Shishu XIE
,
Tieli WANG
,
Junying LU
,
Hongcai YANG
,
Guangpu ZHAO
材料科学技术（英）
0.020, 0.045 and 0.075 wt pct Zr were added to a Ni-base superalloy GH586 to investigate their effects on the microstructure and the short-term strengths at 850℃. The results showed that proper Zr addition could improve the alloy tensile strength at 850℃and short-term rupture life at 850℃, 580 MPa. Zr exists in both γ' phase and γ matrix, which caused Zr to distribute in grain instead of segregating in grain boundaries, therefore increased both of their lattice parameters but decreased the mismatch between them. Meanwhile, it also increased the amount of grain-boundary carbides and decreased their size markedly. These contributed to the improvement of short-term rupture life. However, further addition of Zr resulted in forming Zr4C2S2, a plate-like stable sulphurocarbides in grain boundaries, which decreased short-term strength at high temperature, and led to a worse hot workability. According to the experimental results, the optimum content of Zr should be 0.020 wt pct.
关键词:
刘建国
,
安振涛
,
张倩
,
杜仕国
,
姚凯
,
王金
材料导报
doi:10.11896/j.issn.1005-023X.2017.04.030
为评估氧化剂硝酸羟胺的热稳定性,使用标准液体铝皿于3 K/min、4 K/min、5 K/min加热速率下进行热分析.借助非等温DSC曲线的参数值,应用Kissinger法和Ozawa法求得热分解反应的表观活化能和指前因子,根据Zhang-Hu-Xie-Li公式、Hu-Yang-Liang-Xie公式、Hu-Zhao-Gao公式以及Zhao-Hu-Gao公式,计算硝酸羟胺的自加速分解温度和热爆炸临界温度,并对热分解机理函数进行了研究.设计了7条热分解反应路径,采用密度泛函理论B3LYP/6-311++G(d,p)方法对硝酸羟胺的热分解进行了动力学和热力学计算.计算结果表明,硝酸羟胺热分解的自加速分解温度TsADT=370.05 K,热爆炸临界温度Te0=388.68K,Tbp0=397.54 K,热分解最可几机理函数的微分形式为f(a) =17×(1-α)18/17.硝酸羟胺热分解各路径中,动力学优先支持路径Path 6、Path 5、Path 4和Path 1生成NO和NO2,其次是Path 2、Path 7和Path 3生成N2和N2O.温度在373 K以下时,Path 1'反应无法自发进行,硝酸羟胺无法进行自发的热分解.从热力学的角度来看,硝酸羟胺在370.05K以下储存是安全的.
关键词:
硝酸羟胺
,
热分析
,
热稳定性
,
热分解机理
,
密度泛函理论
