YANG Gang
,
YANG Mu-xin
,
LIU Zheng-dong
,
WANG Chang
钢铁研究学报(英文版)
Commercial pure iron billets having diameter of 60 mm and length of 180 mm were subjected to equal channel angular pressing (ECAP) at 350 ℃ for 1 to 4 passes via route Bc. Microstructural evolutions on three planes (X, Y, Z planes) were characterized by optical microscopy and transmission electron microscopy (TEM). It was found that after four passes an ultrafine microstructure could be formed on the X plane, but a band structure remained on the Z plane. Accordingly, the mechanical properties exhibited apparent dependence on the orientations. The strength in the x and y directions was higher than that in the z direction. The microstructural refinement and mechanical properties were discussed in terms of experimental results.
关键词:
iron
,
ECAP
,
UFG
,
microstructure
,
mechanical property
常永勤
,
介万奇
,
郭喜平
,
陈福义
,
安卫军
功能材料
研究了ACRT-B法生长的Mn0.1Cd0.9In2Te4晶体中界面的形状和各组元沿轴向的分布规律及其分凝因数.发现结晶界面为椭球形;采用理想配比生长MnxCd1-xIn2Te4晶体,其4种组元并不按(Mn,Cd):In:Te=1:2:4比例结晶,而是要重新分布;通过数学方法处理实验数据得到Mn,Cd和In的分凝因数在α相区分别为1.286、1.9257和0.7294,在β相区则分别为1.12、1.055和0.985.
关键词:
ACRT-B法
,
MnxCd1-x In2Te4
,
界面
,
分凝因数
Journal of Materials Science
The response of mu phase to applied stress and long-term thermal exposure has been investigated in the cast Ni-base superalloy K446. It is found that during stress rupture, the applied stress accelerates the precipitation and growth of mu phase. However, during thermal exposure the mu phase precipitating in the form of needles and granules experiences a complicated evolution. The needles, fiber- or sheet-shaped in three-dimension, align very regularly during exposure, either lying in three directions with an acute angle to one another or in two directions perpendicular to each other, the mechanisms of which are characterized in detail. In addition, it is concluded that an excessive precipitation of mu phase severely degrades the mechanical properties of the alloy, whereas its evolution behavior during thermal exposure is determined to have an insignificant influence on the properties.
关键词:
single-crystal superalloy;thermal exposure;precipitation;stability;rupture;stress
常永勤
,
安卫军
,
郭喜平
,
介万奇
无机材料学报
采用Bridgman法生长了x为0.1,0.22和0.4的四元稀磁半导体化合物MnxCd1-xIn2Te4晶体.研究了三根晶体中相的形貌、结构、成分和Mn0.1Cd0.9In2Te4晶体中各组元沿轴向和径向的成分分布.晶体生长初始端的组织为α+β+β1,随着生长的进行,形成β相的单相区.在晶锭末端,形成In2Te3类面心立方结构化合物.组分x增大后,MnxCd1-xIn2Te4晶体的吸收边向短波方向移动,禁带宽度则线性增大.磁化率测量结果表明:晶体在高温区的x-1-T曲线服从居里-外斯定律,在低温区(<50K)则表现出顺磁增强现象.
关键词:
MnxCd1-xIn2Te4
,
compositional distribution
,
infrared transmission spectra
,
mag- netic susceptibility
常永勤
,
安卫军
,
郭喜平
,
介万奇
无机材料学报
doi:10.3321/j.issn:1000-324X.2003.02.004
采用Bridgman法生长了x为0.1,0.22和0.4的四元稀磁半导体化合物MnxCd1-xIn2Te4晶体.研究了三根晶体中相的形貌、结构、成分和Mno.1Cd0.9In2Te4晶体中各组元沿轴向和径向的成分分布.晶体生长初始端的组织为α+β+β1,随着生长的进行,形成β相的单相区.在晶锭末端,形成In2Te3类面心立方结构化合物.组分x增大后,MnxCd1-xIn2Te4晶体的吸收边向短波方向移动,禁带宽度则线性增大.磁化率测量结果表明:晶体在高温区的x-1-T曲线服从居里一外斯定律,在低温区(＜50K)则表现出顺磁增强现象.
关键词:
MnxCd1-xIn2Te4
,
成分偏析
,
红外透射光谱
,
磁化率
Journal of Alloys and Compounds
Precipitation behavior of a topologically close packed (TCP) mu phase as well as its role during the creep deformation in single crystal superalloy CMSX-4 have been investigated. The mu particles nucleated and grew based on low index planes of both the mu phase ({11 (2) over bar 0} and {1 0 (1) over bar0}) and the matrix ({110}, {001} or {111} and {112}) by epitaxial growth toward < 0001 >(mu) or < 110 >gamma directions, which predominantly resulted in a rod-like morphology. Interestingly, composition of these rod-like mu particles varied with the ratio of Ni/(W + Re) due to the different diffusion rates of these elements in the matrix during thermal exposure. Moreover, the gamma' evolution played an important role in the precipitation behavior and the fracture behavior of the mu phase. The rod-like mu particles were not fractured by stress concentration, as they were surrounded by the gamma' envelope. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
Nickel-base single crystal superalloy;Topologically close packed phase;Thermal exposure;Creep;nickel-base superalloys;ni;deformation;microstructure;mechanisms;diffusion;exposure;fatigue;design;damage
Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing
The role of mu phase in a second generation directionally solidified Ni-base superalloy during high temperature creep has been characterized in the present work. A large amount of blocky mu phase enveloped by thick gamma'-film is found at the grain boundaries and in the vicinity of primary MC carbides after heat treatment. However, the creep-rupture properties of the alloy are not affected by the presence of the blocky p, phase at 760-1070 degrees C under a stress of 120-850 MPa. By the investigation of creep microstructure at 975 degrees C/255 MPa, it is found that the thick gamma'-film plays a pivotal role in toughening the grain boundaries and the interfaces between the mu phase (or carbides) particles and the matrix, and preventing the formation of cracks. Meanwhile, during high temperature creep, M(23)C(6) carbides are continuously coarsening with the dissolution of the p. phase particles and MC carbides, especially at the grain boundaries. The poor interface cohesion strength between such large M(23)C(6) carbides and the gamma matrix at the vertical segments of the directionally solidified grain boundaries leads to the final creep failure of the present alloy. (C) 2010 Elsevier B.V. All rights reserved.
关键词:
mu phase;Directionally solidified Ni-base superalloy;Creep;Carbide;Grain boundaries;precipitation
Journal of Physics D-Applied Physics
B-doped ZnO thin films were observed to have a lateral laser-induced photovoltaic effect: the saturation value varied very linearly with the 10.6 mu m constant laser spot position between the electrodes on the ZnO surface. It was found that the temperature gradient in the direction of electron transfer (along the film surface) due to the laser spot causes this photovoltage signal to be linearly dependent on the position of the laser spot in this isotropic system. This linearity is expected to make ZnO a candidate for position-sensitive photodetectors.
关键词:
ultraviolet photodetectors
