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G3镍基耐蚀合金管材热挤压工艺润滑行为研究 I. 玻璃润滑膜厚度模型建立及应用

王宝顺林奔张麦仓董建新

金属学报 doi:10.3724/SP.J.1037.2010.00511

研究了G3镍基耐蚀合金管材玻璃润滑热挤压工艺中润滑膜的成膜行为, 建立了润滑膜厚度的理论计算模型. 同时, 针对6000 t卧式挤压机, 结合G3合金热挤压工艺有限元模拟分析, 对热挤压工艺参数和玻璃润滑剂黏度进行了系统的研究. 结果表明, 可以通过玻璃润滑膜厚度及完成一次热挤压所需玻璃垫厚度的理论计算公式优化G3合金管材热挤压工艺参数, 并进一步获得了玻璃润滑剂黏度性质须满足: 玻璃粉的软化温度大约为720 ℃;在720-800 ℃, 玻璃黏温系数在-0.05 ℃-1和-0.04 ℃-1之间;热变形温度1100-1200 ℃区间的黏度为25-200 Pa?s.

关键词: 镍基合金 , hot extrusion , glass lubricant

爆炸复合LY12/20g双金属板疲劳裂纹扩展行为研究 I.面裂纹

崔建国 , 马莒生 , 傅永辉 , 李年 , 孙军 , 何家文

金属学报

考察了爆炸复合双层金属板LYl2/20g中界面两侧材料弹塑性失配对面裂纹疲劳扩展行为的影响.结果表明,当裂纹由弹性模量、屈服强度高的一侧向低的一侧扩展时,实际驱动力大于外加名义值;当裂纹由弹性模量、屈服强度低的一侧向高的一侧扩展时,实际驱动力小于外加名义值,从而造成裂纹扩展的加速或止裂,其影响离界面越近效果越显著,但弹性模量失配在裂纹开始扩展直至界面的过程中都起作用,而强度失配只在裂尖距界面一定距离范围内(Rp)才起作用.

关键词: LYl2/20g爆炸复合板 , null

爆炸复合LY12/20g双金属板疲劳裂纹扩展行为研究 I.面裂纹

崔建国 , 马莒生 , 傅永辉 , 李年 , 孙军 , 何家文

金属学报 doi:10.3321/j.issn:0412-1961.2001.12.007

考察了爆炸复合双层金属板LYl2/20g中界面两侧材料弹塑性失配对面裂纹疲劳扩展行为的影响.结果表明,当裂纹由弹性模量、屈服强度高的一侧向低的一侧扩展时,实际驱动力大于外加名义值;当裂纹由弹性模量、屈服强度低的一侧向高的一侧扩展时,实际驱动力小于外加名义值,从而造成裂纹扩展的加速或止裂,其影响离界面越近效果越显著,但弹性模量失配在裂纹开始扩展直至界面的过程中都起作用,而强度失配只在裂尖距界面一定距离范围内(Rp)才起作用.

关键词: LYl2/20g爆炸复合板 , 疲劳裂纹 , 弹塑性失配

采用UF法精制I+G产品

张国俊 , 许赵辉 , 刘忠洲

膜科学与技术 doi:10.3969/j.issn.1007-8924.2002.02.010

采用截留分子量(MWCO)1万的卷式超滤膜和截留分子量(MWCO)6 000的中空纤维超滤膜,去除I+G粗品液中影响I+G产品透光的色素、大分子蛋白及可溶性胶体蛋白,不需加碳、压滤等工序,产品透光合格率达100%,产品透光的合格稳定性较现有生产工艺大大提高,该工艺不仅可以省去加碳压滤等工序,而且可以保证产品一次性达到合格产品.

关键词: 肌苷酸 , 鸟苷酸 , 超滤 , 透光

Effect of negative bias voltage on CrN films deposited by arc ion plating. I. Macroparticles filtration and film-growth characteristics

Journal of Vacuum Science & Technology a-Vacuum Surfaces and Films

Chromium nitride (CrN) films were deposited on Si wafers by arc ion plating (AIP) at various negative bias voltages and several groups of N-2/Ar gas flux ratios and chamber gas pressures. The authors systematically investigated the influence of negative bias voltage on the synthesis, composition, microstructure, and properties of the AIP CrN films. In this part (Part I), the investigations were mainly focused on the macroparticle distributions and film-growth characteristics. The results showed that macroparticle densities on the film surfaces decreased greatly by applying negative bias voltage, which can be affected by partial pressure of N-2 and Ar gases. From the statistical analysis of the experimental results, they proposed a new hybrid mechanism of ion bombardment and electrical repulsion. Also, the growth of the AIP CrN films was greatly altered by applying negative bias voltage. By increasing the bias voltage, the film surfaces became much smoother and the films evolved from apparent columnar microstructures to an equiaxed microstructure. The impinging high-energy Cr ions accelerated by negative bias voltages were deemed the inherent reason for the evolution of growth characteristics. (c) 2008 American Vacuum Society.

关键词: chromium nitride films;hybrid coating system;structure zone model;si-n coatings;mechanical-properties;tin films;thin-films;pulse bias;vacuum;evaporation

包晶合金定向凝固过程中的对流效应及带状组织形成机制 I.实验结果

骆良顺张宇民苏彦庆王新郭景杰傅恒志

金属学报 doi:10.3724/SP.J.1037.2010.00485

利用电阻加热和感应加热Bridgman定向凝固系统对非小平面包晶系模型合金Fe-Ni合金进行系统的定向凝固实验研究, 探索2种常规定向凝固条件下对流对包晶合金定向凝固过程中带状组织和宏观偏析的影响规律.发现在高G/V定向凝固过程中, 对流使包晶合金定向凝固过程中轴向和径向形成严重的宏观偏析, 从而使组织演化异常复杂且难以达到稳态.轴向宏观偏析体现在有限长试样从定向凝固开始至凝固结束都将发生初生相向包晶相的转变过程, 转变过程受合金成分和对流强度影响.径向宏观偏析体现在试样心部贫溶质易形成初生相, 边缘富集溶质易形成包晶相, 在径向上也存在初生相向包晶相的转变过程.

关键词: 包晶合金 , directional solidification , convection , segregation , banding structure

Cyclic deformation behavior of Cu-30 wt% Zn single crystals oriented for single slip - I. Cyclic deformation response and slip band behavior

Acta Materialia

Cyclic deformation behavior of Cu-30% Zn single crystals oriented for single slip was studied at constant plastic shear strain amplitudes (gamma(pl)) in the range of 3.8 x 10(-5)-6.4 x 10(-3) in order to understand systematically the fundamental fatigue behavior of low stacking fault energy materials. Results indicate that the cyclic hardening behavior strongly depends on the strain amplitude applied. For low strain amplitudes (gamma(pl) <3 x 10(-4)), cyclic saturation occurred after an initial cyclic hardening stage, but for high strain amplitudes (gamma(pl) greater than or equal to 6.0 x 10(-4)) saturation could not be reached until fatigue failure. The initial cyclic hardening rate (theta(0.2)) was found to decrease with increase in the applied strain amplitude. Slip bands were found to behave very similarly to Luders band appearance at the beginning as well as in the middle stage of cyclic deformation. Particularly, the similarity of the cyclic hardening behavior at low and high strain amplitudes to the work hardening response in stages I and II of tensile deformation of the same alloy has been pointed out. Cyclic stress was further decomposed into two terms, the effective stress and the internal stress, and both were found to increase continuously with cyclic deformation. It has been demonstrated that the activities of secondary slips played an important role in the continuous cyclic hardening at high gamma(pl). A comparison of the present result with previous relevant work on both wavy and planar slip materials has been attempted. The transition of wavy slip mode to planar slip mode of Cu-Al and Cu-Zn alloys has been discussed in terms of the electron-atom ratio and the critical Value of the ratio for such a transition is found to be 1.18-1.19 for both alloys. (C) 1998 Acta Metallurgica Inc. Published by Elsevier Science Ltd. All rights reserved.

关键词: stress-strain response;dislocation-structures;alpha-brass;fatigue;alloys;cu-16;temperature;amplitude

定向凝固包晶相变微观组织演化的相场方法研究 I.三相交节点的延伸

李新中 , 苏彦庆 , 郭景杰 , 吴士平 , 傅恒志

金属学报

通过对当前包晶相变相场模型特征参数的优化, 建立了适合对具体合金包晶相变微观 组织演化进行模拟的相场模型.利用该模型对高G/vp定向凝固Ti-Al合金的 单个包晶相核心依附初生相表面的生长行为进行了模拟.结果表明, 三相交节点延伸特 性的差异将导致形成离散带状和岛屿带状两种典型组织.并且, 计算域宽度、包晶相 形核过冷度和初始成分直接影响到定向凝固包晶合金三相交节点的延伸, 也就影响到其最终的微观组织.

关键词: 包晶合金 , directional solidification , phase-field model

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