X.H Luo
,
T.J. Su
,
C.G Fan
,
Y Y Liand CX Shi(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)X Chen and A.M Guo (Iron & Steel Research Institute
,
Wuhan Iron & Steel (Group) Company
,
Wuhan 430083
,
China)
金属学报(英文版)
1.25Cr-0.5Mo steels with different Ti-B or Al-B treatment were exposed in 18 MPa hydrogen atmosphere at 480℃ fo f 100, 500 and 1000 h respectively. Tensile and bend properties of steels before and after hydrogen changing were tested. The results show that the different mechanical properties of the steels with different B content have different responses to high temperature high pressure hydrogen charging processes.After hydrogen changing, more loss of ductility can be found in the steel not treated with B than those in the steels treated with B. Metallographic analyses indicated that decarburization occurred in all the steels. Furthermore, many methane bubbles were found by SEM analysis in the surface decarburization layer in the steel without B,while only a few bubbles, the number and size of which decreased with increasing B content, were found in steels with B treatment. In addition, hydrogen determination results manifested that after being exposed in hydrogen atmosphere the steel containing no B had higher hydrogen content than that of steels containing B. All this suggests that B treatment improved the HA resistance of 1.25Cgr-0.5Mo steel, and the more B the steel contained the more perceptible the effect.
关键词:
boron
,
null
,
null
,
null
Transactions of Nonferrous Metals Society of China
The microstructure and mechanical properties of Mg-10.1Gd-3.74Y-0.25Zr (mass fraction, %) alloy (GW104 alloy) cast by metal mould casting (MMC) and lost foam casting (LFC) were evaluated, respectively. It is revealed that different forming modes do not influence the phase composition of as-cast alloy. In the as-cast specimens, the microstructures are similar and composed of alpha-Mg solid solution, eutectic compound of alpha-Mg+Mg(24)(Gd, Y)(5) and cuboid-shaped Mg(5)(Gd, Y) phase; whereas the average grain size of the alloy produced by metal mould casting is smaller than that by lost foam casting. The eutectic compound of the alloy is completely dissolved after solution treatment at 525 degrees C for 6 h, while the Mg5(Gd, Y) phase still exists after solution treatment. After peak-ageing, the lost foam cast alloy exhibits the maximum ultimate tensile strength of 285 MPa, and metal mould cast specimen 325 MPa at room temperature, while the tensile yield strengths of them are comparable. It can be concluded that GW104 alloy cast by lost foam casting possesses similar microstructure and evidently lower mechanical strength compared with metal mould cast alloy, due to slow solidification rate and proneness to form shrinkage porosities during lost foam casting process.
关键词:
Mg-Gd-Y-Zr alloy;lost foam casting;metal mould casting;microstructure;mechanical property;age-hardening response;tensile properties
Physica Status Solidi a-Applied Research
Amorphization behavior is studied for several Y-based binary metal systems by room temperature 360 keV xenon ion mixing of multiple metal films to doses ranging from 7 x 10(14) to 1 X 10(16) Xe/cm2. In all systems studied, amorphization is achieved after ion mixing to the relevant doses. Interesting results are observed in the Ti-Y system, having rather positive heat of formation, i.e. 16 kJ/mol. A metastable crystalline Ti-Y phase is formed, for the first time, at medium dose ion mixing, and complete amorphous phase is formed in a narrow composition range, i.e. around Ti45Y55. Recrystallization temperatures of all formed amorphous alloys are determined by both, in-situ transmission electron microscopy annealing and confined furnace annealing. Possible interpretation is given to the observations by comparing with those proposed models for predicting glass forming ability.
关键词:
amorphous alloy formation;phase formation;thin-films;prediction
Journal of Physical Chemistry C
We report the electrical, thermal, magnetic, and thermoelectric properties of Y-doped Ca(3)Co(4)O(9) from 300 down to 5 K. The results indicate that with Y doping, the increase of resistivity originates from the decreases of carrier concentration and mobility, while the increase of Seebeck coefficient is caused by the reduction of carrier concentration together with the enhanced electronic correlation. Point-defect scattering, is the dominant thermal transport mechanism in this system. Due to the considerable difference in mass between Y(3+) and Ca(2+), thermal conductivity is observably suppressed by doping. The substitution of Y also disturbs the interlayer ferrimagnetic coupling. The ground state of this System converts front ferrimagnetism to paramagnetism gradually. The alteration of transport properties of Ca(3-x)Y(x)Co(4)O(9) reveals two Crossovers: the transition from Fermi-liquid-like metal to thermally activated semiconductor occuring at x approximate to 0.25, and the transition from thermally activated semiconductor to two-dimensional variable range hopping semiconductor occurring at x approximate to 0.5. The optimal thermoelectric response In Ca(3-x)Y(x)Co(4)O(9) is found to exist only at the critical state after which the doping-induced metal-insulator transition takes place. Oil the basis of these experimental results, a possible phase diagram for Ca(3-x)Y(x)Co(4)O(9) is proposed.
关键词:
temperature thermoelectric properties;giant magnetoresistance;solid-solutions;conductivity;electron;system;ca3co4o9+delta;thermopower;crystals;behavior
章桥新
材料研究学报
研究了不同组成的TiC—Nb粉用机械合金化合成的固溶体(TiyNb(1-y))Cx,并与电弧熔炼的(TiyNb(1-y))Cx固溶体比较,结果表明,二者的XRD谱及晶格常数变化完全一致
关键词:
机械合金化
,
null
,
null
Applied Physics Letters
The effect of nonmagnetic Y partial substitution at the Dy site in Dy(1-x)Y(x)MnO(3) up to x=0.2 on magnetism, specific heat, and ferroelectricity is investigated, which resulted in a preliminary multiferroic phase diagram. It is revealed that the Y partial substitution suppresses the Dy-spin ordering point (T(Dy)) and ferroelectric ordering point (T(FE)) but enhances the Mn-spin ordering point (T(N)). The interaction between the spins of Dy and Mn is remarkably affected by Y substitution. The measured electrical polarization depends on the Y substitution in a complex way because the ferroelectricity is sensitive to the interaction between the spins of Dy and Mn. (c) 2011 American Institute of Physics. [doi: 10.1063/1.3536506]
关键词:
ferroelectricity;polarization
MA Zongyi YAO Zhongkai Harbin Institute of Technology
,
Harbin
,
China
金属学报(英文版)
The SiC_w/Al composite prepared by squeeze casting has a combination of superior room temperature specific strength and modulus together with excellent thermal properties.The extrusion can make an improvement on the strength and ductility of the composite from 582 MPa as squeeze casted up to 639 MPa,and on the transformation from isotropic to the anisotropic structure.This seems to be explained by the orientation of whiskers and the densification of dislocations in matrix.TEM observation indicates that the stacking fault is the usual planar defect on the SiC_w surface. composite;;SiC whisker;;Al alloy;;microstructure
关键词:
composite
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null
,
null
,
null
Journal of Materials Research
Based on the best bulk metallic glass (BMG) forming alloy in the Mg-Cu-Y ternary system, we introduced Ag (or Ni) to partially substitute for Cu to improve the glass-forming ability (GFA). The objective of this paper is twofold. First, we illustrate in detail a recently developed search strategy, which was proposed but only briefly outlined in our previous publication [H. Ma, L.L. Shi, J. Xu, Y. Li, and E. Ma: Discovering inch-diameter metallic glasses in three-dimensional composition space. Appl. Phys. Lett. 87, 181915 (2005)]. The protocol to navigate in three-dimensional composition space to land large BMGs is spelled out step-by-step using the pseudo-ternary Mg-(Cu,Ag)-Y as the model system. Second, our ability to locate the best BMG former in the composition tetrahedron allows us to systematically examine, and conclude on, the effects of a given alloying element. The large improvement in glass-forming ability in the Mg-(Cu,Ag)-Y system relative to the based ternary will be contrasted with the reduced glass-forming ability in the Mg-(Cu,Ni)-Y pseudo ternary system. It is demonstrated that the improvement of glass-forming ability requires judicious choice of substitutional alloying elements and concentrations, rather than simple additions of multiple elements assuming the "confusion principle."
关键词:
bulk metallic-glass;shaped copper mold;amorphous-alloys;thermal-stability;ternary-system;casting method;p system;diameter;zr;mm
