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Influence of Sputtering Gas on Morphological and Optical Properties of Magnesium Films

Yogendra K. Gautam Amit K. Chawla Vipin Chawla R.D. Agrawal

材料科学技术(英文)

The influence of sputtering gas (He & Ar) on the structural properties of Mg thin films has been investigated. The optical property (reflectance) that results from the growth of films at varying substrate temperatures (Tsub) was also studied. The deposited films were characterized by using X-ray diffraction (XRD), field emission scaning electron microscopy (FE-SEM), atomic force microscopy (AFM) and UV-Vis-NIR spectrophotometer. The smaller crystallite size and lower deposition rate were observed in the presence of Helium atmosphere compared to Argon. Morphology of the films shows 2D hexagonal geometry of grains in the deposition temperature range (Tsub≈50−150°C) in both the sputtering gases. The surface roughness of the polycrystalline films were found to increase with increase in the deposition temperature of both ambient gases. Optical reflectance of Mg films was measured in near infrared region and larger reflectance was observed from Mg films sputtered in He atmosphere compared to that in argon.

关键词: X-ray diffraction (XRD) , XRD , Atomic Force Microscope (AFM) , Reflectance

Cs-K混合蒸气中Cs(8D)+K(4S)碰撞能量转移

沈异凡 , 沈晓燕

量子电子学报 doi:10.3969/j.issn.1007-5461.2004.01.003

在Cs-K混合蒸气中,两步激发Cs原子到8D态,观察了Cs(8D)+K(4S)→Cs(5D)+K(4P)碰撞能量合并逆过程(REP,reverse energy pooling).应用双调制技术探测K(4P)原子发射的荧光,基态K原子密度用光学吸收方法测量.得到了REP速率系数,讨论了其它过程对速率系数的影响.

关键词: 光谱学 , 激发态原子 , 能量合并逆过程 , 速率系数

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

Pressure effects on spectra of tunable laser crystal GSGG : Cr3+ IV: Pressure-induced shifts of R-1 line, R-2 line, and U band at 300 K

Communications in Theoretical Physics

By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R-1 line, R-2 line, and U band of GSGG:Cr3+ at 300 K have been calculated, respectively. The calculated results are in good agreement with all the experimental data. Their physical origins have also been explained. It is found that the mixing-of degree \t(2)(2)(T-3(1))e(4)T(2)> and \t(2)(3) 2E> base-wavefunctions in the wavefunctions of R-1 level of GSGG:Cr3+ at 300 K is remarkable under normal pressure, and the mixing-degree rapidly decreases with increasing pressure. The change of the mixing-degree with pressure plays a key role not only for the 'pure electronic' PS of R-1 line and R-2 line but also the PS of R-1 line and R-2 line due to EPI. The pressure-dependent behaviors of the 'pure electronic' PS of R-1 line (or R-2 line) and the PS Of R-1 line (or R-2 line) due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R-1 line (or R-2 line). In the range of about 15 kbar similar to 45 kbar, the mergence and/or order-reversal between t(2)(2)(T-3(1))e(4)T(2) levels and t(2)(32)T(1) levels take place, which cause the fluctuation of the rate of PS for t(2)(2)(T-3(1))e(4)T(2) (or t(2)(3) T-2(1)) with pressure. At 300 K, both the temperature-dependent contribution to R-1 line (or R-2 line or U band) from EPI and the temperature-independent one are important.

关键词: high-pressure effect;spin-orbit interaction;electron-phonon;interaction;d orbital;coupling between t(2)(2)(3T(1))e(4)T(2) and;t(2)(32)E;tunable laser crystal;theoretical calculations;temperature-dependence;thermal broadenings;garnet crystals;cr3+ ions;r-line;cr-3+;luminescence;ruby;spectroscopy

在氯化物溶液中电解提取K13铁镍铬基高温合金中(r)'相

马翔 , 王凡

冶金分析 doi:10.3969/j.issn.1000-7571.1999.06.005

在研究无铬的铁镍钴基超合金中的r'相分析时,我们发现了该合金中的r'相可以在氯化物水溶液中定量提取.本工作进一步证明,K13铁镍铬基超合金中的r'相也可以在氯化物水溶液中定量提取.这种方法获得的r'相提取量远较传统的含氧阴离子电解液中的提取量高.应当注意的是,随着电解温度的降低,r'相的提取量明显增加,因而必须采用低温(0~5℃)电解.

关键词: 相分析 , r'相 , 高温合金

纤维体积分数对K3D/MCPA复合材料力学性能的影响

雷雨 , 万怡灶 , 张宗强 , 王玉林

材料科学与工程学报 doi:10.3969/j.issn.1673-2812.2003.06.012

本文研究了纤维体积分数对三维编织芳纶纤维增强铸性尼龙(简称K3D/MCPA)复合材料力学性能的影响.研究表明,K3D/MCPA复合材料有优异的抗冲击性能,冲击强度比三维编织芳纶纤维增强铸性尼龙(简称C3D/MCPA)和纯基体均有大幅度的提高,且随着纤维体积的提高而升高.K3D/MCPA复合材料剪切强度随纤维体积比的增大而增大,其纵向剪切强度低于纯基体和C3D/MCPA复合材料,但其横向剪切强度高于它们.K3D/MCPA复合材料弯曲强度与弯曲模量随纤维体积比的提高而提高,但与相同体积比的C3D/MCPA相比,K3D/MCPA的弯曲强度与弯曲模量均较低.

关键词: 纤维体积分数 , 三维编织芳纶纤维 , 铸型尼龙 , 力学性能

X70管线钢J1dK1a与V型缺口Ak关系研究

朱杰武 , 柳永宁 , 许雁 , 冯耀荣

机械工程材料 doi:10.3969/j.issn.1000-3738.2005.06.007

在不同温度下测试了X70管线钢动态断裂韧度K1d、J1d和止裂韧度K1a以及夏氏V型缺口冲击韧度Ak,对三者的关系进行了分析.结果表明:温度和加载速率都对断裂韧度产生影响;加载速率变化引起的韧-脆断裂转变具有热激活特征,在热激活分析基础上,在应力强度因子速率K=15 MPa·m1/2s-1条件下,得出断裂韧度、止裂韧度和冲击韧度三者的关系:Ak=4.84×106T-2.8K1d(或K1a).可以用小试样Ak数据计算得到K1dK1a.

关键词: 管线钢 , 断裂韧度 , 止裂韧度 , 韧-脆断裂转变

Large magnetoresistance over an entire region from 5 to 380 K in double helical CoMnSi compound

Journal of Physics D-Applied Physics

A large magnetoresistance (MR) is observed in a double helical CoMnSi compound over the entire temperature region from 5 K to the maximum measuring temperature of 380 K, with the largest MR ratio of -18.3% at 245 K and the smallest MR ratio of -5.5% at 85 K at 5 T. This phenomenon is ascribed to two different mechanisms in different temperature regions. The suppressed spin fluctuations of the double helical structure are responsible for the MR below 110 K. However, in consideration of the natural multilayer superstructure of CoMnSi, the larger MR above 110 K is ascribed to the decrease in K-space restrictions when the change in magnetic structure from double helical order to fan order occurs.

关键词: giant magnetoresistance;magnetic-structure;crystal;metals

Phase diagram of R-Fe-Co pseudoternary system with R <= 33.3% (mole fraction, R = Sm0.5Dy0.5)

Transactions of Nonferrous Metals Society of China

Phase equilibria of the R-Fe-Co pseudoternary system with R less than or equal to 33.3% ( mole fraction, R = Sm0.5Dy0.5) were determined in an isothermal section at 1073 K and a vertical section of RFe2-RCo2 by using OM, X-ray diffractometer, EP-MA DTA techniques. There are seven intermetallic phases: (Sm, Dy) (Fe, Co)(2), (Sm, Dy) (Fe, Co)(3), (Sm, Dy)(6) (Fe, Co)(23), (Sm, Dy)(2) (Fe, Co)(7), (Sm, Dy) (Fe, Co)(5), Th2Ni17-type and Th2Zn17-type (Sm, Dy)(2)(Fe, Co)(17). The (Sm, Dy)(6)(Fe, Co)(23) phase dissolves 36% Co(mole fraction) at 1073 K. However, the (Sm, Dy)(2)(Fe, Co)(7) phase in R-2(Fe1-xCox)(7) alloys dissolves about 19% Fe(mole fraction) at 1073 K.

关键词: rare earth-iron-cobalt;phase diagram;structure;compounds;sm-co;magnetic-properties;binary-system;magnetostriction

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