李瑛
,
Y.BABA
,
T.SEKIGUCHI
中国腐蚀与防护学报
利用同步辐射光电子能谱(SR-XPS)原位研究了经3 keV O2溅射的SUS 304不锈钢中Fe、Ni、Cr合金元素与氧离子的化学反应活性差异及一种金属元素间的相互作用规律。经低能氧离子溅射后，不锈钢表面形成了一薄层氧化物膜，元素Cr和Ni分别以Cr2O3和NiO形式存在；铁元素的氧化产物随离子溅射量的增加分别以FeO、FeO和Fe2O3共存、全部生成Fe2O3的形式存在。在SUS 304职不锈钢中，铬元素与氧离子的化合能力最强，铁元素次之，镍元素的化合能力较弱。同纯金属与氧离子的化合行为比较发现：三种金属元素合金化后，铁、铬元素与氧离子的化合能力提高，而镍元素的氧化速度降低。氧化过程中铁元素与镍元素间存在相互作用，只有当铁元素与氧离子反应生成Fe2O3后，镍元素才开始氧化。
关键词:
氧离子
,
oxidation behavior
,
saainless steel
,
O2+ ion
,
SR-XPS
LUO Meiqing CHEN Nianyi Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
ChinaYU Zhizhong Shanghai Institute of Testing Technics
,
Shanghai
,
ChianNING Yuantao ZHOU Xinming Kunming Institute of Precious Metals
,
Kunming
,
China CHEN Nianyi
,
Professor
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai 200050
,
China
金属学报(英文版)
The electronic structure of Pd-Y-Si glass has been investigated by ESCA and quantum chem- ical calculation.It was found that the valence electrons of Y transferred to Si atoms in this metallic glass,forming polar covalent bonds.Perhaps these strong covalent bonds link Si and Y atoms to form clusters that hinder the process of crystallization.
关键词:
Pd-Y-Si glass
,
null
,
null
,
null
LI Laifeng XING Zhongshu Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
China XING Zhongshu
,
professor
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
China
金属学报(英文版)
The solubilities of Ce,Nd and Y in α-Fe at 873 to 1153 K have been deter mined by means of electron microprobe quantitative analyses.The temperature dependences of the solubilities were obtained from the experimental data.The results have been compared with those deter- mined by three other technigues,very good agreement was obtained between the results of all these techniques.
关键词:
α-Fe
,
null
,
null
,
null
,
null
翟庆洲
,
蔡建岩
,
于淼
稀有金属材料与工程
以沸石Y及以甲基三甲氧基硅烷对沸石Y进行表面改性后的Y(m)沸石作主体,用离子交换法制备Cd-Y及Cd-Y(m)样品,然后以硫代乙酰胺取代有毒的硫化氢作硫源,水热法制备Y-CdS及Y(m)-CdS主-客体纳米复合材料.利用粉末XRD、化学分析、红外光谱、固体扩散漫反射吸收光谱、发光研究对制备的样品进行了表征.化学分析表明,CdS已进入沸石Y(Ym)主体中;XRD结果表明,CdS进入沸石Y(Ym)后,制得的复合材料沸石骨架仍然存在,且保持高度有序性,不改变骨架的长程有序性;红外光谱结果表明,在所制备的Y-CdS及Y(m)-CdS样品中,有Si-O-Cd新键生成;固体扩散漫反射吸收光谱结果表明,沸石Y和Y(m)对可见光基本无吸收,Y-CdS和Y(m)-CdS吸收无明显差别;组装CdS后,Y-CdS及Y(m)-CdS产生发光现象.所制得的Y-CdS及Y(m)-CdS主-客体纳米复合材料具有作为发光材料的潜在性.
关键词:
Y沸石
,
Y改性沸石
,
甲基三甲氧基硅烷
,
纳米CdS
,
主-客体纳米复合材料
,
表征
D.Q. Wan
,
G.C. Yang
金属学报(英文版)
The microstructure formation and mechanical property involving icosahedral quasicrystal (I-phase) in the Y-rich Mg-Zn-Y alloy have been studied. The equilibrium formation of I-phase from the Y-rich Mg-Zn-Y melt is through a peritectic reaction between the Y-rich melt and the primary W-phase, which is discussed in detail. The independent nucleation and coupling growth mechanism between the W-phase and the I-phase, from the melt, are revealed, which is significant for understanding the peritectic reaction process involving icosahedral quasicrystal in the Mg-Zn-Y alloy. The mechanism of the quasicrystal phase strengthened magnesium alloys is also discussed here.
关键词:
Mg-Zn-Y
,
null
,
null
LI Bei WU Shuangxia MENG Guang'en JIANG Liping PANG Wenjie Baotou Research Institute of Rare Earth
,
Baotou
,
China Baotou Research Institute of Rare Earth
,
P.O.Box 131
,
Baotou 014010
,
China
金属学报(英文版)
With the increase of Y content in the Fe-20Cr-4AI-Y alloy,the uniform deformability of tensile specimens was found to be slightly decreased,as well as,the fracture strength and re- duction after necking remarkably dropped.This seems to be dependent upon the brittle phase containing Y.The behaviour of Y-containing phase may be improved by adjusting the metallurgical technological process.
关键词:
Fe-Cr-A1 alloy
,
null
,
null
腐蚀学报（英文）
研究了Y、Zr、Si对FeAl金属间化合物在1000～1200℃下循环氧化性能的影响,并用X射线衍射、扫描电镜及能谱分析等手段分析了氧化产物。结果表明,Y、Zr、Si的加入大大提高了FeAl金属间化合物表面氧化膜的抗剥落能力。从氧化动力学上看,Y和Zr或Y和Si的同时加入比单独加Zr效果好。
关键词:
FeAl金属间化合物
,
null
,
null
张康侯
,
陈亮维
,
尹俊美
,
陈藜莉
,
谢明
,
符世继
贵金属
doi:10.3969/j.issn.1004-0676.2008.04.001
在Au-Ag、Au-Y和Ag-Y二元合金相图的基础上,采用X-射线衍射分析、电子探针等手段研究了Au-Ag-Y三元系中富金-银区域(Y≤34at%)的700℃等温截面.发现:在该截面的富金银侧沿着Au-Ag二元匀晶系存在一个单相区Au(Ag)或Ag(Au);在二元金属间化合物Au2Y和Ag2Y之间存在一个无限固溶体区域(Au2Y)或(Ag2Y).在该部分700℃等温截面上一共有6个单相区:Au(Ag) 或 Ag(Au)、Au6Y、Au51Y14、α(Au2Y) 或 (Ag2Y)、 Au3Y和 Ag51Y14;9个两相区:Au(Ag)+ Au6Y、 Au(Ag)+ Au51Y14、 Au(Ag)+ Au3Y、 Au(Ag)+ α(Au2Y)、 Au(Ag)+ Ag51Y14、Ag51Y14+α(Au2Y)、α(Au2Y)+ Au3Y、 Au3Y+ Au51Y14 和 Au51Y14+ Au6Y;4个三相区: Ag51Y14+α(Au2Y)+Au(Ag)、α(Au2Y)+ Au3Y+ Au(Ag)、 Au3Y+ Au51Y14+ Au(Ag) 和 Au51Y14+ Au6Y+ Au(Ag).在Au-Ag-Y三元系的该成分区域没有发现新的三元中间相.
关键词:
材料科学基础学科
,
Au-Ag-Y三元系
,
合金
,
相图
,
等温截面
Applied Physics Letters
The effect of nonmagnetic Y partial substitution at the Dy site in Dy(1-x)Y(x)MnO(3) up to x=0.2 on magnetism, specific heat, and ferroelectricity is investigated, which resulted in a preliminary multiferroic phase diagram. It is revealed that the Y partial substitution suppresses the Dy-spin ordering point (T(Dy)) and ferroelectric ordering point (T(FE)) but enhances the Mn-spin ordering point (T(N)). The interaction between the spins of Dy and Mn is remarkably affected by Y substitution. The measured electrical polarization depends on the Y substitution in a complex way because the ferroelectricity is sensitive to the interaction between the spins of Dy and Mn. (c) 2011 American Institute of Physics. [doi: 10.1063/1.3536506]
关键词:
ferroelectricity;polarization
