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The present status and key problems of carbon nanotube based polymer composites

Express Polymer Letters

The state-of-art and key problems of carbon nanotube (CNT) based polymer composites (CNT/polymer composites) including CNT/polymer structural composites and CNT/polymer functional composites are reviewed. Based on the results reported up to now, CNTs can be an effective reinforcement for polymer matrices, and the tensile strength and elastic modulus of CNT/polymer composites can reach as high as 3600 MPa and 80 GPa, respectively. CNT/polymer composites are also promising functional composite materials with improved electrical and thermal conductivity, etc. Due to their multi-functional properties, CNT/polymer composites are expected to be used as low weight structural materials, optical devices, thermal interface materials, electric components, electromagnetic absorption materials, etc. However, the full potential of CNT/polymer composites still remains to be realized. A few key problems, such as how to prepare structure-controllable CNTs with high purity and consistently dependable high performance, how to break up entangled or bundled CNTs and then uniformly disperse and align them within a polymer matrix, how to improve the load transfer from matrix to CNT reinforcement, etc, still exist and need to be solved in order to realize the wide applications of these advanced composites.

关键词: polymer composites;carbon nanotubes;mechanical properties;electrical;properties;thermal properties

Surface metallization of alumina ceramics by pulsed high energy density plasma process

Applied Surface Science

Surface metallization of alumina ceramics was carried out by pulsed high energy density plasma (PHEDP). A layer of copper film was deposited on the surface of alumina ceramics. Scanning auger electron microscopy (SAM) analysis revealed that copper diffused deep into the alumina substrate. Bonding of alumina and copper film was good. The reaction between copper and alumina was studied by X-ray diffraction (XRD) analysis. A copper aluminum oxide unstable at high temperature and very difficult to be synthesized, cubic phase CuAl2O4, was detected. A kinetics complexity in reaction of PHEDP and ceramics was discussed. An adiabatic model was used to describe heating and quenching of the PHEDP processing and analyze the interaction between PHEDP and alumina ceramics. The experimental results suggest that PHEDP method is a useful technology for various metal-ceramics bonding. (C) 2002 Elsevier Science B.V. All rights reserved.

关键词: metallization;pulsed plasma;CuAl2O4;copper film;alumina ceramics;copper deposition;metal

Solid state reaction of Mg with Ni under high pressure

High Pressure Research

Solid state reaction of Mg with Ni was processed under static high pressure and nanocrystalline Mg2Ni was obtained. An unknown phase was also formed at lower temperature. The relation between the mean grain size of Mg2Ni and the synthetizing pressure is given, and its mechanism is discussed.

关键词: solid state reaction;high pressure;nanocrystalline;Mg2Ni;mean grain;size;unknown phase;ab(2)-type intermetallic compounds;crystal-structure

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