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Cu-Zr/ZrN薄膜体系的电阻率和纳米压入研究

白宣羽 , 汪渊 , 徐可为

稀有金属材料与工程

采用磁控溅射方法在Si(111)基片上沉积Cu-Zr/ZrN薄膜体系作为扩散阻挡层.通过比较Cu-Zr/ZrN薄膜体系和三元非晶(Mo,Ta,W)-Si-N的电阻率,同时比较Cu-Zr/ZrN薄膜体系和Ta,YaN的硬度,说明作为扩散阻挡层的材料的选取,应从整体性能上考虑,而不能仅仅考虑热稳定性等单一指标.

关键词: 非晶 , 电阻率 , 纳米压入 , 硬度

CFRP双剪单钉连接接头强度分析

崔海涛 , 温卫东

宇航材料工艺 doi:10.3969/j.issn.1007-2330.2004.04.011

双剪连接接头是复合材料结构连接设计的主要环节.针对T300/KH304复合材料层合板的双剪连接形式,分析了单钉连接情况下的接头强度,并采用Yamada-Sun准则预测了该层合板结构双剪连接接头的破坏载荷.结果表明:该接头的破坏模式主要呈现为挤压破坏;Yamada-Sun准则可以较好地预测该结构的破坏载荷;所预测的接头的破坏载荷及破坏模式,试验结果与数值分析结果比较一致.

关键词: 复合材料层合板 , 双剪连接接头 , 强度分析 , 有限元法

Studies of the g factors and the local structure for Ni3+in LaAl0.9Ni0.1O3, La0.75Y0.25Al0.99Ni0.01O3 and YAl0.9Ni0.1O3

Radiation Effects and Defects in Solids

The electron paramagnetic resonance g factors and the local structure for Ni3+ in LaAl0.9Ni0.1O3 (LAN), La0.75Y0.25Al0.99Ni0.01O3 (LYAN) and YAl0.9Ni0.1O3 (YAN) are theoretically studied from the perturbation formulas of the g factors for a 3d7 ion of low spin (S = 1/2) in tetragonally elongated octahedra. In these formulas, the contributions to the g factors from the tetragonal distortion, characterized by the tetragonal field parameters Ds and Dt are taken into account. According to the calculations, the ligand octahedra around Ni3+ are suggested to suffer 2% relative elongation along the [001] (or C4) axis due to the Jahn-Teller effect.

关键词: defect structures;electron paramagnetic resonance;crystal-fields and;spin Hamiltonians;Ni3+;LaAlO3;LaYAlO3;YAlO3;atomic screening constants;optical-spectra;paramagnetic-resonance;superconducting tapes;lattice-distortions;superposition model;scf;functions;cr3+ ions;crystals;epr

非微扰QCD和核遮蔽效应对K因子的影响

智海素 , 侯召宇

原子核物理评论 doi:10.3969/j.issn.1007-4627.2006.01.002

考虑非微扰量子色动力学物理真空夸克凝聚效应,计算了碳核与碳核在质心系能量分别为630和200 GeV时碰撞Drell-Yan过程的K因子,以及加入核遮蔽因子后非微扰效应对K因子的影响,并把计算结果与没有考虑夸克凝聚非微扰效应的K值进行了对比.结果表明,非微扰效应和核遮蔽效应对K因子影响很小.

关键词: K因子 , Drell-Yan过程 , 夸克凝聚 , 非微扰量子色动力学 , 核遮蔽效应

掺Mn硅酸锌薄膜中微量氧化锌对发光强度的影响

席俊华 , 季振国 , 刘坤 , 王超 , 杜鹃

无机材料学报 doi:10.3724/SP.J.1077.2006.01506

利用溶胶-凝胶法结合高温热处理在硅衬底上制备了掺Mn硅酸锌薄膜, 用XRD、SEM、UV-Vis吸收谱和PL谱测试了样品的结晶性能与光学性能, 并分析了热处理温度对掺Mn硅酸锌薄膜的结晶性能和光学性能的影响. 实验结果发现, ZnO的适量存在对掺Mn薄膜的发光有增强作用. 进一步的分析认为, 这一现象的机理可由G.G. Qin提出的量子约束-发光中心 (QCLC) 模型进行解释, ZnO中受激发的电子和空穴通过隧穿效应到达硅酸锌基体中复合发光, 从而增强发光强度.

关键词: 硅酸锌 , ZnO , photoluminescence , quantum confinement-luminescence center

Extended quantum confinement luminescence center model for photoluminescence from oxidized porous silicon and nanometer-Si-particle- or nanometer-Ge-particle-embedded silicon oxide films

Materials Research Bulletin

Through analysis of the latest experimental results reported in the literature and obtained in our laboratory, we have extended our previous quantum confinement/luminescence center model for the photoluminescence mechanism of porous Si and of nanometer-silicon-particle-embedded Si oxide films (G.G. Qin and Y.Q. Jia, Solid State Commun. 86, 559 (1993)). We consider that there are three main types of competitive photoexcitation/photoemission processes and that the process in which photoexcitation occurs in the nanometer silicon particles (NSPs) while photoemission occurs in the luminescence centers (LCs) in the SiOx layers very close to the NSPs is usually the major one. We discuss under what conditions the other two types of processes will dominate. We believe that the extended quantum confinement/luminescence center model is a physical model that is suitable for the photoluminescence from silicon oxide films embedded with NSPs or nanometer Ge particles (NGPs), as well as from oxidized porous Si. (C) 1999 Elsevier Science Ltd.

关键词: oxides;luminescence;defects;blue-light emission;visible luminescence;optical-properties;nanocrystals;mechanism;dependence;sio2-films;absorption;spectra;defects

Reply to "Comment on 'Low-temperature lattice excitation of icosahedral Al-Mn-Pd quasicrystals' "

Physical Review B

In response to the comment by Wang and Qin, we have rewritten our equation (22) following the coordinate system of Dina, et al. [J. Wuhan Univ. (Nature Science Edition) 3, 23 (1992)]. According to the thermodynamic stability condition and the experiment of Capitan et al., we have chosen the new parameters of the phason elastic constants. Based on this, we have recalculated the coefficients of the expressions on the vibrational denty of states and the specific heat of the icosahedral Al-Nin-Pd quasicrystal. Our results are still in agreement with the experimental data measured by Walti et al. [Phys. Rev. B 57, 10 504 (1998)]. It demonstrates that our method is useful for dealing with the low-temperature vibrational excitation of icosahedral quasicrystals.

关键词: quasi-crystals;diffuse-scattering

掺Mn硅酸锌薄膜中微量氧化锌对发光强度的影响

席俊华 , 季振国 , 刘坤 , 王超 , 杜鹃

无机材料学报 doi:10.3321/j.issn:1000-324X.2006.06.038

利用溶胶-凝胶法结合高温热处理在硅衬底上制备了掺Mn硅酸锌薄膜,用XRD、SEM、UV-Vis吸收谱和PL谱测试了样品的结晶性能与光学性能,并分析了热处理温度对掺Mn硅酸锌薄膜的结晶性能和光学性能的影响.实验结果发现,ZnO的适量存在对掺Mn薄膜的发光有增强作用.进一步的分析认为,这一现象的机理可由G.G.Qin提出的量子约束-发光中心(QCLC)模型进行解释,ZnO中受激发的电子和空穴通过隧穿效应到达硅酸锌基体中复合发光,从而增强发光强度.

关键词: 硅酸锌 , 氧化锌 , 光致发光 , 量子约束-发光中心

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