J. Feng
,
W.D. Huang
,
X. Lin
,
T. Li
,
Y.F. Xue and Y.H. Zhou(State Key Lab. of Solidilication Processing
,
Northwestern Polytechnical University
,
Xi'an 710072
,
China)
金属学报(英文版)
In order to investigate the response of cellular spacing to the variation of growth velocity under near-rapid directional solidification condition, Al-0.53wt%Zn alloy is directionally solidified with Bridgman apparatus. The results show that at the given temperature gradient the obtained microstrvctures are all cells and there exists a wide distribution range of cellular spacing. The maximum, λmax, minimum, λmin, and average cellular spacing, λ, as functions of growth rate, V, can be given by λmax=948.51V-0.4961, λmin= 661.16V-0.5015 and λ=412.41V-0.5049, respectively. The experimental results are compared with that predicted by KGT model, and a good agreement is found. Moreover,it is found that the average cellular spacing is also remarkably history-dependent.
关键词:
Al-Zn alloy
,
null
,
null
,
null
卫英慧
,
贾连锁
,
胡兰青
,
许并社
稀有金属材料与工程
T1(Al2CuLi)相是Al-Li-Cu-Zr合金中的重要强化相.通过TEM在对T1相结构和形貌分析的基础上,构造了T1相的结构.T1相晶核以ABCBA的堆垛顺序,共由36个原子组成,其晶格常数a=0.495nm,c=0.933nm.与基体的位相关系为:{0001}T1∥{111}α,<>T1∥<110>α.合金中铜原子的偏聚降低了基体的层错能,从而为T1相依赖扩散层错形核提供了有利条件.T1相长大依赖于原子扩散和台阶滑移,是一种长程扩散控制的台阶机制.
关键词:
Al-Li基合金
,
相变
,
时效
,
T1相
张立春
,
何安强
,
吴玉琨
,
叶恒强
,
张永昌
金属学报
利用高分辨电镜(HRTEM)和常规电子显微术研究了快速凝固Al-Li-Cu—Mg—Zr合金中Z相和T相的结构关系,发现两相间两种确定的晶体学取向关系,并以此为依据解释了Z相和T相的某些结构缺陷两相的结构有密切关联,其中一相中缺陷的扩展会导致另一相的形成
关键词:
Al-Li-Cu-Mg-Zr合金
,
Z hexagonal phase
,
T f.c.c. phase
,
shear structure
刘奋军
,
傅莉
,
张纹源
,
孟强
,
董春林
,
栾国红
金属学报
doi:10.11900/0412.1961.2014.00297
采用搅拌摩擦焊(FSW)对厚度为2mm的2099-T83与2060-T8 Al-Li合金进行搭接.利用OM和SEM等分析技术探讨搅拌头转速和搅拌针长度对搭接接头界面结构与力学性能的影响.结果表明,2099-T83/2060-T8搭接接头焊缝区可观察到明显的结合界面,焊缝区显微硬度低于母材,且在热机影响区与焊核区的过渡区硬度最低.当搅拌头转速由600 r/min增加到800 r/min,且搅拌针长度由3.0mm减小至2.5mm时,界面形貌由光滑界面转变成“锯齿状”咬合界面,焊缝区结合界面形貌主要受搅拌针长度影响,“锯齿状”咬合界面搭接接头平均破坏载荷为654N.搭接接头均在底部母材2060-T8侧热机影响区与焊核区的过渡区断裂,断裂特征为韧-脆混合断裂.“锯齿状”咬合界面搭接接头经150℃,保温20 h人工时效处理后,焊缝区显微硬度有所提升,接头承载能力较未经人工时效处理的降低了20%,断口呈现脆性断裂模式.
关键词:
2099-T83 Al-Li合金
,
2060-T8 Al-Li合金
,
搅拌摩擦焊接
,
人工时效处理
,
界面形貌
,
接头强度
陈圆圆
,
郑子樵
,
蔡彪
,
徐建秋
,
佘玲娟
,
李海
稀有金属材料与工程
研究了2197-T851合金的疲劳裂纹萌生与扩展特性.结果表明,2197铝锂合金的疲劳裂纹萌生与应力水平有关,在较低应力下,主要萌生在第二相粒子、第二相粒子/基体界面以及表面缺陷处,而在较高应力水平下,还出现沿滑移带和晶界处萌生.裂纹的扩展优先沿有利滑移面,在晶粒间的扩展以沿{111}面的穿晶扩展为主,也有沿小角度晶界扩展的情况,合金具有很好的平面滑移性.裂纹在晶粒内的扩展并非沿一个滑移系的直线扩展而是频繁发生偏折,却始终沿{111}面,可剪切共格相δ'粒子造成晶内扩展路径曲折.
关键词:
2197铝锂合金
,
裂纹萌生和扩展
,
EBSD
,
疲劳断口
International Journal of Hydrogen Energy
Various carbon additives were mechanically milled with LiBH(4)/MgH(2) composite and their hydrogen storage behaviors were investigated. It was found that most of the carbon additives exhibited prominent effect on the host material. Among the various carbon additives, purified single-walled carbon nanotubes (SWNTs) exhibited the most prominent effect on the kinetic improvement and cyclic stability of Li-Mg-B-H system. Results show that LiBH(4)/MgH(2) composite milled with 10 wt.% purified SWNTs additive can release nearly 10 wt.% hydrogen within 20 mm at 450 degrees C, which is about two times faster than that of the neat LiBH(4)/MgH(2) sample. On the basis of hydrogen storage behavior and structure/phase investigations, the possible mechanism involved in the property improvement upon carbon additives was discussed. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
关键词:
Hydrogen storage;Lithium borohydride;MgH(2);Carbon;Mechanical;milling;arc-discharge method;libh4;nanotubes;composites;hydride