材料期刊网

Behaviour of Rare Earths in Solid Solution in Steel

LIN Qin , YE Wen , DU Yuansheng , YU Zongsen Department of Physical Chemistry , University of Science and Technology Beijing , 100083 , China.

材料科学技术（英文）

The contents of rare earth metals(REM) in solid solution in 16 Mn steel were determined by means of inductive coupling plasma (ICP) spectroscopy.The amount of REM in solid solution is only a few ppm in the steel with MnS inclusions, which rises slightly with the increasing of REM content in steel.At RE/S>1.9,the MnS inclu- sions in steel disappear completely,the REM con- tent in solid solution increases rapidly with the in- creasing of REM content.The solubility of cerium in 16 Mn steel(st 52)is less than 0.011 wt—% at room temperature. The results obtained indicate that REM in sol- id solution reduce the amount of pearlite and in- crease that of ferrite and its microhardness.Dis- solved REM oculd increase temperature of critical points,alleviate band structnre and suppress growth of austenite grains.

关键词: rare earth , null , null

Metal-Free Heterogeneous Catalysis for Sustainable Chemistry

Chemsuschem

The current established catalytic processes used in chemical industries use metals, in many cases precious metals, or metal oxides as catalysts. These are often energy-consuming and not highly selective, wasting resources and producing greenhouse gases. Metal-free heterogeneous catalysis using carbon or carbon nitride is an interesting alternative to some current industrialized chemical processes. Carbon and carbon nitride combine environmental acceptability with inexhaustible resources and allow a favorable management of energy with good thermal conductivity Owing to lower reaction temperatures and increased selectivity, these catalysts could be candidates for green chemistry with low emission and an efficient use of the chemical feedstock This Review highlights some recent promising activities and developments in heterogeneous catalysis using only carbon and carbon nitride as catalysts The state-of-the-art and future challenges of metal-free heterogeneous catalysis are also discussed.

关键词: carbon;catalyst;heterogeneous catalysis;selectivity;sustainable;chemistry;graphitic carbon nitride;modified activated carbon;nanofiber/graphite-felt composite;ordered mesoporous carbons;oxygen;reduction reaction;nitrogen-doped graphite;fuel cell cathode;onion-like carbon;oxidative dehydrogenation;hydrogen-production

SERS and Quantum Chemistry Studies of Adsorption of Thiourea and Ethylthiourea on Silver Electrode

Acta Physico-Chimica Sinica

Adsorption of thiourea (TU) and ethylthiourea( ETU) on roughened silver electrode was investigated using in situ surf. enhanced Raman spectroscopy(SERS) Using quantum chemistry and HSAB theories, the influences of electrode potential and the different substituent groups on SERS were disc i. TU is chemisorbed perpendicularly by Ag-S bond on silver at E = -0.3 V and adsorption of TU turns into a parallel orientation at E = -0.9 V. ETU is always chemisorbed at an angle from Ag. The adsorption of ETU is through and C=C and C=O groups at E = -0.3 V, and mainly through C=C at E = -0.9V.

关键词: Surface enhanced Raman spectroscopy;Adsorption;Quantum chemistry;Thiourea;Inhibitor

LOCAL CHEMISTRY AND THE COHESIVE STRENGTH OF GRAIN BOUNDARIES IN Ni_3Al

Shanthi Subramanian , David Muller , John Silcox and Stephen L.Sass (Department of Materials Science and Engineering and Department of Applied and Engineering Physics , Cornell University , Ithaca. NY 14853)

金属学报(英文版)

Local chemistry plays an important role in determining the cohesive strength of grain boundaries in Ni3Al. Doping with B increases the room temperature ductility and changes the fracture mode from intergranular to transgranular, while doping with Zr increases the ductility but leaves the fracture mode predominantly intergranular.Electron Energy Loss Spectroscopy (EELS) and Energy Dispersive X-ray Spectroscopy (EDS) were used to probe the changes in local bonding (and hence the cohesive strength) produced by changes in local chemistry at large angle boundaries in Ni3Al.In addition , small angle tilt boundaries were studied to correlate structure with Nienrichment at the interface. B segregation to Ni-rich grain boundaries was shown to make the bonding similar to that of the bulk, thereby increasing their fracture resistance. Ni-enrichment does not occur in the presence of Zr segregation to grain boundaries. Ni-enrichment to antiphase boundaries (APB) in small angle tilt boundaries lowers the APB energy by reducing the number of high energy Al-Al interactions across the interface. Ni-enrichment to large angle boundaries is expected to produce a similar effect on energy.

关键词: : grain boundary chemistry , null , null , null

MEASUREMENT AND APPLICATION OF PHYSICAL PARAMETERS IN UNSTEADY HEAT CONDUCTION

S. X. Wanng , D. S. Zheng , Y. L. Liu 1) Department of Material Engineering , Luoyang Institute of Technology , Luoyang 471039 , China 2) Luoyang Copper (Group) Co. , Ltd , Luoyang , China

金属学报(英文版)

As far as the accuracy of calculating unsteady temperature field is concerned, it is very important to find the accurate physical parameters such as specific heat, thermal conductivity, latent heat of phase transformation and surface heat flux. The model for calculating H and Q is established in this paper. The measurement methods and data processing for physical parameters such as volume specific heat C, thermal conductivity k, volume latent heat of phase transformation c1 and surface heat flux are introduced The physical parameters of 1Cr18Ni9Ti and 45 steels and the surface heat flux for 1 Cr18Ni9Ti probe cooled in water,10% NaCl water and oil with different temperatures are measured, respectively. These data show that the probability of absolute error less than 2* C between the calculated and measured values in temperature field calculation reaches above 80% if using the above physical parameters, which provides a reliable technology basis for precise calculation of temperature field.

关键词: unsteady temperature field , null

APPLICATIONS OF PHYSICAL SIMULATION IN THE DEVELOPMENT OF HOT WORKING PROCESSES

L. P. Karjalainen (Department of Mechanical Engineering , University of Oulu , Oulu , Finland)

金属学报(英文版)

Modelling has become a more and more valuable tool in the design, control and development of steel processing. Empirical regression equations, physically based approachs, artificial neural networks and hybrid models are being theied in computer modelling. In all cases, relevant data are necessary, which can be most economically obtained by physical simulation. Physical simulation with a Gleeble simulator has been used in a large number of tasks at the University of Oulu for ten years in cooperotion with the Finnish metals industry. Some examples of these will be described and discussed below, such as the optimization of the recrystallization controlled rolling process, the improvement of the hot strength model for the control of coiling tension and the optimization of continuous strip annealing schedules.Finally,brief remarks will be then on a couple of projects now under way.

关键词: physical simulation , null , null , null , null

STRUCTURE AND PHYSICAL PROPERTIES OF SUBMICROCRYSTALLINE METALS PREPARED BY SEVERE PLASTIC DEFORMATION

R. R. Mulyukov and M. D. Starostenkov( 1) Institute for Metals Superplasticity Problems of Russian Academy of Sciences , Khalturina 39 , Ufa 450001 , Russia 2)Altai State Technical University)

金属学报(英文版)

The results of investigations of structure and physical properties of submicrocrystalline (SMC) metals are presented. The SMC structure was formed by severe plastic deformation.The structure was investi- gated by calorimetric and mossbauer measurements and TEW stuidies. The behavior of physical proper- ties of SMC metals were analysed taking into account spectific features of their structure.

关键词: submicrocrystal , null , null , null

PHYSICAL SIMULATION OF INTERFACIAL CONDITIONS IN HOT FORMING OF STEELS

Y. H. Li , M. Krzyzanowski , J. H. Beynon and C. M. Sellars IMMPETUS( Institute for Microstructural and Mechanical Process Engineering: The University of Sheffield , Sheffield SI 3JD , UK)

金属学报(英文版)

In the last few years,substantial experimental simulation and mumerical modelling hare been carried out in IMMPETUS to characterise the interfacial heat transfer and friction conditions during hot forging and rolling of steels. Emphasis has been placed on the influence of the oxide scale which forms on the steel workpiece. In the present paper, the experimental methods used for investigating interfacial heat transfer and friction conditions are described. Theses include hot flat rolling of steel slabs and hot axi- symmetric forging of steel cylinders and rings.Temperature measurements and computations demon- strate that for similar conditions, similar conditions, the effective interfacial heat transfer coefficients (IHTC) derived for hot rolling are significantly higher than those for forging, mainly due to the contribution of scale cracking during rolling. On the basis of experimental observations and numerical analysis,physical models for interfacial heat transfer in forging and rolling have been established. In addition, hot" sandwich" rolling and hot tensile tests with finite element modelling have been carried out to evaluate the hot ductility of the oxide scale.The results indicate that the defomation, cracking and decohesion behaviour of the oxide scale depend on deformation temperature, strain and relative strengths of the scale layer and scale - steel interface.Finaly, friction results from hot ring compression tests and from hot rolling with forward/backward slip measurements are reported.

关键词: interfacial heat transfer , null , null , null , null , null

STRUCTURES OF γ Al_2O_3 AND AlON STUDIED BY ~(27)Al NMR AND QUANTUM CHEMISTRY CALCTLATIONS

X.M.Min , Y. Daiand C.W.Nan National Key Laboratory of Advanced Technology for Materials Synthesis and Processing , Wuhan University ofTechnology , Wuhan 430070 , China

金属学报(英文版)

Al NMRand quantum chemistry calculation have been used to study thestructureof γ Al2O3 and AlON. The NMRspectra arecharacterized bythree distinctresonance peaksat114 , 66 and 12 , corresponding to 〔AlN4〕,〔AlO4〕and 〔AlO6〕respectively. The uantum chemistrycalculationsshowqd thatthe models with vacancieslocated at octahedralsitein B block are morestablethanthose with vacancieslocated attetrahedralsitein A blockforboth of γ Al2 O3 and AlON. In AlON, nitrogen atoms preferentially replace oxygen atoms in〔AlO4〕tetrahedrons, and the model with 〔AlN4〕is morestablethan that with 〔AlO4 xNx〕(x= 1 ,2 and 3) and 〔AlO6 - yNy〕(y= 1 ,2 ,3 and 4) , which isin agreement with theexperimental analysisby NMR.

关键词: Al2 O3 and AlON , null , null , null

Chemistry and Process Optimization of V-Microalloyed N80-Class Seamless Casing Tube

PAN Tao , YANG Cai-fu

钢铁研究学报(英文版)

Chemistry and process optimization of N80 seamless tube was studied by thermo-mechanical simulation tester Gleeble 1500D. Several heats of V-microalloyed steel with different N contents were firstly made at lab in order to simulate N80 seamless tube steel. The results showed that N addition increased strength under condition that toughness was kept at a high level compared with low-N steel. In this study N content with 120-200 ppm enhanced combination performance of strength and toughness whether in-line normalizing process was adopted or not. In-line normalizing process was helpful to improve the toughness though it lowered strength by some degree. However, direct final rolling after tandem rolling (without in-line normalizing) helped increase strength while the toughness remained somehow poor. The above phenomena concerning N80 seamless tube was closely associated with dissolution and precipitation behavior of V(CN). V(CN) precipitation was optimized when N content was increased. When in-line normalizing process was adopted, V(CN) precipitation in austenite increased due to low temperature history during intermediate (in-line) normalizing process. V(CN) particles existing in austenite contributed to grain refinement for VN induced intergranular ferrite, while they weakened precipitation strengthening effect since V precipitating in ferrite wais reduced.

关键词: seamless tube;in-line normalizing;V-N microalloying;reheating;mechanical properties;Gleeble simulation