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基于不同压电材料作动机制的压电层厚度研究

韩国华 , 靳晓雄 , Joris Degrieck , Wim Van Paepegem , 侯艳芳

材料导报

研究了压电材料复合板的3种作动机制,弯曲作动机制、剪切作动机制、混合作动机制,针对粘贴在纤维板上不同厚度的压电作动层,具体分析了复合板的端部位移,研究结果对噪声和振动的主动控制中的模态控制和智能结构静态形状控制提供了一定的参考.

关键词: 作动机制 , 主动控制 , 压电作动 , 端部位移

Simple approach to estimating the van der Waals interaction between carbon nanotubes

Physical Review B

The van der Waals (vdW) interactions between carbon nanotubes (CNTs) were studied based on the continuum Lennard-Jones model. It was found that all the vdW potentials between two arbitrary CNTs fall on the same curve when plotted in terms of certain reduced parameters, the well depth, and the equilibrium vdW gap. Based on this observation, an approximate approach is developed to obtain the vdW potential between two CNTs without time-consuming computations. The vdW potential estimated by this approach is close to that obtained from complex integrations. Therefore, the developed approach can greatly simplify the calculation of vdW interactions between CNTs.

关键词: molecules;clusters;bundles;growth;phase;c-60

Van der Waals interactions between two parallel infinitely long single-walled nanotubes

Chemical Physics Letters

The potential energies of van der Waals (VDW) interactions between two parallel, infinitely long and perfect SWNTs with identical, and different sizes were studied based on the continuum Lennard-Jones model. The conclusion of Girifalco's work on (n, n) SWNTs that the potentials of SWNT-SWNT fell on a single curve, is also applicable to SWNTs with different sizes. We further obtained the corresponding constants of the well depth \phi(0)\ and equilibrium VDW gap g(0) for SWNTs with a radius from 2 to 25 Angstrom. (C) 2005 Elsevier B.V. All rights reserved.

关键词: carbon nanotubes;graphite;bundles;c-60;moduli;ropes

Purification of multiwalled carbon nanotubes by annealing and extraction based on the difference in van der Waals potential

Journal of Physical Chemistry B

The potential energies of van der Waals interactions between two multiwalled carbon nanotubes (MWNTs) as well as two carbon nanoparticles (CNPs) were calculated and compared on the basis of the continuum Lennard-Jones model. The well depth of the potential is 1 order of magnitude higher for MWNTs than for CNPs, indicating that MWNTs and CNPs can be separated from each other through polymer-induced steric stabilization. On the basis of this prediction, a novel method for the purification of MWNTs was proposed. The method involves a high-temperature annealing ( 2600 degrees C, 1 h) followed by an extraction treatment with a selected dispersing agent. While the annealing process evaporates the metal particles, the extraction treatment removes CNPs. The quality of the nanotubes obtained after purification was examined by laser Raman, thermogravimetric analysis, and electron microscopy observations.

关键词: decomposition;hydrocarbons;temperature;nanofibers;pyrolysis;monoxide;bundles;purity;gas

Van Hove奇异性、非电声作用与HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导电性

张霞 , 苏希玉 , 侯芹英 , 侯艳丽

低温物理学报 doi:10.3969/j.issn.1000-3258.2008.03.011

考虑态密度的Van Hove奇异性和非电声作用,我们在BCS理论框架内研究了HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导转变温度和同位素效应.结果表明,当同时考虑Van Hove奇异性和非电声作用时,可以更好地解释HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导性质.

关键词: Van Hove奇异性 , 非电声作用 , 超导转变温度 , 同位素效应

聚丙烯/乙丙橡胶共混体系相分离的流变学表征方法

钱晨 , 杨斌 , 章于川 , 夏茹 , 钱家盛

高分子材料科学与工程

通过动态流变学方法研究了不同配比下聚丙烯/乙烯-丙烯-二烯三元共聚物(PP/EPDM)共混体系相分离行为.结果表明,EPDM与PP相容性不佳,当EPDM质量分数达到20%即已发生相分离,在质量分数为50%时形成双连续相结构,在质量分数50%~60%时发生相反转.采用Cole-Cole曲线、Han曲线、van Gurp曲线等方法表征了PP/EPDM体系相分离行为,其中van Gurp曲线最为敏感.

关键词: 聚乙烯 , 三元乙丙橡胶 , 共混 , 动态流变行为 , 相分离

Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations

Science in China Series B-Chemistry

The equation of the state of the hydrogen bonding fluid system of A(a)D(d) type is studied by the principle of statistical mechanics. The influences of hydrogen bonds on the equation of state of the system are obtained based on the change in volume due to hydrogen bonds. Moreover, the number density fluctuations of both molecules and hydrogen bonds as well as their spatial correlation property are investigated. Furthermore, an equation describing relation between the number density correlation function of "molecules-hydrogen bonds" and that of molecules and hydrogen bonds is derived. As application, taking the van der Waals hydrogen bonding fluid as an example, we considered the effect of hydrogen bonds on its relevant statistical properties.

关键词: hydrogen bonding fluid;equation of state;fluctuation;correlation;effect;liquid methanol;temperature;water;dependence

Microstructure and preparation of nano S-W-S new solid lubrication system

Transactions of Nonferrous Metals Society of China

The method for preparing a new solid lubrication system of nano S-W-S was presented. The microstructure of the S-W-S nano cluster was investigated using TEM and XRD. The system is a mixture clusters of both monocrystal and polycrystal of layered hexagonal structure with one tungsten atom linking with two sulphur atoms, and the week Van der Waals' force bonding together the different layers. The changes of electronic structure were studied with XPS. The hybridization of different electronic shelf orbitals of the sulphur atom in the nano cluster is regarded as the quantum size effect. The clusters are found to be of a closed spherical,structure without any dangling bond.

关键词: solid lubrication system;nanometer cluster;quantum size effect;powders

Magnetic properties of a mixed spin-1/2 and spin-3/2 transverse Ising model in a longitudinal magnetic field

Physica a-Statistical Mechanics and Its Applications

The mixed spin-1/2 and spin-3/2 transverse Ising model in a longitudinal magnetic field is studied within the framework of the effective-field theory with correlations. In this approach the effective-field equations are derived by using a probability distribution method based on the generalized but approximated van der Waerden identities. The total longitudinal and transverse magnetizations, the transverse susceptibility and longitudinal susceptibility and the critical temperatures are obtained. We find a number of interesting phenomena in these quantities, due to the applied transverse field and the longitudinal field. (C) 2008 Elsevier B.V. All rights reserved.

关键词: transverse Ising model;longitudinal magnetic field;magnetization;susceptibility;critical temperature;molecular-based magnet;system;behavior;transitions

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