HU Chang-qing
,
HAN Tao
,
ZHANG Yu-zhu
,
ZHANG Zhi-xia
钢铁研究学报(英文版)
For the recycling of ferrous sludge from steel industry, the carbonation pellet process should be considered as a “green” process, since no impurities are added as well as CO2 can be sequestrated and consumed. Through the thermodynamic calculation, the carbonation reaction can occur spontaneously and is an exothermic reaction. Based on the kinetic analysis through unreacted core model, the interfacial chemical reaction was the rate controlling step in the initial fast stage of carbonation, and the CO2 diffusion through the CaCO3 product layer was the rate controlling step in the following extremely slow stage. For the carbonation bonded mechanism, the pellet strength was gained by the formation and growing of CaCO3 product layer. Since the interfacial chemical reaction was the critical stage of the entire carbonation process, the emphasizes should be focused on the improvement of sorbent activity and the optimization of process parameters, such as pore structure, pore surface area, and total pressure, CO2 partial pressure, reaction temperature, etc to accelerate the reaction rate and to improve the quality of carbonation pellets.
关键词:
CO2 sequestration
,
ferrous sludge
,
carbonation pellet
,
thermodynamics
,
kinetics
,
unreacted core model
中国腐蚀与防护学报
N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....
关键词:
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
关键词:
room-temperature
Philosophical Magazine
The error of Equation (15b) in my article [Z.D. Zhang, Phil. Mag. 87 (2007) p.5309] in the application of the Jordan-Wigner transformation does not affect the validity of the putative exact solution, since the solution is not derived directly from that equation. Other objections of Perk's comment [J.H.H. Perk, Phil. Mag. 89 (2009) p.761] are the same as those in Wu et al.'s comments [F.Y. Wu et al., Phil. Mag. 88 (2008) p.3093; p.3103], which do not stand on solid ground and which I have sought to refute in my previous response [Z.D. Zhang, Phil. Mag. 88 (2008) p.3097]. The conjectured solution can be utilized to understand critical phenomena in various systems, whereas the conjectures are open to rigorous proof.
关键词:
3D Ising model;exact solution;conjecture;critical phenomena;ferromagnetism;magnetic phase transition;model;analyticity