材料期刊网

High Nitrogen Austenitic Stainless Steels Manufactured by Nitrogen Gas Alloying and Adding Nitrided Ferroalloys

LI Huabing , JIANG Zhouhua , SHEN Minghui , YOU Xiangmi

钢铁研究学报(英文版)

A simple and feasible method for the production of high nitrogen austenitic stainless steels involves nitrogen gas alloying and adding nitrided ferroalloys under normal atmospheric conditions. Alloying by nitrogen gas bubbling in FeCrMnMo series alloys was carried out in MoSi2 resistance furnace and air induction furnace under normal atmospheric conditions. The results showed that nitrogen alloying could be accelerated by increasing nitrogen gas flow rate, prolonging residence time of bubbles, increasing gas/molten steel interfaces, and decreasing the sulphur and oxygen contents in molten steel. Nitrogen content of 069% in 18Cr18Mn was obtained using air induction furnace by bubbling of nitrogen gas from porous plug. In addition, the nickelfree, high nitrogen austenitic stainless steels with sound and compact macrostructure had been produced in the laboratory using vacuum induction furnace and electroslag remelting furnace under nitrogen atmosphere by the addition of nitrided alloy with the maximum nitrogen content of 081%. Pores were observed in the ingots obtained by melting and casting in vacuum induction furnace with the addition of nitrided ferroalloys and under nitrogen atmosphere. After electroslag remelting of the cast ingots, they were all sound and were free of pores. The yield of nitrogen increased with the decrease of melting rate in the ESR process. Due to electroslag remelting under nitrogen atmosphere and the consequential addition of aluminum as deoxidizer to the slag, the loss of manganese decreased obviously. There existed mainly irregular Al2O3 inclusions and MnS inclusions in ESR ingots, and the size of most of the inclusions was less than 5 μm. After homogenization of the hot rolled plate at 1 150 ℃×1 h followed by water quenching, the microstructure consisted of homogeneous austenite.

关键词: nitrogen gas alloying;nitrided ferroalloy;high nitrogen austenitic stainless steel;vacuum induction melting;electroslag remelting

Studies of the g factors for the tetragonally elongated and compressed CuIIN6 octahedra in image omitted (MI = K, Rb, Cs; MII = Ca, Sr, Ba, Pb) crystals

Philosophical Magazine

The EPR g factors, g// and g perpendicular to, of tetragonally elongated and compressed CuIIN6 octahedral clusters (with the ground states |dx2 - y2 > and |dz2 >, respectively) in [image omitted] (MI = K, Rb, Cs; MII = Ca, Sr, Ba, Pb) crystals were calculated using a two-mechanism model. In the model, the contributions to the g-shifts, gi (= gi - gs, where i = // or perpendicular to; gs approximate to 2.0023 is the free-ion g value), from both the crystal-field (CF) mechanism related to CF excited states and the charge-transfer (CT) mechanism related to CT excited states, which is neglected in the widely-used CF theory, were considered. For the CF mechanism, two theoretical methods, the perturbation theory method (PTM) and the complete diagonalization (of energy matrix) method (CDM), were applied. The CF parameters used were calculated from the superposition model, in which the structural data for CuIIN6 clusters in [image omitted] crystals were measured exactly by X-ray diffraction. The calculated g factors for both the tetragonally elongated and compressed CuIIN6 octahedra are in reasonable agreement with the experimental values. For the strongly covalent CuIIN6 clusters in crystals with different ground states, both the PTM and CDM can be applied to calculate the g-shifts, [image omitted], arising from the CF mechanism, but exact and reasonable calculations of g factors should take both CF and CT mechanisms into account.

关键词: crystal field;electron paramagnetic resonance;octahedral cluster;charge transfer;spin-hamiltonian parameters;atomic screening constants;jahn-teller;distortion;temperature-dependence;lead hexanitrocuprate(ii);2-mechanism model;scf functions;br crystals;complexes;bands

Cu对MI(NiAlMnCoCu)5.1贮氢合金电化学性能的影响

林玉芳 , 李蓉 , 张羊换 , 陈梅艳 , 王新林

功能材料

研究了Cu含量对MINi3.9-xCoo.4 Al0.2 Mno.6Cux贮氢合金的电化学性能的影响.实验发现:随着Cu含量x从0增加至0.3,合金的活化性能仍保持在2～3次;但合金的最大放电容量从344mAh/g下降到310mAh/g;高倍率放电性能均在81%以上;合金的循环寿命随着Cu含量的增加而有所提高的.实验表明,合金中加入适量的Cu,可有效的改善舍金的循环寿命.

关键词: 贮氢合金 , Cu含量 , 电化学性能

Characteristics of multi-component MI-based hydrogen storage alloys and their hydride electrodes

稀有金属（英文版）

关键词:

金属有机骨架材料MI L-53对氯代甲烷的吸附?

王铭扬 , 田凤鸣 , 周林 , 张兴华 , 陈云琳

功能材料 doi:10.3969/j.issn.1001-9731.2016.05.011

采用水热法合成了金属-有机骨架材料 MIL-53(Al,Fe,Cr),并用 X射线衍射(XRD)、氮气吸/脱附等进行了测试表征.利用固定床吸附试验装置和气相色谱测定了在298 K,101 kPa 时,MIL-53(Al,Fe,Cr)对二氯甲烷、三氯甲烷的吸附情况.结果表明,二氯甲烷比三氯甲烷更易被MIL-53(Al,Fe,Cr)吸附,且 MIL-53(Al)对氯代甲烷的吸附能力最强,MIL-53(Cr)次之,MIL-53(Fe)最弱,MIL-53(Al)对二氯甲烷和三氯甲烷的吸附量最高分别可达16．88和7．11 mmol/g.实验结果与巨正则系综蒙特卡洛(GCMC)模拟结果一致.

关键词: 金属有机骨架 , MIL-5 3 , 吸附 , 氯代 , 挥发性有机物(VOCs)

Ni52MI24Ga24金属间化合物的单晶生长和磁性功能

陈京兰 , 胡凤霞 , 高书侠 , 王中 , 高智勇 , 赵连城 , 宫声凯 , 徐惠彬

金属学报

研究了Ni52Mn24Ga24合金单晶在磁场作用下能产生的目前最大的磁致伸缩应变.发现了该材料的双向相变应变效应以及磁场对此的增强现象在1.2 T磁场的作用下,可逆的相变应变达4%以上.实现这一结果的关键条件是马氏体变体的择优取向报道了获得马氏体变体的择优取向样品的单晶生长特性和后处理方法.根据前人报道的理论模型分析了实验结果,指出磁感生应变的物理机制是磁场提供的Zeeman能驱动变体间孪晶界的移动.

关键词: Ni52Mn24Ga24 , null , null

Ni52MI24Ga24金属间化合物的单晶生长和磁性功能

陈京兰 , 胡凤霞 , 高书侠 , 王中 , 高智勇 , 赵连城 , 宫声凯 , 徐惠彬

金属学报 doi:10.3321/j.issn:0412-1961.2001.04.004

研究了Ni52Mn24Ga24合金单晶在磁场作用下能产生的目前最大的磁致伸缩应变.发现了该材料的双向相变应变效应以及磁场对此的增强现象在1.2 T磁场的作用下,可逆的相变应变达4%以上.实现这一结果的关键条件是马氏体变体的择优取向报道了获得马氏体变体的择优取向样品的单晶生长特性和后处理方法.根据前人报道的理论模型分析了实验结果,指出磁感生应变的物理机制是磁场提供的Zeeman能驱动变体间孪晶界的移动.

关键词: Ni52Mn24Ga24 , 形状记忆 , 磁致伸缩

Effect of Pr content in Ml on the electrochemical properties of Ml(Ni-Co-Mn-Al)(5) alloys

Journal of Alloys and Compounds

The electrochemical properties of MINi(3.5)Co(0.8)Mn(0.4)Al(0.3) alloys with various Pr contents in MI were studied in this work, It was found that the Pr content in MI obviously affected the electrochemical properties of MI(Ni-Co-Mn-Al)(5) alloys. The electrochemical properties were greatly improved if the electrode alloy contained about 20 at.% Pr in MI. The electrode made from this alloy has a higher capacity, better discharge rate characteristics and longer cycle life than that from alloy with less than 10 at.% Pr in MI, as in common misch metal. The AA size cells in which electrode alloy contains about 17 at% Pr in MI are also studied. It was found that these cells have a very long cycle life (1400 cycles) with reasonable capacity (1250 mA h) and rate capability (1100 mAh) when discharged at 5 C). In particular, they have a very superior low temperature capability. For example, their capacity was higher than 1050 mA h when discharged at 1C and -18 degrees C.

关键词: Pr;Ml;electrochemical properties;Ml-Ni alloys;hydrogen batteries;electrodes;hydrides;storage;lani5

试验因素对LDPE熔融接枝AA影响的灰色系统分析

刘朝宗 , 任露泉 , 蒋蔓

高分子材料科学与工程

研究了丙烯酸(AA)作为接枝单体,过氧化二异丙苯(DCP)作为引发剂,与低密度聚乙烯(LDPE)混合,在单螺杆挤出机中进行熔融接枝反应,测定了LDPE-g-AA的熔融指数(MI)和表征接枝率的吸光比(R).用灰色系统理论的方法分析了试验因素,如AA、DCP及螺杆转速(r/min)对MI和R的关联度.结果表明,各因素对MI和R的影响程度是不同的,AA掺入量与MI有密切关系,而DCP加入量对MI影响程度较小.所考查的3个因素对接枝率的影响无明显差异,所得结果对高聚物的接枝改性有一定的指导意义.

关键词: 低密度聚乙烯 , 接枝 , 灰色系统

MECHANISM RESEARCH ON MECHANICS PROPERTIES’FLUCTUATION OF 67CrVA PATENTED SPRING STEEL WIRE

Z.T. Yang , X.Q. Xing , H.Y. Wang and S.L. Tao Departmentof Research and Design , Research Institute of Steel Wire and Wire Products , Zhengzhou 450007 , China

金属学报(英文版)

Advanced TEMand SEMexperimenteinstrumentshave been used to analysethe Φ4 5 m m , 67 CrVAspringsteel wire, which hasbeen patented underthe processof920℃×3 15 min + (500 ～600)℃×2 min. The mechanics properties’fluctuation and corresponding mi crostructure featuresof which havebeenstudied.

关键词: CrVAsteel wire , null , null