{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以FeCuK/SiO2为母体催化剂,用不同浓度的NH4HSO4水溶液进行等体积浸渍,制备了不同SO2-4含量的费托合成(FTS)铁基催化剂.采用原子发射光谱、低温N2吸附、 X射线光电子能谱、程序升温还原和穆斯堡尔谱等技术对催化剂进行了表征,并在H2/CO摩尔比0.67,WHSV=2 000 h-1,压力1.5 MPa和温度250 ℃条件下进行了浆态床FTS反应.结果表明,少量SO2-4能促进催化剂在H2中的还原;在合成气还原过程中,少量SO2-4对催化剂的碳化程度影响不大,但大量SO2-4严重抑制催化剂的碳化.在约500 h的运行实验中,各催化剂样品表现出的催化活性有所差异,但均呈现较好的稳定性.SO2-4可抑制水煤气变换反应活性,且随着SO2-4含量的增加,抑制作用愈加明显;同时,催化剂上浸渍少量SO2-4可有效抑制CH4的生成,提高低碳烯烃的选择性.","authors":[{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"07aaac42-7171-4acf-9c91-9ebc6d8942e3","originalAuthorName":"安霞"},{"authorName":"吴宝山","id":"4c535b73-7ca8-433d-89ae-df91ea5ed988","originalAuthorName":"吴宝山"},{"authorName":"万海军","id":"49b28d75-fa66-4140-ad62-3795994f3db6","originalAuthorName":"万海军"},{"authorName":"李廷真","id":"0e377f22-eb1f-4398-9633-a58dd2543ba5","originalAuthorName":"李廷真"},{"authorName":"陶智超","id":"5ed89078-5925-40ca-ac5f-3a4172086aff","originalAuthorName":"陶智超"},{"authorName":"相宏伟","id":"84e71e0c-b6f4-4ed1-88b1-4a4676d19f47","originalAuthorName":"相宏伟"},{"authorName":"李永旺","id":"0f9f78d6-aa3f-4b7b-8315-a671f702b989","originalAuthorName":"李永旺"}],"doi":"","fpage":"681","id":"41fa0a6b-dfdd-4460-af73-3622b83ac3df","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"ed4374ae-f1be-435d-8975-59aaa21ec1b3","keyword":"硫酸根","originalKeyword":"硫酸根"},{"id":"37aa7c0f-d4ae-464d-8a52-8e9fce8675df","keyword":"费托合成","originalKeyword":"费托合成"},{"id":"8157c480-2101-4589-8313-fefab0d5abcd","keyword":"铁基催化剂","originalKeyword":"铁基催化剂"},{"id":"871d70c3-5b32-405e-ac59-36e96f92bbda","keyword":"浆态床反应器","originalKeyword":"浆态床反应器"}],"language":"zh","publisherId":"cuihuaxb200708005","title":"SO2-4对铁基催化剂上费托合成反应的影响","volume":"28","year":"2007"},{"abstractinfo":"以FeCuK/SiO2为母体催化剂,通过乙酸钠浸渍得到一组不同Na含量的费托合成铁基催化剂. 采用原子发射光谱、低温N2吸附、程序升温还原和Mssbauer谱等技术对催化剂进行了表征. 在H2/CO摩尔比为0.67, 空速为 2 000 h-1, 压力为1.5 MPa和温度为250 ℃的条件下进行了浆态床F-T合成反应性能评价实验. 结果表明,浸渍少量Na能提高催化剂的比表面积,促进铁物相的分散,而浸渍大量Na却大大降低了催化剂的比表面积,使催化剂中的铁物相聚集形成较大的颗粒; 浸渍Na抑制了催化剂在H2中的第一步还原,但促进了催化剂在CO中的碳化; 在原位合成气还原过程中,浸渍Na有利于催化剂的碳化. 在500 h的运行实验中,浸渍Na的催化剂均表现出不同程度的失活现象. 反应结果表明,浸渍Na对水煤气变换反应活性影响不大,对费托合成反应活性和烃产物选择性有较大的影响. 在铁基催化剂上浸渍Na有利于C12+重质烃和低碳烯烃的生成.","authors":[{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"0734c2cc-da40-40fb-b6ad-fbf4171a6859","originalAuthorName":"安霞"},{"authorName":"吴宝山","id":"3d9c0ec7-e92b-426e-8ae7-04234c2e2dc7","originalAuthorName":"吴宝山"},{"authorName":"万海军","id":"97a6eba8-5547-4abc-b2e9-5c62c033506c","originalAuthorName":"万海军"},{"authorName":"李廷真","id":"49967fc2-6304-4e52-8a82-bacaf5ab66f5","originalAuthorName":"李廷真"},{"authorName":"陶智超","id":"d3baf6d2-5c1d-4332-9a70-873b18e9a875","originalAuthorName":"陶智超"},{"authorName":"相宏伟","id":"4e28428d-4c56-46aa-9d53-54e8002a0a03","originalAuthorName":"相宏伟"},{"authorName":"李永旺","id":"ca02ce4f-4cfd-4816-9d23-096a14dc8b0d","originalAuthorName":"李永旺"}],"doi":"","fpage":"766","id":"f444346b-2d0f-47c4-a125-9fc08ea64059","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"6fe40c86-ad31-4191-bf33-f22b89589364","keyword":"钠","originalKeyword":"钠"},{"id":"5a1ee9c4-768e-412b-8b0f-54c6f140e1d9","keyword":"费托合成","originalKeyword":"费托合成"},{"id":"710a6a20-f718-43dc-8e77-e1e874f6acf3","keyword":"铁基催化剂","originalKeyword":"铁基催化剂"},{"id":"3a2865bc-5dcb-491b-bb72-81613fc88dfa","keyword":"浆态床反应器","originalKeyword":"浆态床反应器"}],"language":"zh","publisherId":"cuihuaxb200709006","title":"浸渍钠对铁基催化剂F-T合成浆态床反应性能的影响","volume":"28","year":"2007"},{"abstractinfo":"","authors":[{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"72be0752-b7fe-45fc-815d-599665b6d433","originalAuthorName":"安霞"},{"authorName":"董四美","id":"446c5007-310c-489e-bd9f-0d14ae8a4c33","originalAuthorName":"董四美"},{"authorName":"张晓香","id":"4e8d21dc-72c6-4742-b4d6-bc3c89d3aec0","originalAuthorName":"张晓香"},{"authorName":"杨树鹏","id":"37169053-59dd-422e-8c1e-964d04f5ae9f","originalAuthorName":"杨树鹏"}],"doi":"10.3969/j.issn.1000-6826.2014.06.07","fpage":"24","id":"48999f00-d127-48d0-9098-033003283add","issue":"6","journal":{"abbrevTitle":"JSSJ","coverImgSrc":"journal/img/cover/3abe017a-2574-4821-8152-4ae974ef0471.jpg","id":"47","issnPpub":"1000-6826","publisherId":"JSSJ","title":"金属世界"},"keywords":[{"id":"afb479d4-dfc1-4c01-8d59-7be7eeddfdf5","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"jssj201406007","title":"降低角钢表面黑斑的控制技术","volume":"","year":"2014"},{"abstractinfo":"","authors":[{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"a4addf10-bc40-49cd-a9ef-a8af6a6d9a3b","originalAuthorName":"安霞"},{"authorName":"左启伟","id":"0c0fbfeb-d6b3-482e-b720-5e6ac7123245","originalAuthorName":"左启伟"},{"authorName":"陈春生","id":"3f256c36-9653-45a9-9c64-993d83b57316","originalAuthorName":"陈春生"},{"authorName":"张晓光","id":"2c2791d8-2345-4256-b0f5-84552d8aba51","originalAuthorName":"张晓光"},{"authorName":"杨树鹏","id":"2a53dd94-190d-4603-9927-15c627e281dd","originalAuthorName":"杨树鹏"}],"doi":"10.3969/j.issn.1000-6826.2013.02.014","fpage":"46","id":"720214cf-ec8c-46e9-9a06-4a701764a2f2","issue":"2","journal":{"abbrevTitle":"JSSJ","coverImgSrc":"journal/img/cover/3abe017a-2574-4821-8152-4ae974ef0471.jpg","id":"47","issnPpub":"1000-6826","publisherId":"JSSJ","title":"金属世界"},"keywords":[{"id":"fe732169-5485-48d7-9a6f-1e197f33aa0f","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"jssj201302014","title":"Q345角钢矫直开裂原因分析","volume":"","year":"2013"},{"abstractinfo":"以三嵌段共聚物聚氧乙烯-聚氧丙烯-聚氧乙烯(PEO-PPO-PEO)为模板剂,正硅酸乙酯为无机硅源,HCl、HNO3、H2 SO4及H3 PO4四种酸为酸性介质,采用水热法合成有序介孔分子筛SBA-15.通过扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)、N2吸附-脱附等手段对产物的形貌和结构进行分析.结果表明:控制合成母液中H+浓度在一定范围时,HCl、HNO3、H2 SO4、H3 PO4四种介质中合成出的产品分别为“麦穗”状、“铜钱”状、长程连续“糖块”状和高度分散“糖块”状;在酸种类相同条件下,酸浓度对孔道的大小、微孔含量、孔壁厚度等孔道结构参数有一定影响,但酸浓度对孔道的影响要远小于酸种类的影响.","authors":[{"authorName":"胡伟涛","id":"59c02edf-2efb-4b4d-b195-5e00f693e5c2","originalAuthorName":"胡伟涛"},{"authorName":"蔺丹丹","id":"4609c970-9436-4574-bb55-293cf33e04e9","originalAuthorName":"蔺丹丹"},{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"4f73ef1c-6cd2-473e-970f-6d25101673bc","originalAuthorName":"安霞"},{"authorName":"吴旭","id":"50cbeba4-18cb-4c19-9016-fb5c91e718d7","originalAuthorName":"吴旭"},{"authorName":"谢鲜梅","id":"6969a581-ad81-4879-9fc0-1ecc9cf445b9","originalAuthorName":"谢鲜梅"}],"doi":"10.11896/j.issn.1005-023X.2015.08.008","fpage":"33","id":"74165956-540b-43ff-8ab3-a1f733604b9b","issue":"8","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"e1aadf78-106e-4dc7-b0a0-847bc4ec3db7","keyword":"无机材料","originalKeyword":"无机材料"},{"id":"e3a6d0bb-82f8-41f5-b5d6-2663edde43b9","keyword":"有序介孔二氧化硅","originalKeyword":"有序介孔二氧化硅"},{"id":"e7428363-753a-4b7d-81b0-d30923796483","keyword":"孔结构","originalKeyword":"孔结构"},{"id":"4c0d52f5-69fa-4fc7-aa01-9fc7d08ed0c1","keyword":"分子筛形貌","originalKeyword":"分子筛形貌"}],"language":"zh","publisherId":"cldb201508008","title":"酸的种类和浓度对有序介孔二氧化硅形貌和孔结构的影响","volume":"29","year":"2015"},{"abstractinfo":"为获得一种分散性好、载体酸性易调变和高热稳定性的新型催化材料，该研究采用插层法和原位法制备NiAl-LDH/MMT复合材料，并借助XRD、IR、TG-DTA、BET、SEM等手段对合成材料进行了表征。插层法是先将NiAl-LDH 进行剥离形成带正电荷的无机层片，然后与蒙脱土进行插层复合；原位法是先将蒙脱土的层间阳离子Na+交换为Ni2+和Al3+，然后加碱使Ni2+、Al3+在蒙脱土层间反应生成 NiAl-LDH。结果表明，两种方法均合成出了晶型良好的复合材料，形成单层 LD H 层板与单层蒙脱土层板交替排列结构；复合材料的LDH 层板羟基脱除温度达525℃。","authors":[{"authorName":"周景龙","id":"aa30a461-ffcf-48e8-b8b6-bf383cc6e6f5","originalAuthorName":"周景龙"},{"authorName":"谢鲜梅","id":"ada4e822-087b-4d78-874f-df49dddb988b","originalAuthorName":"谢鲜梅"},{"authorName":"吴旭","id":"5798e90f-c6d8-46f0-99d2-4d9cd05bee29","originalAuthorName":"吴旭"},{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"9bee4b40-0880-41d3-b49a-a18242b00343","originalAuthorName":"安霞"},{"authorName":"马小茜","id":"6b05364e-510e-4662-81c4-d820aaaa8a99","originalAuthorName":"马小茜"}],"doi":"10.3969/j.issn.1001-9731.2013.20.029","fpage":"3035","id":"af936534-c114-4a76-8792-95f127396fd4","issue":"20","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"e17a0af0-e150-48ce-9a94-669b48762444","keyword":"蒙脱土","originalKeyword":"蒙脱土"},{"id":"bbf70adb-ac30-407f-8355-b34072933821","keyword":"镍铝类水滑石","originalKeyword":"镍铝类水滑石"},{"id":"fbaa7c9e-72e3-4b71-88d6-fed4555c79c4","keyword":"插层","originalKeyword":"插层"},{"id":"af8cd039-3d3b-450e-a1cd-5b08d6fe2d34","keyword":"原位","originalKeyword":"原位"},{"id":"1a2fca62-9b38-4569-9cef-b3676f5d8d0c","keyword":"复合材料","originalKeyword":"复合材料"}],"language":"zh","publisherId":"gncl201320029","title":"两种方法合成NiAl-LD H/MMT复合材料","volume":"","year":"2013"},{"abstractinfo":"以尿素和六水合硝酸镍为原料,采用水热法合成了粒径较小、颗粒尺寸均一且具有较大比表面积的纯相α-Ni(OH)2.详细考察了反应物浓度、物料配比、反应温度、反应时间等因素对产物晶型结构、粒径和形貌的影响,筛选出合成α-Ni(OH)2的最佳条件.借助XRD、粒度分析、BET、红外分析对其物化性能进行表征.采用循环伏安法表征了其电化学性能.结果表明,当硝酸镍浓度为0.05 mol/L,尿素与六水合硝酸镍的物质的量比为3∶1,反应时间为4h,反应温度为150℃时,制备的样品为纯相α-Ni(OH)2,其粒径主要分布在10.09～22.79 μm,比表面积为267m2/g,且具有较好的电化学可逆性.","authors":[{"authorName":"牛虎虎","id":"6ca0a328-83c4-4ade-8869-ec4e4a2f58fa","originalAuthorName":"牛虎虎"},{"authorName":"谢鲜梅","id":"ad46f35b-6528-46b1-8fd8-118f8e2d03a9","originalAuthorName":"谢鲜梅"},{"authorName":"吴旭","id":"73967587-b775-4caa-9e62-da8119d5980d","originalAuthorName":"吴旭"},{"authorName":"<span style=\"color:red\">安</span><span style=\"color:red\">霞</span>","id":"e0913171-9f81-4ced-bf76-794e6fa0690a","originalAuthorName":"安霞"},{"authorName":"陈生","id":"2338a7e0-d2a7-4d4e-acb1-4f7b6fadd282","originalAuthorName":"陈生"}],"doi":"","fpage":"31","id":"b4a971d5-3627-4954-90e8-613dfe68a880","issue":"12","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"bcdd8303-e730-4332-b8d8-3d16572b556c","keyword":"尿素","originalKeyword":"尿素"},{"id":"6d21b314-5903-4eff-a45f-a7915b0b6c98","keyword":"均匀沉淀","originalKeyword":"均匀沉淀"},{"id":"209762fa-96ae-4994-8da0-db39aff215e8","keyword":"水热合成","originalKeyword":"水热合成"},{"id":"48c0a6c9-343e-4d7d-932b-f3de79e34c02","keyword":"α-Ni(OH)2","originalKeyword":"α-Ni(OH)2"},{"id":"f7a333f2-44fd-4378-ae83-df929191a573","keyword":"电化学","originalKeyword":"电化学"}],"language":"zh","publisherId":"cldb201312009","title":"α-Ni(OH)2的合成及其性能表征","volume":"27","year":"2013"},{"abstractinfo":"随州硬玉质变霓<span style=\"color:red\">霞</span>正长岩的岩石组织结构、矿物赋存状态、矿石可选性和玻璃陶瓷原料应用试验研究表明:该资源具有易采易选两大优点,矿石经单一磁选的精矿可作玻璃和陶瓷的原料;同时已反复试验证实该资源可烧成原矿用量达90%的釉面墙地砖.","authors":[{"authorName":"赵文俞","id":"0775c5d3-e323-46f8-ae4f-aa22afa3d577","originalAuthorName":"赵文俞"},{"authorName":"王勤燕","id":"a2b342a3-1f15-4bc0-9dd5-91d76a5bb62e","originalAuthorName":"王勤燕"},{"authorName":"陈文怡","id":"10a7bf9a-8ba5-4767-bc1e-90e1dce5c22a","originalAuthorName":"陈文怡"},{"authorName":"叶先贤","id":"bf105e21-5176-42a7-b229-2017e9d65e2c","originalAuthorName":"叶先贤"}],"doi":"10.3969/j.issn.1001-1625.2000.02.014","fpage":"48","id":"bbcde545-6ae6-4706-9803-79bf82f84098","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"e88566cb-7044-4e99-bd41-f4f5d6fa2ef8","keyword":"湖北随州","originalKeyword":"湖北随州"},{"id":"bf4415b1-000e-4a50-bf1a-59e569a80a89","keyword":"硬玉质变霓<span style=\"color:red\">霞</span>正长岩","originalKeyword":"硬玉质变霓霞正长岩"},{"id":"b67eebb1-db95-44f5-8c41-ef15a7aaf9ab","keyword":"玻璃陶瓷原料","originalKeyword":"玻璃陶瓷原料"}],"language":"zh","publisherId":"gsytb200002014","title":"湖北随州硬玉质变霓<span style=\"color:red\">霞</span>正长岩的岩石矿物特征及应用研究","volume":"19","year":"2000"},{"abstractinfo":"介绍了<span style=\"color:red\">安</span>钢制氧厂在实现制氧机经济运行工作中取得显著经济效益的做法.","authors":[{"authorName":"姚文献","id":"194f2e5f-e5b2-4359-bd7f-3ffb6ce21c84","originalAuthorName":"姚文献"},{"authorName":"何凤杰","id":"bb89b4bb-f643-48ab-8017-6323821ee278","originalAuthorName":"何凤杰"},{"authorName":"李华","id":"b51b77e7-dfff-452a-bbf5-0999d140b951","originalAuthorName":"李华"}],"doi":"10.3969/j.issn.1006-9356.2004.01.004","fpage":"13","id":"955a72bd-aae9-4952-a501-dfd7abd3c5e4","issue":"1","journal":{"abbrevTitle":"ZGYJ","coverImgSrc":"journal/img/cover/ZGYJ.jpg","id":"87","issnPpub":"1006-9356","publisherId":"ZGYJ","title":"中国冶金"},"keywords":[{"id":"03e04e6f-02c0-469a-8139-4bc686a5b320","keyword":"制氧机","originalKeyword":"制氧机"},{"id":"e1093d15-f897-43d8-b8f3-c667fc9343c9","keyword":"开发","originalKeyword":"开发"},{"id":"0a5d81ab-088e-46a9-83b7-c8bcb2de5744","keyword":"改造","originalKeyword":"改造"},{"id":"dbc03adb-d4ad-446c-aa02-6e43c1f1b165","keyword":"管理","originalKeyword":"管理"},{"id":"9ed144da-b7c9-4084-8e81-d8b58085bcf1","keyword":"经济效益","originalKeyword":"经济效益"}],"language":"zh","publisherId":"zgyj200401004","title":"<span style=\"color:red\">安</span>钢制氧经济运行实践","volume":"","year":"2004"},{"abstractinfo":"回顾了<span style=\"color:red\">安</span>钢烧结的发展及其主要设备的技术改造，介绍了不同发展阶段的具体做法和经验。","authors":[{"authorName":"姚桐","id":"416b962b-02f2-4752-ad59-7932481d8251","originalAuthorName":"姚桐"},{"authorName":"陈旋","id":"42612a39-0ec3-426f-bf55-e953673ab24a","originalAuthorName":"陈旋"},{"authorName":"刘拥军","id":"dc52b1c2-6a1f-4cbb-8645-676b47342fc3","originalAuthorName":"刘拥军"},{"authorName":"曹世杰","id":"06297df6-fd92-4e62-8924-39c032663102","originalAuthorName":"曹世杰"},{"authorName":"高阳","id":"bc1b590b-0e9b-48f7-b7b7-19e945d5f20f","originalAuthorName":"高阳"}],"doi":"","fpage":"1","id":"7340aa04-a03c-4432-8167-e1500116ecfb","issue":"2","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"c0cfa270-b7ff-4c1c-9ad6-c9b539143cac","keyword":"烧结","originalKeyword":"烧结"},{"id":"7059d455-0cda-423a-abf0-e1558da712aa","keyword":"生产","originalKeyword":"生产"},{"id":"5b0485fe-c12e-4e82-b605-31b89518b5e8","keyword":"进步","originalKeyword":"进步"}],"language":"zh","publisherId":"gt200102001","title":"<span style=\"color:red\">安</span>钢烧结生产的进步","volume":"36","year":"2001"}],"totalpage":32,"totalrecord":319}