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Synthesis and Catalytic Activities of Polymer-Supported Neodymium Complexes —Polymers Containing Thiol and Sulphoxide

李楠 , 林艳红

稀土学报(英文版)

关键词:

Synthesis and Catalytic Activities of Polymer-Supported Neodymium Complexes —Polymers Containing Thiol and Sulphoxide

李楠 , 林艳红

稀土学报(英文版)

关键词:

Synthesis and Catalytic Activities of Polymer-Supported Neodymium Complexes —Polymers Containing Thiol and Sulphoxide

李楠 , 林艳红

稀土学报(英文版)

关键词:

Synthesis and Catalytic Activities of Polymer-Supported Neodymium Complexes —Polymers Containing Thiol and Sulphoxide

李楠 , 林艳红

稀土学报(英文版)

关键词:

Synthesis and Catalytic Activities of Polymer-Supported Neodymium Complexes —Polymers Containing Thiol and Sulphoxide

李楠 , 林艳红

稀土学报(英文版)

关键词:

Synthesis and Catalytic Activities of Polymer-Supported Neodymium Complexes —Polymers Containing Thiol and Sulphoxide

李楠 , 林艳红

稀土学报(英文版)

关键词:

交联聚苯乙烯-丙烯酸负载钕复合物的制备及其催化丁二烯聚合

李晓莉 , 王晓菊 , 林艳红

稀土 doi:10.3969/j.issn.1004-0277.2006.06.011

制备了含功能团-COOH的聚合物载体和聚合物载体稀土复合物P-COO·NdCl3.考察了致孔剂用量和交联度对聚合载体骨架结构的影响.实验结果表明,聚合物载体负载金属离子的能力与聚合物载体的骨架结构有关,聚合物稀土复合物是通过官能团的羰基氧原子与稀土离子配位.P-COO·NdCl3对丁二烯聚合的催化活性与其骨架结构和负载金属的量有关.聚丁二烯顺-1,4结构含量在98%以上.

关键词: 聚合物载体-稀土金属复合物 , 稀土催化剂 , 丁二烯 , 聚合