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New Fabrication and Mechanical Properties of Styrene-Butadiene Rubber/Carbon Nanotubes Nanocomposite

Xiangwen Zhou Yuefeng Zhu Ji Liang Suyuan Yu

材料科学技术(英文)

A novel technology to prepare styrene-butadiene rubber (SBR)/carbon nanotubes (CNTs) composites was developed by combining a spray drying method and a subsequent mechanical mixing process. The cross-linking degrees of the vulcanized composites increased gradually with the additive CNTs contents. By comparing with those of the pure SBR composites, the mechanical properties such as tensile strength, tear strength and hardness of the composites filled with CNTs at certain contents were dramatically improved almost by 600%, 250% and 70%, respectively. The fabrication of the CNTs filled with SBR composites by combination of the spray drying method and subsequent mechanical mixing process was effective for enhancing the reinforcement effects of CNTs in rubbers. The novel technology can also open a new route for the modification and reinforcement on the nanocomposites with large amount of CNTs.

关键词: Carbon nanotubes , styrene-butadiene rubber , spray drying , mechanical mixing , nanocomposite , mechanical property

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

EFFECT OF SPECIMEN SIZE ON J_R RESISTANCE CURVE

H.P. Chen and Z.J. Deng (State Key Lab. for Mechanical Behavior of Materials , Xi'an Jiaotong University , Xi'an 710049 , China)

金属学报(英文版)

The effect of specimen thinkness on JR resistance curve has been investigated using low and middle strength steels. As the J dominance regime is reached, the initial J-integral values, J(i), are definite even if the elastic component Ji(e) and plastic component Ji(p)vary with the thinkness of specimen. The wider the specimen width, the larger the Ji(e)/Ji and the smaller the Ji(p)/Ji. The crack propagation resistance, dJR/da and dJp/da, decreases, while dJe/da increases linearly with increasing specimen thinness.Based on the above experimental results, an empirical formula dJ/da = α+β. B is given, which can be used to evaluate the safety of practical structural components.A modified J-integral is presented, upon which a new view is Put forward that the increase in crack growth resistance is induced mainly by the increase in the plastic J-integral component with the crack propagation,

关键词: : fracture mechanics , null , null , null

加载速率对20g钢高温断裂韧性的影响

张淑佳 , 卢炎麟 , 任立义 , 洪起超

金属学报

对20 g钢高温断裂韧性随加载速率的变化规律进行了实验研究.在400℃和500℃下,分别测量了几种加载速率下20 g钢的Ji值.实验结果表明:Ji值随应变速率的增大而有较大幅度的降低;在同一应变速率下,400℃时的Ji值小于500℃时的Ji值;400℃时裂纹扩展比500℃时更快.因此,当温度在400℃附近时更应注意避免超载.

关键词: 断裂韧性 , null , null

加载速率对20g钢高温断裂韧性的影响

张淑佳 , 卢炎麟 , 任立义 , 洪起超

金属学报 doi:10.3321/j.issn:0412-1961.2002.07.010

对20 g钢高温断裂韧性随加载速率的变化规律进行了实验研究.在400℃和500℃下,分别测量了几种加载速率下20 g钢的Ji值.实验结果表明:Ji值随应变速率的增大而有较大幅度的降低;在同一应变速率下,400℃时的Ji值小于500℃时的Ji值;400℃时裂纹扩展比500℃时更快.因此,当温度在400℃附近时更应注意避免超载.

关键词: 断裂韧性 , 加载速率 , 高温

形状记忆合金的本构关系

王振清 , 周博 , 梁文彦

金属学报

利用DSC(示差扫描热量分析)热流-温度曲线和马氏体体积分数与自由能增量间的微分关系,建立了一个新的余弦型形状记忆合金马氏体相变模型。在Tanaka和Liang研究的基础上,推导了一个新的形状记忆合金本构方程。研究表明:Liang建立的马氏体相变模型和本构方程分别为本文建立的马氏体相变模型和本构方程所描述的一种特殊情况;本文建立的马氏体相变模型和本构方程比Liang及其它现存马氏体相变模型和本构方程能更准确地描述形状记忆合金的相变行为和力学行为。

关键词: DSC , Shape Memory Alloy , Martensitic transformation model , Constitutive equation

LOCAL-STRUCTURE OF THE AXIAL FE3+ CENTER IN THE K+ SITE OF A KTAO3 CRYSTAL

Physical Review B

In order to understand the unusually large value of zero-field splitting D for the axial Fe3+ center in a KTaO3 crystal, Zhou made two assumptions in his recent report [Phys. Rev. B 42, 917 (1990)]. In this Comment we will show that his assumption II is qualitatively reasonable, whereas assumption I is unnecessary and doubtful.

关键词: electric-field;srcl2

基于遗传算法的MIVM预测合金溶液组元活度

周兰花 , 陶东平 , 曾富洪

稀有金属 doi:10.3969/j.issn.0258-7076.2011.04.011

在求解分子相互作用体积模型(MIVM)中的分子对位能参数B(ij),B(ji)时,为避免出现计算超量问题,基于遗传算法,提出了一种新算法--多个体参与交叉遗传算法,并给出了新算法的实现方案.在新算法中,采用了轮盘选种法与优秀个体保存、多个体参与交叉和多点变异等策略;选择B(ij),B(ji)个体时,按照适应度函数值愈大,个体被选中的概率愈大的原则,选择二元合金溶液中一组元活度的计算值与实验测定值之间偏差(σ)建立的适应度函数f(x)最大为优化目标.采用Matlab软件编制新算法下的B(ij),B(ji)计算程序,并分别求算了Cd-Bi,Cd-Pb,Cd-Sn,Bi-Pb,Bi-Sn,Pb-Sn等6组二元合金溶液在773 K下合金溶液的参数B(ij),B(ji)优化值.由B(ij),B(ji)计算优化值和其他一些资料数据,使用MIVM进一步预测773 K下Cd-Bi-Pb,Cd-Bi-Sn,Cd-Pb-Sn,Cd-Bi-Pb-Sn多元合金溶液中组元Cd的活度,模型预测值与实验测定值之间的相对误差低于4.6%,偏差低于0.022,两者吻合很好.结果表明,所提出的多个体参与交叉遗传算法为求解MIVM中的参数B(ij),B(ji)提供了一种有力工具,从而也能提高MIVM对多元合金溶液中组元活度的预测效果.

关键词: MIVM模型 , 分子对位能参数Bij , Bji , 遗传算法 , 活度

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