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Microstructure Evolving Behaviors of Undercooled Ultrafine Austenite Grains During Deformation

YAO Shengjie , DU Linxiu , LI Guanglong , JIAO Xing , WANG Guodong

钢铁研究学报(英文版)

Samples with ultrafine grained austenite were prepared by repetitive rapid heating and quenching for three times and were used to investigate the dynamic microstructural evolving behaviors at different temperatures. A simultaneous development of dynamic straininduced transformation (DSIT) and austenite grain growth was detected at the deformation temperatures above Ar3, while only DSIT happened as the deformation proceeded at lower temperatures close to and below Ar3. In addition, a reverse ferritetoaustenite transformation was also observed. Most of the straininduced ferrite nucleated on the boundaries of ultrafine prior austenite grains, especially at the corners and no evidence about intragranular nucleus was obviously obtained.

关键词: ultrafine grained austenite , ferrite , dynamic straininduced transformation (DSIT) , grain growth

Effect of WarmRolled Pearlite Microstructural Features on Austenitic Transformation

YAO Shengjie , DU Linxiu , LIU Xianghua , WANG Guodong

钢铁研究学报(英文版)

The austenite transformation characteristics for various warmrolled pearlite during rapid heating were investigated. The results indicate that the start temperature (Ts) is sensitive to the microstructural feature of pearlite, whereas the dislocation plays an important role in the transformation rate; at the same time, the uniformity of austenite grains is more or less affected by the amount of spheroidized pearlite. A critical effect on the state of austenite grain is created through the influence of initial microstructures on the start temperature of transformation.

关键词: warm rolling;pearlite;dislocation;austenite;transformation

Pulsed laser deposition of aluminate YAlO3 and LaAlO3 thin films for alternative gate dielectric applications

Applied Physics a-Materials Science & Processing

Amorphous aluminate YAlO3 (YAO) thin films on n-type silicon wafers as gate dielectric layers of metal - oxide semiconductor devices are prepared by pulsed laser deposition. As a comparison, amorphous aluminate LaAlO3 (LAO) thin films are also prepared. The structural and electrical characterization shows that the as-prepared YAO films remain amorphous until 900 degrees C and the dielectric constant is similar to 14. The measured leakage current of less than 10(-3) A/cm(2) at a bias of V-G = 1.0 V for similar to 40-nm-thick YAO and LAO films obeys the Fowler Nordheim tunneling mechanism. It is revealed that the electrical property can be significantly affected by the oxygen pressure during deposition and post rapid thermal annealing, which may change the fixed negative charge density at the gate interface.

关键词: hafnium oxide;si;stability;silicon;transition;dioxide;devices;hfo2

Comparison of Inconel 625 and Inconel 600 in resistance to cavitation erosion and jet impingement erosion

Nuclear Engineering and Design

Liquid droplet erosion (LDE), which often occurs in bellows made of nickel-based alloys, threatens the security operation of the nuclear power plant. As the candidate materials of the bellows, Inconel 600 and Inconel 625 were both tested for resistance to cavitation erosion (CE) and jet impingement erosion (JIE) through vibratory cavitation equipment and a jet apparatus for erosion-corrosion. Cumulative mass loss vs. exposure time was used to evaluate the erosion rate of the two alloys. The surface and cross-sectional morphologies before and after the erosion tests were observed by scanning electron microscopy (SEM), the inclusions were analyzed by an energy dispersive spectroscopy (EDS), and the surface roughness was also measured by surface roughness tester to illustrate the evolution of erosion process. The results show that the cumulative mass loss of CE of Inconel 625 is about 1/6 that of Inconel 600 and the CE incubation period of the Inconel 625 is 4 times as long as that of the Inconel 600. The micro-morphology evolution of CE process illustrates that the twinning and hardness of the Inconel 625 plays a significant role in CE. In addition, the cumulative mass loss of JIE of Inconel 625 is about 2/3 that of Inconel 600 at impacting angle of 90 degrees, and almost equal to that of the Inconel 600 at impacting angle of 30 degrees. Overall, the resistance to CE and JIE of Inconel 625 is much superior to that of Inconel 600. (C) 2010 Elsevier By. All rights reserved.

关键词: stress-corrosion cracking;aluminide intermetallic alloys;high-purity;water;mechanical-properties;crevice corrosion;solid particles;wear;behavior;microstructure;deformation;steam

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

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Cavitation erosion and jet impingement erosion mechanism of cold sprayed Ni-Al(2)O(3) coating

Nuclear Engineering and Design

A composite coating was deposited on Inconel 600 substrate by cold spray method using pure Ni powder (60 wt.%) blended with alpha-Al(2)O(3) (40 wt.%) as feedstock. It is expected to be applied to repair the bellows eroded by the liquid droplet erosion (LDE). Microstructure of the coating was observed using optical microscope (OM) and scanning electron microscopy (SEM). Microhardness of the coating was determined by Vickers hardness tester. Cavitation erosion (CE) experiments were carried out in the distilled water. Jet impingement erosion (JIE) experiments were performed in slurry containing 1 wt.% quartz particle with the flow velocity of 15 m/s at impingement angles of 30 degrees, 60 degrees and 90 degrees, respectively. Cumulative mass loss vs. testing time was used to evaluate the erosion rate of the coating. The erosion mechanism was analyzed by OM, SEM, X-ray diffraction (XRD) and the microhardness measurement. The results show that the composite coating has compact microstructure and relatively high hardness. The resistance to CE of the coating is not as good as that of Inconel 600 substrate due to the weak bonds of the Al(2)O(3) particles. However, the results of the JIE test indicate that the slurry erosion resistance of the coating is better than that of Inconel 600 at the impact angles of 30 degrees and 60 degrees, but not at the normal impact angle. (C) 2011 Elsevier B.V. All rights reserved.

关键词: large powder particles;composite coatings;slurry erosion;kinetic;spray;liquid impact;alloy;microstructure;steels;deposition;resistance

Hardness of T-carbon: Density functional theory calculations

Physical Review B

We reconsider and interpret the mechanical properties of the recently proposed allotrope of carbon, T-carbon [Sheng et al., Phys. Rev. Lett. 106, 155703 (2011)], using density functional theory in combination with different empirical hardness models. In contrast with the early estimation based on Gao et al.'s model, which attributes to T-carbon a high Vickers hardness of 61 GPa comparable to that of superhard cubic boron nitride (c-BN), we find that T-carbon is not a superhard material, since its Vickers hardness does not exceed 10 GPa. Besides providing clear evidence for the absence of superhardness in T-carbon, we discuss the physical reasons behind the failure of Gao et al.'s and Simunek and Vackar's (SV) models in predicting the hardness of T-carbon, residing in their improper treatment of the highly anisotropic distribution of quasi-sp(3)-like C-C hybrids. A possible remedy for the Gao et al. and SV models based on the concept of the superatom is suggested, which indeed yields a Vickers hardness of about 8 GPa.

关键词: superhard rhenium diboride;elastic-constants;ambient-pressure;metal;borides;crystals;diamond;search;boron

(1-x)Bi4Ti3O12-xSrBi2Nb2O9铋层状铁电陶瓷结构与性能研究

涂娜 , 江向平 , 李小红 , 傅小龙 , 杨帆

人工晶体学报

采用传统固相法制备了(1-x)Bi4Ti3 O12-xSrBi2 Nb2 O9(BIT-SBN,x=0,0.025,0.050,0.100,0.150,0.200)铋层状无铅压电陶瓷.系统研究了SrBi2 Nb2 O9掺杂对Bi4Ti3 O12基陶瓷物相结构、微观结构以及jie电性能的影响.结果表明:所有陶瓷样品均为单一的铋层状结构;当SBN掺量为0.100时,样品具有最佳的电性能:d33=21 pC/N,相对密度ρ =98.1%,机电耦合系数kp=8.26%,εr=220,介电损耗tanδ =0.29%,剩余极化强度Pr=9.128 μC/cm2,Tc=594℃.同时,SBN的引入增强了样品的抗老化性和热稳定性.

关键词: Bi4Ti3O12 , SrBi2Nb2O9 , 铋层状 , 铁电陶瓷 , 介电性能

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