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RELATIONSHIP BETWEEN FRACTAL DIMENSION AND CYCLIC CREEP PROPERTIES OF ROTOR STEEL 34CrMoA

YI Jianzhang Shenyang Institute of Aeronautical Engineering , Shenyang , ChinaYANG Zhi'an ZHU Shijie WANG Zhongguang Institute of Metal Research , Academia Sinica , Shenyang , China lecturer , Department of Safety Engineering , Shenyang Institute of Aeronautical Engineering , Shenyang 110031 , China

金属学报(英文版)

Vertical section method has been used to measure the fractal dimension of cyclic creep frac- ture surfaces of rotor steel 34CrMoA at 550℃.The relationship between fractal dimension and cyclic creep properties has been analyzed.The fractal dimension is dependent upon the power product of minimum creep rate and rupture time,and satisfies the linear function with rupture strain.

关键词: cyclic creep , null , null , null

Image analysis of periodic rain accelerated corrosion of aeronautical aluminium alloys

Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing

Periodic rain tests have been carried out for simulating atmospheric corrosion of aeronautical aluminium alloys. A digital image preprocessing and analysis method based on wavelet transformation was used to study the corrosion morphology of aluminium alloys samples, through which an image feature parameter 8 was extracted and discussed. The influences of orthogonal experiment parameters on acceleration were analyzed according to image feature parameter 6 with analysis of variance (ANOVA) method, and the optimal parameters for accelerated corrosion test were also obtained. The result was shown to be consistent with that from weight loss method. (c) 2007 Elsevier B.V. All rights reserved.

关键词: aeronautical aluminium alloys;accelerated corrosion;linage analysis;simulated environment;atmospheric corrosion;electrochemical impedance;pitting corrosion;exposure;steel;zinc

The effect of environmental variables on atmospheric corrosion of carbon steel in Shenyang

Chinese Science Bulletin

A study was carried out in order to investigate the effect of contaminants and meteorological variables on the rust layer of carbon steel exposed in Shenyang urban atmosphere. Seven kinds of contaminants and twelve kinds of meteorological parameters were also registered in order to correlate the data with respect to corrosion rate and the stepwise multiple regression analysis was carried out in order to obtain the best regression model. The sum of rainfall time as well as sunshine time and the concentration of H(2)S could stimulate initial atmospheric corrosion of carbon steel. The initial atmospheric corrosion kinetics of carbon steel was observed to follow the cubic equation. The corrosion products were analyzed by XRD and the transformation of phases in different periods was discussed.

关键词: contaminants;meteorological parameters;carbon steel;urban atmospheric;corrosion;stepwise multiple regression;corrosion products;rust;pollution

Service Performance of Engineering Materials

Andrej Atrens

材料科学技术(英文)

Corrosion research by Atrens and co-workers has made significant contributions to the understanding of the service performance of engineering materials. This includes: (1) elucidated corrosion mechanisms of Mg alloys, stainless steels and Cu alloys, (2) developed an improved understanding of passivity in stainless steels and binary alloys such as Fe-Cr, Ni-Cr, Co-Cr, Fe-Ti, and Fe-Si, (3) developed an improved understanding of the melt spinning of Cu alloys, and (4) elucidated mechanisms of environment assisted fracture (EAF) of steels and Zr alloys. This paper summarises contributions in the following: (1) intergranular stress corrosion cracking of pipeline steels, (2) atmospheric corrosion and patination of Cu, (3) corrosion of Mg alloys, and (4) transgranular stress corrosion cracking of rock bolts.

关键词: Stress corrosion cracking , null , null

0℃时YI3-C6H12N4·HI-H2O的相图及YI3·C6H12N4·HI·14H2O的合成与表征

王丽 , 吴希文 , 张晨鼎 , 张通 , 简丽 , 武朝军 , 周涛

稀土 doi:10.3969/j.issn.1004-0277.1999.02.003

采用湿渣法研究了0℃时碘化钇(YI3)-乌洛托品氢碘酸盐(C6H12N4.HI)-水(H2O)的三元体系相平衡,绘制了该体系的等温溶解度相图,相图分析结果表明,该体系中有组成为YI3.C6H12N4.HI.14H2O的配合物生成,对所得配合物进行了化学分析、X-射线粉末衍射、红外光谱、差热-热重分析,测定了其密度、晶体轴性,确定了配合物结构中的配位关系.

关键词: 相平衡 , 碘化钇 , 乌洛托品氢碘酸盐 , 配合物

Biomimicry of bamboo bast fiber with engineering composite materials

Materials Science & Engineering C-Biomimetic Materials Sensors and Systems

Bamboo, one of the strongest natural structural composite materials, has many distinguishing features. It has been found that its reinforcement unit, hollow, multilayered and spirally-wound bast fiber, plays an extremely important role in its mechanical behavior. In the present work, on the basis of the study on bamboo bast fiber and wood tracheid, a biomimetic model of the reinforcing element, composed of two layers of helically wound fiber, was suggested. To detect the structural characteristics of such a microstructure, four types of macro fiber specimens made of engineering composites were employed: axially aligned solid and hollow cylinders, and single- and double-helical hollow cylinders. These specimens were subjected to several possible loadings, and the experimental results reveal that only the double-helical structural unit possesses the optimum comprehensive mechanical properties. An interlaminar transition zone model imitating bamboo bast fiber was proposed and was verified by engineering composite materials. In our work, the transition zone can increase the interlaminar shear strength of the composite materials by about 15%. These biomimetic structural models can be applied in the design and manufacture of engineering composite materials.

关键词: bamboo;bast fiber;biomimetics;engineering composites

Strengthening Materials by Engineering Coherent Internal Boundaries at the Nanoscale

Science

Strengthening materials traditionally involves the controlled creation of internal defects and boundaries so as to obstruct dislocation motion. Such strategies invariably compromise ductility, the ability of the material to deform, stretch, or change shape permanently without breaking. Here, we outline an approach to optimize strength and ductility by identifying three essential structural characteristics for boundaries: coherency with surrounding matrix, thermal and mechanical stability, and smallest feature size finer than 100 nanometers. We assess current understanding of strengthening and propose a methodology for engineering coherent, nanoscale internal boundaries, specifically those involving nanoscale twin boundaries. Additionally, we discuss perspectives on strengthening and preserving ductility, along with potential applications for improving failure tolerance, electrical conductivity, and resistance to electromigration.

关键词: strain-rate sensitivity;stacking-fault energy;nano-scale twins;cu-al;alloys;nanocrystalline metals;mechanical-properties;activation;volume;copper;deformation;behavior

Crystal facet engineering of semiconductor photocatalysts: motivations, advances and unique properties

Chemical Communications

Crystal facet engineering of semiconductors has become an important strategy for fine-tuning the physicochemical properties and thus optimizing the reactivity and selectivity of photocatalysts. In this review, we present the basic strategies for crystal facet engineering of photocatalysts and describe the recent advances in synthesizing faceted photocatalysts, in particular TiO(2) crystals. The unique properties of faceted photocatalysts are discussed in relation to anisotropic corrosion, interaction dependence of adsorbates, photocatalytic selectivity, photo-reduction and oxidation sites, and photocatalytic reaction order. Ideas for future research on crystal facet engineering for improving the performance of photocatalysts are also proposed.

关键词: shape-controlled synthesis;exposed 001 facets;rutile tio2 nanorods;visible-light photocatalysis;solvent-solute interactions;anatase;titanium(iv) oxide;low-temperature synthesis;ordered solid-phases;platinum nanocrystals;hydrogen-production

Study on compression behavior of porous magnesium used as bone tissue engineering scaffolds

Biomedical Materials

In this work, porous magnesium (Mg) with a three-dimensional open-cellular structure, potentially employed as bone tissue engineering scaffolds, was fabricated by the mechanical perforation method. The influences of porosity, pore size and pore arrangement on compressive behavior and the anisotropy of new porous Mg were analyzed theoretically using orthogonal arrays and the finite element method (FEM). The results showed that the parameters of porosity, pore size and pore arrangement had different effects on the compressive properties. The compressive strength could be improved by optimizing these parameters. The anisotropy of porous Mg was also verified in this study. The theoretical results showed good agreement with the experimental ones before the strain reaches 0.038.

关键词: unidirectional solidification;pore-size;hydroxyapatite;replacement;cartilage;porosity;matrix

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