合物的热稳定性及动力学进行了分析.","authors":[{"authorName":"<span style=\"color:red\">解</span><span style=\"color:red\">凤</span><span style=\"color:red\">霞</span>","id":"009301c6-a7f2-4722-980f-ee5d39042d87","originalAuthorName":"解凤霞"},{"authorName":"张欣欣","id":"fe5f26cc-8d1a-4fcf-80da-64cbf48cb4c6","originalAuthorName":"张欣欣"},{"authorName":"张丹","id":"8b4522fc-9c57-47c9-ae46-bbe5dec76eab","originalAuthorName":"张丹"},{"authorName":"华敏","id":"06677c65-021a-4472-8be5-b4ba7b3e6319","originalAuthorName":"华敏"},{"authorName":"张逢星","id":"759c4c78-7683-4935-8700-c10f6a3bf2b8","originalAuthorName":"张逢星"}],"doi":"","fpage":"365","id":"033063a9-7e5b-484b-9f41-a191187c8eb4","issue":"2","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"bb3120cf-8998-473d-8487-063ff3c70417","keyword":"稀土","originalKeyword":"稀土"},{"id":"6220814b-774f-489d-b1dc-0e549f95b3fe","keyword":"羧酸","originalKeyword":"羧酸"},{"id":"641e5b06-4e21-4122-a0fe-55b56d6b9e4f","keyword":"配合物","originalKeyword":"配合物"},{"id":"af9d5654-401e-4f7e-853e-e4a22dc513bc","keyword":"水热合成","originalKeyword":"水热合成"}],"language":"zh","publisherId":"rgjtxb98201302033","title":"新型稀土配位聚合物{Ln2(m-bdc)3(H2O)2}n(Ln=Ce,Nd)的合成、结构和动力学分析","volume":"42","year":"2013"},{"abstractinfo":"以Tb(NOa)3·6H2O、吡啶-2,5-二甲酸(H2pydc)为原料,合成了一个新型中心对称的三维配位聚合物{ (H3O)[Tb(pydc)2]}n.经X射线单晶衍射、元素分析、红外光谱、热重分析,荧光光谱等对配合物的结构进行表征.在配位单元[Tb(pydc)2]-中,Td(Ⅲ)离子与吡啶-2,5-二甲酸配体上的N原子、O原子配位形成八配位的十二面体构型.相邻的两个Td(Ⅲ)离子通过吡啶-2,5-二甲酸的桥连作用形成三维网状结构.荧光光谱实验表明该化合物在546 nm处有强的荧光发射.另外对配合物的分解过程进行了动力学分析.","authors":[{"authorName":"<span style=\"color:red\">解</span><span style=\"color:red\">凤</span><span style=\"color:red\">霞</span>","id":"be128026-67b1-4aed-b707-7d659e823ae7","originalAuthorName":"解凤霞"},{"authorName":"张欣欣","id":"c2b63508-5b59-46c9-82e2-9cd81b089804","originalAuthorName":"张欣欣"},{"authorName":"张丹","id":"29d4575c-e1d8-40a4-ba79-e0a7719d9c7a","originalAuthorName":"张丹"},{"authorName":"华敏","id":"cc1e53ef-001e-42ce-8dae-a6d1cf8c43c0","originalAuthorName":"华敏"},{"authorName":"张逢星","id":"0d0a5224-7188-4a91-bdce-80f1bb59b58e","originalAuthorName":"张逢星"}],"doi":"","fpage":"2207","id":"21705991-9ca6-47eb-8a15-491789307e5c","issue":"10","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"ad6c4899-c299-48e5-a566-a982710dea1f","keyword":"稀土配合物","originalKeyword":"稀土配合物"},{"id":"545ef647-8e06-4f9c-be40-f715a66fa2ba","keyword":"吡啶-2,5-二甲酸","originalKeyword":"吡啶-2,5-二甲酸"},{"id":"18dc9d80-3b04-4dac-969b-e399dcc6b788","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"683ab862-9568-4c89-b7d7-32a60c5dd2f8","keyword":"动力学","originalKeyword":"动力学"}],"language":"zh","publisherId":"rgjtxb98201310044","title":"基于吡啶2,5二甲酸的铽配位聚合物合成、表征及动力学分析","volume":"42","year":"2013"},{"abstractinfo":"利用热分析技术研究了顺丁烯二酸酐在N2气气氛中不同升温速率条件下的热失重过程,得出失重过程的动力学方程和动力学参数.顺丁烯二酸酐在温度为110-160℃,质量损失率>98%.通过热重-红外联用技术得出热失重过程的气体产物为顺丁烯二酸酐气体,该失重过程的实质是顺丁烯二酸酐的升华过程.在质量损失率a为0.2～0.9范围内,用迭代的等转化率法求得失重过程的活化能为(75.147±0.48)KJ/mol.与Coats-Redfern方程计算出的Ea((75.064 5±1.239)kJ/mol)吻合.由此推出,顺丁烯二酸酐的失重过程可以用单一的机理函数来描述,排除了存在多个分解反应步骤相互重叠的可能性;并用主曲线法确定了失重过程的最可几机理函数的积分式G(a)=1-(1-a)m(m=0.813 9±0.02);由Ea和G(a)求得速率方程中的指前因子In(A/s-1)为23.57±0.018.","authors":[{"authorName":"<span style=\"color:red\">解</span><span style=\"color:red\">凤</span><span style=\"color:red\">霞</span>","id":"1e35ef58-4965-40ad-ae9d-75ceb255b6f0","originalAuthorName":"解凤霞"},{"authorName":"张逢星","id":"f10825da-55ff-4058-b801-5690b0a46569","originalAuthorName":"张逢星"},{"authorName":"薛凝","id":"5abfc8c5-41a0-4aea-b35b-76dc0b229955","originalAuthorName":"薛凝"}],"doi":"10.3969/j.issn.1000-0518.2008.03.018","fpage":"340","id":"f7212f37-381b-46b8-af4f-6dc95e5baec1","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bc078e5a-a7a4-4d4a-921d-e77ed37689f2","keyword":"顺丁烯二酸酐","originalKeyword":"顺丁烯二酸酐"},{"id":"acd1a1d2-99f3-4aa8-b02b-c0ba3d1817d0","keyword":"等转化率法","originalKeyword":"等转化率法"},{"id":"2e2c6c21-18f7-46fd-8fc2-8ea0b19d2954","keyword":"主曲线法","originalKeyword":"主曲线法"},{"id":"33857c49-c64b-4fa4-b671-1d6ef777a560","keyword":"热分析动力学","originalKeyword":"热分析动力学"}],"language":"zh","publisherId":"yyhx200803018","title":"顺丁烯二酸酐的热失重动力学","volume":"25","year":"2008"},{"abstractinfo":"五<span style=\"color:red\">凤</span>金矿床是延边地区中生代火山岩金、铜成矿带中典型的金矿床,通过对该矿床构造控矿和矿体富集规律的研究,认为断裂构造是控制矿化蚀变带及矿体的主要因素.百草沟-金苍北东东向深断裂带与北西向小延吉河和朝阳河断裂的组合控制火山盆地的产生,为主要的导岩、导矿构造,小延吉河和朝阳河两条断裂的次级北东和北西向断层为主要的容矿构造.断层的交汇、张性断层、产状变化和多期次活动叠加等是控制富矿体的主要因素,依据构造控矿和矿体富集规律可以进行就矿找矿和成矿预测.","authors":[{"authorName":"汪建宇","id":"72893220-bd47-4b39-b7ce-aeef9f8600d9","originalAuthorName":"汪建宇"},{"authorName":"贾大成","id":"354cc3c1-3dab-44cf-96dc-fa0d32317ccc","originalAuthorName":"贾大成"},{"authorName":"高文","id":"884a19dc-1cbc-416e-8861-b9d4b53d9dd9","originalAuthorName":"高文"},{"authorName":"徐爱军","id":"37a1089c-6ce7-42a6-a0f8-3e5bc1135c33","originalAuthorName":"徐爱军"},{"authorName":"任德奎","id":"75bc4205-1ea0-4292-b60a-efcb6dbddb46","originalAuthorName":"任德奎"}],"doi":"10.3969/j.issn.1001-1277.2011.10.005","fpage":"23","id":"b4cc2086-e79f-4317-8dea-f99325334e93","issue":"10","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"5a1a5f00-7524-4188-98d7-bc700b27f76e","keyword":"五<span style=\"color:red\">凤</span>金矿床","originalKeyword":"五凤金矿床"},{"id":"c3170ea9-0dc7-46e5-abd8-fefcaec58405","keyword":"断裂构造","originalKeyword":"断裂构造"},{"id":"ce5a9ed7-bb55-4c87-a08b-9efc7ac650ac","keyword":"控矿构造","originalKeyword":"控矿构造"},{"id":"4b5767b9-51b5-4a87-a3d8-cba806e9f41a","keyword":"成矿预测","originalKeyword":"成矿预测"},{"id":"6f606ed6-03c9-4ccf-9e9f-1b483dac2ff8","keyword":"吉林延吉","originalKeyword":"吉林延吉"}],"language":"zh","publisherId":"huangj201110005","title":"吉林延吉五<span style=\"color:red\">凤</span>金矿床构造控矿及矿体富集规律","volume":"32","year":"2011"},{"abstractinfo":"随州硬玉质变霓<span style=\"color:red\">霞</span>正长岩的岩石组织结构、矿物赋存状态、矿石可选性和玻璃陶瓷原料应用试验研究表明:该资源具有易采易选两大优点,矿石经单一磁选的精矿可作玻璃和陶瓷的原料;同时已反复试验证实该资源可烧成原矿用量达90%的釉面墙地砖.","authors":[{"authorName":"赵文俞","id":"0775c5d3-e323-46f8-ae4f-aa22afa3d577","originalAuthorName":"赵文俞"},{"authorName":"王勤燕","id":"a2b342a3-1f15-4bc0-9dd5-91d76a5bb62e","originalAuthorName":"王勤燕"},{"authorName":"陈文怡","id":"10a7bf9a-8ba5-4767-bc1e-90e1dce5c22a","originalAuthorName":"陈文怡"},{"authorName":"叶先贤","id":"bf105e21-5176-42a7-b229-2017e9d65e2c","originalAuthorName":"叶先贤"}],"doi":"10.3969/j.issn.1001-1625.2000.02.014","fpage":"48","id":"bbcde545-6ae6-4706-9803-79bf82f84098","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"e88566cb-7044-4e99-bd41-f4f5d6fa2ef8","keyword":"湖北随州","originalKeyword":"湖北随州"},{"id":"bf4415b1-000e-4a50-bf1a-59e569a80a89","keyword":"硬玉质变霓<span style=\"color:red\">霞</span>正长岩","originalKeyword":"硬玉质变霓霞正长岩"},{"id":"b67eebb1-db95-44f5-8c41-ef15a7aaf9ab","keyword":"玻璃陶瓷原料","originalKeyword":"玻璃陶瓷原料"}],"language":"zh","publisherId":"gsytb200002014","title":"湖北随州硬玉质变霓<span style=\"color:red\">霞</span>正长岩的岩石矿物特征及应用研究","volume":"19","year":"2000"},{"abstractinfo":"本文研究了用庚烷(C_7H_(16))和丁二烯(C_4H_6)气相浸渍热<span style=\"color:red\">解</span>碳制备不渗石墨,石墨的透气率降低几个数量级。用乙炔(C_2H_2)和丙烯(C_3H_6)在流化床中裂解在颗粒状材料上沉积疏松和致密热<span style=\"color:red\">解</span>碳层,这两层热<span style=\"color:red\">解</span>碳可以起微型压力容器的作用。最后,介绍气相生长碳纤维的研究。","authors":[{"authorName":"朱钧国","id":"c7692363-b1a9-4323-9d0b-49be291f9169","originalAuthorName":"朱钧国"},{"authorName":"徐世江","id":"0032dd4e-3ada-43f2-ac3e-008758f5bae5","originalAuthorName":"徐世江"},{"authorName":"杨冰","id":"2922faa3-91a4-4cd9-9b44-48c668dfb552","originalAuthorName":"杨冰"},{"authorName":"张秉忠","id":"7f20e803-cc30-43fb-960b-5f2386c36ffb","originalAuthorName":"张秉忠"},{"authorName":"王庆敏","id":"53e86e0e-269d-48a2-a0cd-b8eef362bff0","originalAuthorName":"王庆敏"},{"authorName":"刘少民","id":"0b46e766-e11c-4805-93d1-4c7c9cb6b397","originalAuthorName":"刘少民"}],"categoryName":"|","doi":"","fpage":"15","id":"f4213cc8-5d47-4e04-85e2-0bae7dbd9b62","issue":"2","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[],"language":"zh","publisherId":"1005-3093_1988_2_5","title":"热<span style=\"color:red\">解</span>碳研究","volume":"2","year":"1988"},{"abstractinfo":"通过对不同结构热<span style=\"color:red\">解</span>炭的显微结构、显微图像分析,消光角的测试,将热<span style=\"color:red\">解</span>炭的微观结构分为粗糙层结构RL、光滑层结构SL、再生层状结构ReL和各向同性结构ISO.其中RL消光角最大在16-21之间;SL的消光角居中;ReL经常与SL相伴,也存在生长锥,但较之RL的柱状生长锥,ReL的生长锥不仅宽短,而且在整个生长面上可以连续再生,而RL中的柱状生长锥是贯穿整个生长面、不可再生的;ISO不具有光学活性,其消光角为零.","authors":[{"authorName":"于澍","id":"809ea2fb-60cf-44d4-a60a-111ca209f86a","originalAuthorName":"于澍"},{"authorName":"张红波","id":"54f9f17c-229e-4286-9e80-d20d845ea7d9","originalAuthorName":"张红波"},{"authorName":"张传福","id":"38d5b4fc-3751-4b7e-8e69-1a8eff2e15e9","originalAuthorName":"张传福"},{"authorName":"廖寄乔","id":"fc73f857-23a6-4754-8bab-3725feedcfce","originalAuthorName":"廖寄乔"},{"authorName":"邓艳","id":"116a86f5-1796-424c-850a-771a014a424d","originalAuthorName":"邓艳"}],"doi":"10.3969/j.issn.1005-5053.2007.01.013","fpage":"57","id":"1f9ec3be-7c77-4323-895c-cef378f4c10a","issue":"1","journal":{"abbrevTitle":"HKCLXB","coverImgSrc":"journal/img/cover/HKCLXB.jpg","id":"41","issnPpub":"1005-5053","publisherId":"HKCLXB","title":"航空材料学报"},"keywords":[{"id":"63f859b8-0335-44e2-9886-0680c9f90f3e","keyword":"热<span style=\"color:red\">解</span>炭","originalKeyword":"热解炭"},{"id":"d090a1ea-32a9-47e0-99e0-98ba3a3900f4","keyword":"粗糙层","originalKeyword":"粗糙层"},{"id":"7d191354-0166-4a67-b086-30e0e63df7dc","keyword":"光滑层","originalKeyword":"光滑层"},{"id":"087a06c4-2d70-48f1-9814-4d39e850fbfb","keyword":"再生层状结构","originalKeyword":"再生层状结构"},{"id":"e8e68384-85b4-47c3-9d1a-fa3dc2cf8730","keyword":"消光角","originalKeyword":"消光角"}],"language":"zh","publisherId":"hkclxb200701013","title":"热<span style=\"color:red\">解</span>炭的表征","volume":"27","year":"2007"},{"abstractinfo":"对废轮胎在中试回转窑中进行中温热<span style=\"color:red\">解</span>(450～650℃)所得热<span style=\"color:red\">解</span>油进行了GC-MS研究.通过对热<span style=\"color:red\">解</span>油化学组成的全面分析,讨论了轮胎热<span style=\"color:red\">解</span>反应,尤其是较高热<span style=\"color:red\">解</span>温度和较长气相停留时间下的二次热<span style=\"color:red\">解</span>反应途径.通过与不同反应器的比较研究,进一步得出了微负压回转窑热<span style=\"color:red\">解</span>技术的反应特点,并为回转窑热<span style=\"color:red\">解</span>油的应用提供了重要参考依据.","authors":[{"authorName":"张志霄","id":"732e0078-5da8-47c7-9214-dc16d3d78ff3","originalAuthorName":"张志霄"},{"authorName":"池涌","id":"4b482e45-1851-40bb-86b5-f1c4f2b73de7","originalAuthorName":"池涌"},{"authorName":"高雅丽","id":"8e7f3075-8eb2-4188-b727-cb2ed8966a6b","originalAuthorName":"高雅丽"},{"authorName":"严建华","id":"41645e58-b656-4666-b4d0-3163b2e8faff","originalAuthorName":"严建华"},{"authorName":"阎大海","id":"e4dac16b-22df-4ffe-9d2a-87a5f8fb34e1","originalAuthorName":"阎大海"},{"authorName":"岑可法","id":"b807485e-966c-4e65-8ddd-c7063286256b","originalAuthorName":"岑可法"}],"doi":"","fpage":"159","id":"a6b045a3-37e8-4ed0-91a7-ac223fe69986","issue":"1","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"0a4c44af-57e4-4bf4-9471-201e74339605","keyword":"废轮胎","originalKeyword":"废轮胎"},{"id":"504e34bd-cc1d-47fe-9652-7f53da0f1669","keyword":"热<span style=\"color:red\">解</span>","originalKeyword":"热解"},{"id":"0596424d-8f03-4075-9e7e-51d8edd8bab4","keyword":"芳香烃","originalKeyword":"芳香烃"}],"language":"zh","publisherId":"gcrwlxb200501046","title":"废轮胎热<span style=\"color:red\">解</span>油的成分分析及二次热<span style=\"color:red\">解</span>反应","volume":"26","year":"2005"},{"abstractinfo":"利用Painlevé展开和扩展同宿测试法,获得了CDGKS方程的新的同宿呼吸波<span style=\"color:red\">解</span>、周期波<span style=\"color:red\">解</span>和扭结孤立波<span style=\"color:red\">解</span>,丰富了该方程<span style=\"color:red\">解</span>的内容及其动力学特征.","authors":[{"authorName":"王玲","id":"c768799b-47f2-48bb-a0fd-18049fa45254","originalAuthorName":"王玲"},{"authorName":"鲜大权","id":"42a95d3d-d4ed-4073-b919-4e1288d3f268","originalAuthorName":"鲜大权"}],"doi":"10.3969/j.issn.1007-5461.2012.04.006","fpage":"417","id":"5db9fe67-1f25-4724-8d36-69b4865ef4fd","issue":"4","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报   "},"keywords":[{"id":"0f61076b-8082-4c4f-88ef-00e2751a242d","keyword":"非线性方程","originalKeyword":"非线性方程"},{"id":"468e6ed5-4005-4699-a318-1ea00d6ee9da","keyword":"CDGKS方程","originalKeyword":"CDGKS方程"},{"id":"ac1fa26d-e4d7-4f64-ad70-bdad5e1b42c1","keyword":"Painlevé展开法","originalKeyword":"Painlevé展开法"},{"id":"fcc3faa0-c33f-4468-a507-91c984f6c04a","keyword":"扩展同宿测试法","originalKeyword":"扩展同宿测试法"},{"id":"38a9bf11-ec3d-45e0-b2bd-57ca70a8a9b2","keyword":"同宿呼吸波<span style=\"color:red\">解</span>","originalKeyword":"同宿呼吸波解"}],"language":"zh","publisherId":"lzdzxb201204006","title":"Caudrey-Dodd-Gibbon-Kotera-Sawada方程的同宿呼吸波<span style=\"color:red\">解</span>、周期波<span style=\"color:red\">解</span>和扭结孤立波<span style=\"color:red\">解</span>","volume":"29","year":"2012"},{"abstractinfo":"用同样的原料和配方合成醇酸树脂因醇<span style=\"color:red\">解</span>工艺不同会得到不同的结果.人们对醇<span style=\"color:red\">解</span>工艺和醇<span style=\"color:red\">解</span>产物的研究大都停留在实验数据阶段,没有为分析和设计醇酸树脂提供醇<span style=\"color:red\">解</span>产物的计算方法.为了配合采用高分子反应统计理论分析和设计醇酸树脂的配方和生产工艺,文中给出醇<span style=\"color:red\">解</span>产物组成的计算方法及适用范围.此方法计算所得结果虽然与实验数据有误差,但此误差导致醇酸树脂分析或设计的最终误差远小于试验或生产正常的质量波动,因而是可接受的.","authors":[{"authorName":"许继光","id":"b53748aa-dc2d-4b70-a6ea-10f09ee729e1","originalAuthorName":"许继光"}],"doi":"","fpage":"19","id":"b57b1416-09cb-43eb-9d18-9ed7676141ef","issue":"3","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"66b33798-5c8c-4186-abe8-97bd177840a8","keyword":"醇酸树脂","originalKeyword":"醇酸树脂"},{"id":"11c9ce99-68c6-4407-8195-c5099dfca234","keyword":"醇<span style=\"color:red\">解</span>产物","originalKeyword":"醇解产物"},{"id":"485c26b8-1e53-4baf-a2bb-f1c17c8b8151","keyword":"化学反应统计理论","originalKeyword":"化学反应统计理论"}],"language":"zh","publisherId":"tlgy201603004","title":"醇<span style=\"color:red\">解</span>产物组成的计算","volume":"46","year":"2016"}],"totalpage":231,"totalrecord":2305}