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EQUILIBRATING PARTITION RATIOS OFNb,Mn AND Si BETWEEN LIQUID IRON AND MgO-SiO_2-MnO SLAG MELTS

TANG Zhonghe GUO Shangxing CHEN Yongding Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , China [Originally published in ACTA METALL SIN (CHINESE EDN) 24 (5) 1988pp B325—B330 , [received 18 May 1987 , in revised form 26 November 1987]

金属学报(英文版)

The liquid iron containing elements Nb,Mn and Si has been equilibrated with MgO-SiO_2-MnO slag melts at 1600℃ in a Mo wire-wound resistance furnace with a duration of 4h.The oxygen activities in liquid iron were measured with oxygen sensors.Using the known equilibrium constants of concerning reactions and the oxygen activities in liquid iron,the activities of components in the slag melts can be calculated.It was found that the par- tition ratios of Nb.Mn and Si have a close linear relationship with α_(FeO) in logarithmic scale.The dependence of Nb partition ratio on mole fractions of the slag components was al- so obtained.

关键词: MgO-SiO_2-MnO slag , null

Fractal growth and form by molecular dynamics

材料科学技术(英文)

The fractal growth and form is considered by molecular dynamics and simulated using computer.

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FORM AND EFFECT OF Zr IN CuCoBeZr ALLOY

LIU Hefa SUN Naizhen DAI Xueli REN He Zhenjiang Shipbuilding Institute , Zhenjiang , Jiangsu , ChinaLI Lijun Shanghai , Electrical Machinery Plant.Shanghai.China professor.Institute of Metallic Materials Research , Zhenjiang Shipbuilding Institute , Zhenjiang , Jiangsu 212003 , China

金属学报(英文版)

Precipitation form of Zr in CuCoBeZr alloy during solidificotion.cooling and final aging,as well as its effect on the high temperature properties have been studied and discussed.Results show that during solidificotion and cooding.Zr precipitates as fine particle.Cu_3Zr,which pre- vents X-Cu grains from growing and provides more nuclei for CoBe and hence leads to finer primary CoBe.Fine Cu_3Zr partrticles also precipitate during aging. Because Co_3Zr is difficult to coalesce at high temperatures,the recrystallization temper- uture increases and the high temperature mechanical properties improve.

关键词: CuCoBeZr alloy , null

Electromagnetic confinement and shaping for plate-form p

Jun SHEN , Jianguo LI , Hengzhi FU , Junyi SU

材料科学技术(英文)

The relationship between melt shape, electromagnetic pressure and magnetic field is studied for electromagnetic confinement and shaping of plate-form part. The results of experimental observation and theoretical inference can be summarized as follows. As the melt thickness a is large enough, causing the ratio of plate thickness to current theoretic skin depth a/delta larger than 2.2, the electromagnetic pressure acting on melt can be simply expressed as P-m = B-2/2 mu, and the melt shape would be known only by measuring the distribution of magnetic flux density As a is small and makes the ratio a/delta less than 2.2, the melt shape and electromagnetic pressure for confining and shaping are determined not only by magnetic flux density B but also by melt thickness a, electromagnetic parameter mu gamma and current frequency f. In this paper, an equation used to calculate electromagnetic pressure acting on "thin plate-form melt" is brought forward. The equation gives a precise relationship between electromagnetic pressure factor p and melt thickness a, electromagnetic parameter mu gamma and current frequency f.

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Microstructure and Mechanical Properties of Two-phase TiAl Alloys in Lamellar Form

Masaharu Yamaguchi and Haruyuki Inui(Department of Metal Science and Technology , Kyoto University , Sakyo-ku , Kyoto 606 , Japan)

材料科学技术(英文)

In two-phase TiAl alloys, the lamellar structures are of special interest and importance since they are so common and persistent. not only under as-cast conditions but also after thermal treatment. However. the lamellar structures are still poor in ductility,although they are beneficial for toughness and high temperature strength. This article will review the recent progress made in understanding the basic mechanical properties of the γ and α2 phases which comprise the two-phase alloys in Iamellar form, and discuss how an improved balance of strength and ductillty in the lamellar form may be achieved

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Preparation and oxidation resistance of a crack-free Al diffusion coating on Ti22Al26Nb

Corrosion Science

A crack-free Al diffusion coating has been developed to improve the oxidation resistance of Ti22Al26Nb. It was produced by a two-step method; an Al film was deposited on the substrate alloy by arc ion plating followed by a diffusion process conducted at 873 K in pure Ar to form the Al diffusion coating. The two-step method lowers the temperature required to form the diffusion coating, which dramatically decreases the thermal stress developed in the coating and results in it being crack-free. The oxidation resistance of the non-coated Ti22Al26Nb alloy in isothermal and cyclic tests in air at 1073 K was poor, but the coated specimens possessed excellent oxidation resistance because a protective alpha-Al2O3 scale formed. The life of the Al diffusion coating greatly depends upon the rapid initial formation of a protective Al2O3 scale and interdiffusion between coating and substrate. Once the stable Al2O3 scale has formed and the composition changes from (Ti, Nb)Al-3 into (Ti, Nb)Al-2, the coating has a long life. Published by Elsevier Ltd.

关键词: alloy;metal coatings;titanium;effects of strain;oxidation;titanium-aluminum system;thermal barrier coatings;pack cementation;method;cyclic oxidation;orthorhombic alloys;tial intermetallics;nb;addition;behavior;phases;al3ti

Relationship between the existing form and inhibiting behavior of DDA on inhibiting interface

Acta Physico-Chimica Sinica

The relationship bettween the existing form and inhibiting behavior of dolecylamine(DDA) on amorphous alloy has been studied by electrochemical measurement, physical test and scanning tunneling microscopy. The experiment shows that there is different relationship between the inhibition concentration and inhibition percentage in different concentration scale. In w(DDA)=10(-6) similar to 10(-4) concentration range, the inhibition percentage increased strongly with the inhibitor concentration but the increase tendency of inhibition percentage became gently in 10(-4) similar to 10(-3) concentration scale. The adsorption isotherm formula fitting result shows that a typical mono-molecular layer of DDA was adsorbed on amorphous alloy during 10(-6) similar to 10(-4) concentration scale, without any effect from the neighbor inhibitor molecule, but in 10(-4) similar to 10(-3) range the force between the nearing neighbor inhibitor molecule decided the adsorption form. The result from STM and conductivity test indicats that the micelle had been formed when the concentration approached w(DDA)=2.3x10(-5), the protection effect DDA was prevented because of the forming of micelle.

关键词: dodecylamine;micelle;inhibiting mechanism

Design of Slant-Form Tool in Precision Reuse of Digital Paper Display

Pai-Shan Pa

材料科学技术(英文)

A reuse fabrication module using micro electroetching as a precision machining process with a new design of a slant-form tool to remove the defective indium-tin-oxide (ITO) nanostructure from the optical poly-ethyleneterephthalate (PET) surfaces of digital paper display is presented in current studies. The low yield of ITO thin film deposition is an important factor in optoelectronic semiconductor production. The adopted precision reuse process requires only a short period of time to remove the ITO nanostructure easily and cleanly, which is based on technical and economical considerations and is highly efficient. In the current experiment, a large inclined angle of the cathode and a small end radius of the anode take less time for the same amount of ITO removal. A higher feed rate of the optical PET diaphragm combines with enough electric power to drive fast micro electroetching. A small rotational diameter of the anode accompanied by a small width of the cathode corresponds to a higher removal rate for the ITO nanostructure. A pulsed direct current can improve the effect of dreg discharge and is advantageous to couple this current with the fast feed rate of the workpiece. This improvement is associated with an increase in current rating. High rotational speed of the slant-form tool can improve the effect of dregs discharge and is advantageous to associate with the fast feed rate of the workpiece (optical PET diaphragm).

关键词: Reuse fabrication

Design of Slant-Form Tool in Precision Reuse of Digital Paper Display

Pai-Shan Pa

材料科学技术(英文)

A reuse fabrication module using micro electroetching as a precision machining process with a new design of a slant-form tool to remove the defective indium-tin-oxide (ITO) nanostructure from the optical poly-ethyleneterephthalate (PET) surfaces of digital paper display is presented in current studies. The low yield of ITO thin film deposition is an important factor in optoelectronic semiconductor production. The adopted precision reuse process requires only a short period of time to remove the ITO nanostructure easily and cleanly, which is based on technical and economical considerations and is highly efficient. In the current experiment, a large inclined angle of the cathode and a small end radius of the anode take less time for the same amount of ITO removal. A higher feed rate of the optical PET diaphragm combines with enough electric power to drive fast micro electroetching. A small rotational diameter of the anode accompanied by a small width of the cathode corresponds to a higher removal rate for the ITO nanostructure. A pulsed direct current can improve the effect of dreg discharge and is advantageous to couple this current with the fast feed rate of the workpiece. This improvement is associated with an increase in current rating. High rotational speed of the slant-form tool can improve the effect of dregs discharge and is advantageous to associate with the fast feed rate of the workpiece (optical PET diaphragm).

关键词: Reuse fabrication

Research on superplasticity and superplastic extrusion of MB26 magnesium alloy

Fuxiao CHEN , Juanhua SU , Yunlin YANG , Hongtao MA

材料科学技术(英文)

The superplastic flow characteristics of hot extruded MB26 Mg alloy under the conditions of tension are studied. The effects of deformation temperature and strain rate on superplasticity are analyzed. On the other hand, the superplastic extrusion of MB26 Mg alloy is also studied.

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