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INFLUENCE OF ENVIRONMENT ON TENSILE BEHAVIOR OF Ni_3Al SYNTHESIZED UNDER COMPRESSION

LI Gang , WANG Zhongguang , LI Guangyi(State Key Laboratory of Fatigue and Fracture for Materials , Institute of Metal Research , Chinese Academy of Sciences , Shenyang 110015 , China)V.OVCHARENKO(Institute of Strength Physics and Materials Science , Russian Academy of Science , Siberian Branch , Tomsk , Russia) Manuscript received 3 May 1995

金属学报(英文版)

Self propagating high temperature synthesis(SHS) under compression was utilized to obtain an intermetallic compound Ni_3 Al by using elemental powders.The microstructure of the SHS product was observed by optical microscopy(OM) and scanning electron microscopy(SEM).The results reveal that the SHS Ni3Al is a single-phase polycrystalline alloy wilh LI2 crystal structure.Tensile tests were conducted from room temperature to 800℃ both in air and in vacuum.The results show that the SHS Ni_3Al exhibits an anomalous temperature dependence of ultimate tensile strength.The ultimate tensile strength in vacuum is much higher than that in air over the whole temperature range.Fracture surfaces are characterized by the brittle grain boundary fracture and the intergranular fracture mode can not be affected markedly by the test environment.

关键词: :Ni_3Al , null , null , null

The Study of Dual-phase Steel after Cyclic Deformation at Various Strain Amplitudes

SUN Zhengming , WANG Zhongguang , AI Suhua Institute of Metal Research , Academia Sinica , Shenyang , China. To whom correspondence should be addressed.

材料科学技术(英文)

Low cycle fatigue tests under plastic strain control were carried out with a dual-phase steel containing 23 Vol.-% martensite. Specimens hardened rapidly at first few cycles followed by a slight softening to saturation stages when cycled at higher strain amplitudes, whereas at lower strain amplitudes the specimens presented continually hardening for a long time until saturation. TEM examination of the saturation dislocation structures show that clusters, parallel walls and cells were found at low, medium and high strain amplitude, respectively. It also has been found that the martensite/ferrite interfaces did not affect the dislocation structures signi- ficantly when a specimen was fatigued at lower strain amplitude. However, the dislocation struc- ture adjacent to the two-phase boundary is dif- ferent to some extent from that in the remote regions in the ferrite when a higher strain amplitude is applied.

关键词: cyclic deformation , null , null

Intergranular Fatigue Cracking Behaviour in Aluminium

LIU Wei , WANG Zhongguang , XIA Yuebo Institute of Matal Research , Academia Sinica , Shenyang , China.

材料科学技术(英文)

In order to understand the basic mechanism of intergranular cracking in pure metals during fatigue, stress-controlled push-pull fatigue tests were carried out with high purity aluminium. Tests were interrupted frequently so as to study the grain boundary (GB) cracking behaviour by the surface observation. The results show that crack initiation at GB was a process controlled by multi-factors, such as boundary structure, GB-slip interaction, GB sliding and so on. If these factors are varied so that the incompati- bility at a GB increased, the possibility of cyacking at the boundary will be raised. Some inteygranular cracking phenomena are not able to be explained by the GB stepping mechanism.

关键词: intergranular crack , null , null , null , null

Two-step magnetization in a spin-chain system on the triangular lattice: Wang-Landau simulation

Physical Review B

The Wang-Landau algorithm is used to study the thermodynamic and magnetic properties of triangular spin-chain system based on two-dimensional Ising model in order to understand the magnetic-order dynamics in Ca(3)Co(2)O(6) compound. The calculated results demonstrate that the equilibrium state of the rigid spins produces the two-step magnetization curve at low temperature even when the random-exchange term is considered. This work indicates that the four-step magnetization behavior observed experimentally must be due to the nonequilibrium magnetization.

关键词: calcium compounds;exchange interactions (electron);Ising model;magnetisation;thermodynamics;one-dimensional ca3co2o6;density-of-states;compound ca3co2o6;phase-diagram;proteins;crystal

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

Effect of interstitial hydrogen on cohesive strength of Al grain boundary with Mg segregation

材料科学技术(英文)

The effect of interstitial hydrogen on the cohesion of the Al Sigma=11(113) grain boundary (GB) is investigated based on the thermodynamic model of Rice-Wang using the first-principles density function calculation. The results indicate that interstitial H behaves as an embrittler from "strengthening energy" analysis. The reduced GB cohesion due to the presence of H at the GB is attributed to the low affinity between H and Al, and the weakened bonding of Al atomic pairs perpendicular to GB plane.

关键词: hydrogen;grain boundary;Al-Mg alloys;pseudopotentials;1st-principles

Effect of Interstitial Hydrogen on Cohesive Strength of Al Grain Boundary with Mg Segregation

Xiaoguang LIU , Xiaowei WANG

材料科学技术(英文)

The effect of interstitial hydrogen on the cohesion of the Al ∑=11(113) grain boundary (GB) is investigated based on the thermodynamic model of Rice-Wang using the first-principles density function calculation. The results indicate that interstitial H behaves as an embrittler from "strengthening energy" analysis. The reduced GB cohesion due to the presence of H at the GB is attributed to the low affinity between H and Al, and the weakened bonding of Al atomic pairs perpendicular to GB plane.

关键词: Hydrogen , null , null

First-principles study on the effect of Mn and N on the cohesion of a gamma-iron grain boundary

Physical Review B

By use of the linear-combination-of-atomic-orbital (LCAO) method for a cluster model, we studied the electronic structure of gamma-from Sigma 11 [1 (1) over bar0](11 (3) over bar) grain boundary doping with N and Mn atoms. The effect of the segregation on the cohesion of the grain boundary is investigated based on the Rice-Wang thermodynamic model. It is found that N could not only largely enhance the cohesion of the grain boundary but also eliminate the detrimental effect of Mn. The cosegregation effect of Mn and N on the cohesion of the grain boundary depends on where they segregate. Nitrogen could be reliably used in alloyed steels as an efficient strengthening element.

关键词: electronic-structure;phosphorus segregation;stainless-steel;embrittlement;austenite;nitrogen;boron;impurities;fracture;metals

First-principle study of electronic properties of Ti3Si1-xAlxC2 solid solutions

Journal of Physics and Chemistry of Solids

The layered ternary ceramics Ti3SiC2 and Ti3AlC2 are isostructural and can form Ti3Si1-xAlxC2 solid solutions combining the advanced properties of both compounds [H.B. Zhang, Y.C. Zhou, Y.W. Bao, M.S. Li, Improving the oxidation resistance of Ti3SiC2 by forming a Ti3Si0.90Al0.1C2 solid solution, Acta Mater. 52 (2004) 3631-3637; E.D. Wu, J.Y. Wang, H.B. Zhang, Y.C. Zhou, K. Sun, Y.J. Xue, Neutron diffraction studies of Ti3Si0.9Al0.1C2 compound, Mater. Lett. 59 (2005) 2715-2719; J.Y. Wang, Y.C. Zhou, First-principles study of equilibrium properties and electronic structure of Ti3Si0.75Al0.25C2 solid solution, J. Phys.: Condens. Matter 15 (2003) 5959-5968; Y.C. Zhou, J.X. Chen, J.Y. Wang, Strengthening of Ti3AlC2 by incorporation of Si to form Ti3Al1-xSixC2 solid solutions, Acta. Mater. 54 (2006) 1317-1322]. In the present work, the solid solutions of Ti3Si1-xAlxC2 (x = 0, 0.25, 0.33, 0.5, 0.67, 0.75, 1) are investigated by first-principle calculations based on pseudo-potential plan-wave method within the density functional theory framework. The results show that as Al content increases in the solid solution, all the bonds have weakened to certain extents, which lead to an unstable structure both energetically and geometrically. The calculated results are compared and discussed with the reported data for the Ti3Si1-xAlxC2 solid solutions. (c) 2007 Elsevier Ltd. All rights reserved.

关键词: ceramics;ab initio calculations;electronic structure;electrical;conductivity;oxidation behavior;mechanical-properties;ti3sic2;temperature;ti3alc2;air;si

GH4169合金高温力学行为本构建模及参数识别

魏洪亮 , 杨晓光 , 于慧臣

材料工程 doi:10.3969/j.issn.1001-4381.2005.04.011

针对涡轮盘用GH4169合金开展了高温下单调拉伸、对称循环及非对称循环的实验工作,结果表明,该材料具有比较明显的循环软化和平均应力松弛特性.采用带Ohno/Wang修正的Chaboche粘塑性理论本构方程,对其表现出的复杂力学现象进行本构建模,介绍了Levenberg-Marquadt非线性优化算法,结合材料实验数据并通过该算法识别了本构方程参数,将本构方程通过用户子程序嵌入到有限元软件ABAQUS中,对GH4169合金的上述实验现象进行了数值模拟,计算曲线与实验曲线取得了较好的一致性.

关键词: 循环软化 , 平均应力松弛 , 本构方程 , 参数识别

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