刘英
,
李元元
,
李卫
材料热处理学报
doi:10.3969/j.issn.1009-6264.2007.03.013
为研究ZE10镁合金的成形性能,在20～300℃条件下对ZE10镁合金板进行拉伸力学性能、锥杯及扩孔试验.结果表明:随着变形温度的升高,ZE10镁合金板的抗拉强度逐渐下降而伸长率、"拉深+胀形"复合成形性能、扩孔成形性能显著提高.200℃、250℃锥杯实验时,ZE10镁合金试样可顺利拉深进入锥杯凹模底部直圆孔而不出现开裂,具有较小的锥杯值;而300℃时反而增加,说明在200℃、250℃时ZE10镁合金具有最佳的拉胀复合成形性能.150℃、200℃扩孔试验时,试样中心φ10 mm预制孔可胀大到凸模直径φ25 mm大小,成功实现翻边(翻边系数为0.37),显示ZE10镁合金具有很好的扩孔成形性能.
关键词:
镁合金
,
"拉深+胀形"复合成形
,
扩孔成形
,
性能
刘悦
,
王忠军
,
金辉
,
周乐
稀有金属
采用光学显微镜、扫描电镜、盐水浸泡等方法研究了退火热处理工艺对Al/ZE42/Al复合板界面微观组织和该复合板在5.0％NaCl(质量分数)水溶液中腐蚀行为的影响.实验结果表明:Al/ZE42/Al复合板经退火处理后,界面区域发生Mg和Al等元素的互扩散,界面扩散层包含2个反应层,靠近ZE42镁合金一侧的反应层为Mg17Al12相,靠近Al板一侧的反应层为Al3Mg2相,随着退火温度的升高或者保温时间的延长,ZE42/Al界面扩散层的厚度增加,ZE42镁合金发生了再结晶组织转变;退火热处理没有明显改善Al/ZE42/Al复合板的耐腐蚀性能,提高了腐蚀速率,其腐蚀机制为复合板边部向内部扩散而导致的电偶腐蚀加剧.
关键词:
ZE42
,
Al
,
界面
,
退火
,
腐蚀
机械工程材料
对挤压态ZE10镁合金在300～400℃及应变速率10-4～10-2s-1条件下进行了超塑性拉伸试验研究.结果表明:晶粒约为5μm的ZE10镁合金挤压材,在350℃及应变速率为4.80×10-3s-1条件下即可获得330%的较大伸长率,在5.55×10-4s-1应变速率下,可获得364%的最大伸长率.在350℃以应变速率4.80×10-3s-1拉伸,在变形初始阶段伸长量为50%时,合金的晶粒尺寸为2.8μm,当试样拉伸至断裂时,晶粒尺寸为4.2μm.说明在变形过程中具有动态再结晶的发生,而且晶粒长大趋势较小.试样拉断时,断口具有典型的空洞形貌特征.
关键词:
ZE10镁合金
,
超塑性
,
组织性能
张志巍
,
李敏霞
,
马一太
工程热物理学报
在实验数据基础上,建立了适用于HFC32/HFO1234ze二元混合工质的PR方程模型,并对实验数据、模型计算结果和Refprop 9.0计算结果进行了比较分析;作出了定温度下泡、露点压力随混合比的变化关系图以及定压力下饱和温度随混合比的变化关系图,分析得出HFC32/HFO1234ze二元混合工质属于非共沸工质,存在温度滑移,500 kPa压力下混合物在0.27/0.75处温度滑移达到最大为12.7℃;选取状态参考点后,作出了不同混合比下的混合工质的logP-h图,得出了随混合比变化混合工质的热力学性质的变化趋势,为系统的设计提供基本的热力学数据;最后,以R410A循环性能为基准,对不同混合比下混合工质的“相对循环性能”(COPmix/COPR410A)进行了分析,为家用空调制冷剂的替代和系统的优化提供方向.
关键词:
HFC32/HFO1234ze
,
混合工质
,
PR方程模型
,
热物性
,
循环性能
宾远红
,
刘英
,
李卫
,
郑洋
电镀与涂饰
采用含硅酸钠14g/LK、氟化钠14g/L、氢氧化钠2g/L和甘油5 mL/L的电解液,以微弧氧化技术在ZE10镁合金的表面成功制备了微弧氧化膜.采用涡流测厚仪、扫描电镜、X射线衍射、电化学工作站等,研究了电压和时间对镁合金微弧氧化膜的厚度、表面形貌和耐蚀性的影响.结果表明,微弧氧化膜层主要由MgO、MgF2和Mg2SiO4及少量非晶态物质组成.随着电压的增大,膜层不断增厚.随着氧化时间的延长,膜厚迅速增加,20 min后膜层厚度基本稳定.微弧氧化膜的耐蚀性随着电压的增大和时间的延长均呈现先增强后降低的趋势.脉冲占空比和频率对膜层的耐蚀性也有一定的影响.
关键词:
镁合金
,
微弧氧化
,
硅酸盐
,
耐蚀性
王忠军
,
范明达
,
朱晶
,
李胜利
,
赵晖
,
杨庆祥
稀有金属
doi:10.3969/j.issn.0258-7076.2012.04.025
采用光学显微镜和TEM观察等方法,分析了ZE42镁合金热挤压板材在不同退火温度和时间条件下的显微组织结构.结果表明:该合金板材经过退火热处理后均发生明显的再结晶组织转变,晶粒尺寸在10 ～60μm之间,合金基体中存在大量含有稀土元素的第二相颗粒,这些第二相在热变形过程中破碎成细小的颗粒,促进了再结晶晶粒的形核.当退火温度一定时,随着保温时间的延长,该合金板材的平均晶粒尺寸首先增加,随后少量减小,最后又随退火时间的增加而增加；当保温时间一定时,随着退火温度的增加,晶粒平均尺寸持续增加,并且温度越高,增长速率越大.同时,通过晶粒长大动力学分析和计算建立了该合金再结晶晶粒长大的动力学模型,通过计算可知:该合金的再结晶晶界迁移激活能为15.32 kJ·mol-1.
关键词:
ZE42
,
镁合金
,
显微组织
,
性能
,
退火
Nuclear Engineering and Design
Liquid droplet erosion (LDE), which often occurs in bellows made of nickel-based alloys, threatens the security operation of the nuclear power plant. As the candidate materials of the bellows, Inconel 600 and Inconel 625 were both tested for resistance to cavitation erosion (CE) and jet impingement erosion (JIE) through vibratory cavitation equipment and a jet apparatus for erosion-corrosion. Cumulative mass loss vs. exposure time was used to evaluate the erosion rate of the two alloys. The surface and cross-sectional morphologies before and after the erosion tests were observed by scanning electron microscopy (SEM), the inclusions were analyzed by an energy dispersive spectroscopy (EDS), and the surface roughness was also measured by surface roughness tester to illustrate the evolution of erosion process. The results show that the cumulative mass loss of CE of Inconel 625 is about 1/6 that of Inconel 600 and the CE incubation period of the Inconel 625 is 4 times as long as that of the Inconel 600. The micro-morphology evolution of CE process illustrates that the twinning and hardness of the Inconel 625 plays a significant role in CE. In addition, the cumulative mass loss of JIE of Inconel 625 is about 2/3 that of Inconel 600 at impacting angle of 90 degrees, and almost equal to that of the Inconel 600 at impacting angle of 30 degrees. Overall, the resistance to CE and JIE of Inconel 625 is much superior to that of Inconel 600. (C) 2010 Elsevier By. All rights reserved.
关键词:
stress-corrosion cracking;aluminide intermetallic alloys;high-purity;water;mechanical-properties;crevice corrosion;solid particles;wear;behavior;microstructure;deformation;steam
庄厚龙
,
彭平
,
周惦武
,
刘金水
稀有金属材料与工程
采用第一原理赝势平面波方法--CASTEP程序计算了4种B2型Y基金属间化合物YX(X=Ag,Cu,In,Rh)的部分弹性性质,计算结果与文献报道值基本一致.通过Pugh定律、Cauchy压力和泊松比等经验判据,分析并预测了它们的脆性/延性,其延性高低次序为:YRh＞YAg＞YCu＞YIn.电子结构分析表明:这4种金属间化合物良好的延性源于其较强的金属键,而不同程度的Y(d)-X(p)电子杂化则导致了其延性的差异.YIn中因In的p电子较多,杂化程度高,共价键方向性强,因而延展性最低,而YRh则由于存在Y(d)-Rh(d)电子间强的相互作用,增强了其金属键作用,因而延性最好.
关键词:
Y基金属间化合物
,
脆性/延性
,
第一原理
,
电子结构
Nuclear Engineering and Design
A composite coating was deposited on Inconel 600 substrate by cold spray method using pure Ni powder (60 wt.%) blended with alpha-Al(2)O(3) (40 wt.%) as feedstock. It is expected to be applied to repair the bellows eroded by the liquid droplet erosion (LDE). Microstructure of the coating was observed using optical microscope (OM) and scanning electron microscopy (SEM). Microhardness of the coating was determined by Vickers hardness tester. Cavitation erosion (CE) experiments were carried out in the distilled water. Jet impingement erosion (JIE) experiments were performed in slurry containing 1 wt.% quartz particle with the flow velocity of 15 m/s at impingement angles of 30 degrees, 60 degrees and 90 degrees, respectively. Cumulative mass loss vs. testing time was used to evaluate the erosion rate of the coating. The erosion mechanism was analyzed by OM, SEM, X-ray diffraction (XRD) and the microhardness measurement. The results show that the composite coating has compact microstructure and relatively high hardness. The resistance to CE of the coating is not as good as that of Inconel 600 substrate due to the weak bonds of the Al(2)O(3) particles. However, the results of the JIE test indicate that the slurry erosion resistance of the coating is better than that of Inconel 600 at the impact angles of 30 degrees and 60 degrees, but not at the normal impact angle. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
large powder particles;composite coatings;slurry erosion;kinetic;spray;liquid impact;alloy;microstructure;steels;deposition;resistance
