ZHANG Yuanhu ZHANG Yun HU Gengxiang Shanghai Jiaotong University
,
Shanghai
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China
金属学报(英文版)
An investigation was made on the creep crack growth behaviour under static load at 1023 K for Ni-base superalloy GH30 exposed to air and air+10% SO_2.The results showed that in the region of low stress intensity factor,the creep crack growth rate is higher in air+10% SO_2 than in air only,while in the high region,it is reverse.The fractograph of specimens has been analyzed,and the mechanism of creep crack growth together with the influences of sul- phur and oxygen has been discussed as well.
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Ni-base superalloy
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null
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null
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null
王君
,
邹家桂
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陈政标
,
高建武
,
刘彦坤
,
张杰元
,
宋莎
绝缘材料
为解决苯乙烯和甲基苯乙烯在VPI浸渍树脂应用于风力发电机中的不足,采用不饱和聚酯亚胺、引发剂和无挥发活性稀释剂研制出116HU聚酯亚胺无挥发浸渍树脂,并对其各项性能进行了研究。结果表明:116HU聚酯亚胺无挥发浸渍树脂的常规性能满足风力发电机的要求,其耐热等级可达H级。用该树脂浸渍的风电模拟线棒具有优异的介电性能、耐湿热交变和高低温循环冲击性能及耐盐雾性能等,能满足风力发电机在极端环境运行的要求。
关键词:
聚酯亚胺
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无挥发
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VPI
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风力发电机
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耐湿热
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耐盐雾
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
关键词:
room-temperature
刘建国
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安振涛
,
张倩
,
杜仕国
,
姚凯
,
王金
材料导报
doi:10.11896/j.issn.1005-023X.2017.04.030
为评估氧化剂硝酸羟胺的热稳定性,使用标准液体铝皿于3 K/min、4 K/min、5 K/min加热速率下进行热分析.借助非等温DSC曲线的参数值,应用Kissinger法和Ozawa法求得热分解反应的表观活化能和指前因子,根据Zhang-Hu-Xie-Li公式、Hu-Yang-Liang-Xie公式、Hu-Zhao-Gao公式以及Zhao-Hu-Gao公式,计算硝酸羟胺的自加速分解温度和热爆炸临界温度,并对热分解机理函数进行了研究.设计了7条热分解反应路径,采用密度泛函理论B3LYP/6-311++G(d,p)方法对硝酸羟胺的热分解进行了动力学和热力学计算.计算结果表明,硝酸羟胺热分解的自加速分解温度TsADT=370.05 K,热爆炸临界温度Te0=388.68K,Tbp0=397.54 K,热分解最可几机理函数的微分形式为f(a) =17×(1-α)18/17.硝酸羟胺热分解各路径中,动力学优先支持路径Path 6、Path 5、Path 4和Path 1生成NO和NO2,其次是Path 2、Path 7和Path 3生成N2和N2O.温度在373 K以下时,Path 1'反应无法自发进行,硝酸羟胺无法进行自发的热分解.从热力学的角度来看,硝酸羟胺在370.05K以下储存是安全的.
关键词:
硝酸羟胺
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热分析
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热稳定性
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热分解机理
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密度泛函理论
新型炭材料
The 2011 Annual World Conference on Carbon (Carbon 2011) was held in Shanghai, China, during 24-29 July, 2011. This conference was hosted jointly by East China University of Science and Technology, University of Shanghai for Science and Technology, and Institute of Coal Chemistry Chinese Academy of Sciences. About 800 attendees from 42 countries/regions participated in this conference, and 797 papers were accepted for presentation, including 5 plenary lectures, 42 keynote lectures, 280 oral presentations, and 470 posters, involving 10 topics: graphene; nanocarbon, carbon for energy storage and conversion, porous carbon and adsorption, carbon fiber and composites, precursor/carbonization and graphitization, computation and modeling, bio-carbon and safety, novel experimental techniques and characterization, bulk carbon and industrial applications. Research and development of nanocarbons are quite active and in particular, graphene received tremendous interest. Rapid progress has also been made on the electrochemical properties, energy conversion and energy storage applications of carbon materials.
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