材料期刊网

In Situ Laser Coating of Calcium Phosphate on TC4 Surface for Enhancing Bioactivity

DENG Chi , WANG Yong , ZHANG Yaping , GAO Jiacheng

钢铁研究学报(英文版)

Titanium alloy has been a successful implant material owing to its excellent ratio of strength to weight, toughness, and bioinert oxide surface. Significant progress has been made in improving the bioactivity of titanium alloy by coating its oxide surface with calcium phosphates. In the present study, in situ coating was reported on Ti6Al4V(TC4) surface with calcium phosphate (CaP) bioceramics synthesized and synchronously cladded by laser beam. This coating was grown by first preplacing directly the raw powders, which contain 80% of CaHPO4·2H2O, 20% of CaCO3, and dram of rare earth (RE), on the TC4 surfaces, and then exposing the surfaces to the laser beam with a power density of 1273-1527 MW·m-2 and a scanning velocity of 105 m/s. The resultant coating was characterized using scanning electron microscopy (SEM), Xray diffraction (XRD), thermogravimetric analysis and Differentthermal Scanning (TGDSC), and Energy Dispersive Xray Detection (EDX). The results show that these laser ceramics include hydroxyapatite (HA), tricalcium phosphate (TCP), Ca2P2O7, and other CaP phases, and the interface between the coating and the TC4 substrate has tighter fixation, in which the chemical bonding is approved. These laser hybrid coatings are useful in enhancing the bioactivity of titanium alloy surfaces.

关键词: titanium alloy surface;calcium phosphate ceramics;laser cladding;bioactivity

集装箱用SM490YA钢的试验研究

宋育来 , 陈吉清 , 陈邦文 , 刘静 , 刘志勇 , 胡敏

钢铁研究

研究了集装箱用SM490YA钢板的力学性能、工艺性能、微观组织结构等.采用气体保护焊对钢板进行焊接性能试验评价,并对钢的强韧化机理进行初步探讨.结果表明,SM490YA钢板不仅性能稳定,不存在明显的各向异性,易于成型,而且钢板焊接性能优良,是制造集装箱的理想钢板.

关键词: 集装箱钢 , 力学性能 , 工艺性能 , 焊接性能 , 微观组织

Jian ZHANG/Langhong Lou

材料科学技术（英文）

关键词:

掺杂稀土的xSrO.yA12O3系长余辉发光材料的制备及其光学性能

林元华 , 张中太 , 张枫 , 唐子龙 , 吕霄 , 郑子山

功能材料

利用SrCO3-A12O3-RE(NO3)3(RE:Eu,Dy)粉体为原料,加入少量酒精,进行预混合、球磨、干燥.将此混合粉体在还原气氛下高温烧成,最终制得不同发光性能的xSrO.yAl2O3:RE(RE:Eu,Dy)光致发光材料,并对其性能进行了研究.发光粉体的发射光谱表明,随着A12O3/SrO(摩尔比x)的增加,其相应粉体发射光谱的主峰位置(λE)逐渐向短波方向移动,符合λE=531.018-23.028X关系式.余辉衰减曲线表明,这些发光材料均具有一定的长余辉特性.从而说明只要控制一定的Al2O3/SrO比例,即可获得发光颜色为紫色到绿色的多种发光材料.对于其长余辉机制,认为是加入的Dy3+起到了陷阱能级的作用,它将部分空穴俘获,并在热扰动下,慢慢将空穴释放出来,并再次与介稳态Eu1+复合发光,从而达到延长余辉的作用.

关键词: 长余辉 , 发光材料 , 发射光谱 , 空穴

YA系列激光晶体原材料--高纯Y2O3、Nd2O3的研制与应用

张静筠

人工晶体学报

关键词:

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

高尔夫球杆轧机的设计

马余选 , 王普毅

稀有金属材料与工程

阐述了国内首台用于轧制钛高尔夫球杆的装备--YA15轧管机的总体构成及设计研制中解决的主要技术难点、主要参数的设计计算和最终达到的性能.

关键词: 钛 , 高尔夫球杆 , 轧管机:设计

烧结助剂种类对Si3N4/SiC陶瓷力学与摩擦性能的影响

胡海龙 , 曾宇平 , 左开慧 , 夏咏锋 , 姚冬旭

无机材料学报 doi:10.15541/jim20140181

分别以Y2O3-Al2O3(YA)和Y2O3-MgO(YM)为烧结助剂，采用气压烧结工艺制备了Si3N4/SiC陶瓷，研究了两种不同的烧结助剂对陶瓷的力学和摩擦性能的影响。研究结果表明：添加不同种类的烧结助剂对制备陶瓷的相对密度、抗弯强度、断裂韧性、硬度、摩擦系数和磨损率影响很大；与添加烧结助剂YM相比较，添加烧结助剂YA的Si3N4/SiC陶瓷在烧结过程中表现出了更好的烧结性能，得到的陶瓷样品最终显示了更好的力学和摩擦性能，尤其是SiC添加量为20wt%的Si3N4/SiC陶瓷。这主要归因于烧结助剂YA的添加使Si3N4/SiC陶瓷呈现出了更高的相对密度，获得的晶粒长径比更小。

关键词: Si3N4/SiC陶瓷 , 烧结助剂 , 抗弯强度 , 摩擦性能

Broer-Kaup-Kupershmidt方程的新精确解

杨立娟 , 杨琼芬 , 杜先云

量子电子学报 doi:10.3969/j.issn.1007-5461.2012.02.003

CK方法是求解非线性发展方程的一种有效的直接方法.利用推广的CK方法,求得(2+1)维Broer-Kaup-Kupershmidt方程的Backlund公式,从而获得方程的大量新的精确解,推广了Xu和Zhang的结果.

关键词: 非线性发展方程 , Broer-Kaup-Kupershmidt方程 , 精确解 , CK方法 , Backlund变换

Three-dimensional (3D) Ising universality in magnets and critical indices at fluid-fluid phase transition

Phase Transitions

Experimental data for critical exponents in some magnetic materials are compared with recent theoretical results on the three-dimensional (3D) Ising model, as derived by one of us (ZDZ) based on two conjectures [Z.D. Zhang, Conjectures on the exact solution of three-dimensional (3D) simple orthorhombic Ising lattices, Phil. Mag. 87 (2007), pp. 5309-5419]. It is found that critical exponents in some bulk magnetic materials indeed form a 3D Ising universality. Our attention is then focused on the critical indices at fluid-fluid phase transition. We suggest to use Zhang's exponent = 3/8 to fit the experimental data over the wider asymptotic region near the critical point of a fluid-fluid phase transition. The 3D Ising universality should exist for critical indices in a certain class of magnets and at fluid-fluid phase transition.

关键词: magnetically ordered materials;fluid-fluid;phase transitions;order-disorder effects;ferromagnetic curie temperature;liquid critical phenomena;x-ray-scattering;critical exponents;critical-point;coexistence;curves;binary-solutions;ionic-solutions;behavior;equation