赵克清
,
W.Dahl
中国腐蚀与防护学报
<正> 对碳钢和低合金钢,特别是一系列高强钢构件,除用作与硝酸盐直接接触的化工设备外,用于氮肥厂的钢结构、混凝土中的钢筋,地下管道以及高温热风炉等都观察到过由硝酸盐引起的应力腐蚀开裂。 过去人们主要用恒载荷法或恒变形法在较高温度(90℃到沸点)和较高浓度的硝酸盐介质中研究各种因素对低合金钢或碳钢应力腐蚀开裂的影响。近来发现,在室温和含较低浓度NO_3~(?)的介质中,即使碳钢或低合金钢所受的机械应力低于屈服点也会出现应力腐蚀,并且在硝酸盐介质中除恒载荷条件下能产生应力腐蚀外,还会产生与应变率有关的应力腐蚀,它不存在阳极极化临界电位。由于以往的工作或者没有采用恒电位控制,
关键词:
HUANG Huimin CHEN Xinmin Central South University of Technology
,
Changsha
,
China HUANG Huimin Associate Professor
,
Department of Chemistry
,
Central South University of Technology
,
Changsha
,
China
金属学报(英文版)
The nature of the oxygen contained in β-W was investigated with DSC,X-ray analysis on quenched samples and Auger spectroscope.It was shown that the oxygen contained in nonpyrophoric β-W consists of the reversibly chemisorbed oxygen and the interstitial oxygen which could form an interstitial solid solution with β-W.It seems better to consider β-W to be a metastable phase of tungsten with the interstitial oxygen as stabilizer.
关键词:
tungsten
,
null
,
null
,
null
Physical Review B
The effect of W on the structural stability of TiAl intermetallic systems and the site preference of W in B2 and L1(0) TiAl were studied based on first-principles calculations. It was found find that about 15 at. % W addition, in good agreement with experiment, is required to stabilize the B2 structure in a TiAl base alloy. W was predicted to occupy Al sites in the B2 phase, but Ti sites in the L1(0) phase. The B2-stabilizing effect of W and its site preference can be explained perfectly on the basis of the pseudogap effect and the strong covalent W-Ti bonding. The strong W-Ti bonding pairs are maximized when W occupies Al sites in B2 TiAl. But when W occupies Al sites in L1(0) TiAl, the W-Ti bonding is weakened by the existence of Al in the alternating (002) plane, which can, however, strengthen the in-plane W-Ti bonding when W occupies Ti sites.
关键词:
gamma-titanium aluminides;electronic-structure;microstructure;deformation;systems;alloys
Xiaobo LI
,
Youqing XIE
金属学报(英文版)
doi:10.1016/S1006-7191(08)60099-X
The valence bond structure of substitutional BCC based Ta-W alloys is studied using characteristic crystal (CC) theory. This theory is based on cluster statistics of random alloys. By studying the correlativity between energy and volume of the CC in Ta-W alloys, the valence bond structure of CC is determined by the energy and shape method. Then, following additive law of CC, the valence bond structure of Ta-W alloys is calculated. It is found that the outer shell valence electronic distribution of Ta-W alloys shows a continuous change in the whole composition range. The covalent electrons ec(dc, sc, and pc) increase, whereas near free electrons ef decrease with increasing W concentration. The bond length and single-bond radius decrease, whereas bond energy and bond valence increase with increasing W concentration. The mechanism of solid solution strengthening of Ta-W alloys is analyzed based on their valence bond structure.
关键词:
Valence bond structure
,
null
Xiaobo LI
金属学报(英文版)
The characteristic crystal model is applied to the study of phase stability and thermodynamics in substitutional bcc-based Ta-W alloys. The basic principle and method of alloy thermodynamics which is described by the characteristic crystal model is introduced in detail. The Gibbs energy of various phases including both disordered and ordered phases of the Ta-W system are evaluated. The phase diagram of Ta-W alloys is assessed and predicted. The results are in good agreement with experiments and better than that of first principle.
关键词:
Ta-W alloys
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phase diagram
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characteristic crystal model
,
thermodynamics
,
phase stability
Bo YANG
金属学报(英文版)
A series of hexagonal close-packed (HCP) Co-W thin films were deposited by sputtering on surface oxidized silicon substrates at 300℃. A linear dependency of saturation magnetization (Ms) on W content was found up to about 9~at.~pct W, and then it underwent an increased Ms vs. W content curve as compared to the initial linear dependency. The thermal magnetization technique was used to confirm that the increased Ms behaviour is correlated to the phase separation of the Co-W thin films. The phase separation behaviour was also found to be dependent on W content and the reason was discussed in detail. Finally an interesting composition range was suggested to be about 13at.pct-17 at. pct W for the Co-W thin films, in which they exhibit much higher magnetic anisotropy energy than Co-Cr thin films and improved phase separation.
关键词:
Magnetic recording media
