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DU-Ti合金表面N+Ti+多层Ti/TiN复合膜的制备与耐蚀性

严东旭 , 刘天伟 , 龙重 , 白彬 , 张鹏程 , 黄河 , 郎定木 , 王晓红 , 朱建国

材料保护

采用单一的表面改性技术难以提高贫铀钛合金(Du-Ti)的耐蚀性能.采用等离子体浸没离子注入技术依次在Du-Ti合金表面注入N和Ti,再利用非平衡脉冲磁控溅射技术制备多层Ti/,TiN,研究了膜层的形貌、结构及耐蚀性能.结果表明:膜层厚约3μm,呈柱状结构,致密,但存在一些微缺陷,膜基结合紧密;膜层出现面心立方结构的TiN和密排六方的Ti,在DU-Ti合金界面形成了少量的UO2,没有铀的氮化物;膜层耐蚀性能较基体得到较大提高;微观缺陷是TiN层局部片状脱落的主要原因,外层TiN出现片状脱落后.注入层和内层Ti/TiN多层膜仍能有效保护基体.

关键词: 等离子体浸没离子注入 , 非平衡磁控溅射 , 复合膜 , DU-Ti合金 , 电化学腐蚀 , 耐蚀性

Comparison of Inconel 625 and Inconel 600 in resistance to cavitation erosion and jet impingement erosion

Nuclear Engineering and Design

Liquid droplet erosion (LDE), which often occurs in bellows made of nickel-based alloys, threatens the security operation of the nuclear power plant. As the candidate materials of the bellows, Inconel 600 and Inconel 625 were both tested for resistance to cavitation erosion (CE) and jet impingement erosion (JIE) through vibratory cavitation equipment and a jet apparatus for erosion-corrosion. Cumulative mass loss vs. exposure time was used to evaluate the erosion rate of the two alloys. The surface and cross-sectional morphologies before and after the erosion tests were observed by scanning electron microscopy (SEM), the inclusions were analyzed by an energy dispersive spectroscopy (EDS), and the surface roughness was also measured by surface roughness tester to illustrate the evolution of erosion process. The results show that the cumulative mass loss of CE of Inconel 625 is about 1/6 that of Inconel 600 and the CE incubation period of the Inconel 625 is 4 times as long as that of the Inconel 600. The micro-morphology evolution of CE process illustrates that the twinning and hardness of the Inconel 625 plays a significant role in CE. In addition, the cumulative mass loss of JIE of Inconel 625 is about 2/3 that of Inconel 600 at impacting angle of 90 degrees, and almost equal to that of the Inconel 600 at impacting angle of 30 degrees. Overall, the resistance to CE and JIE of Inconel 625 is much superior to that of Inconel 600. (C) 2010 Elsevier By. All rights reserved.

关键词: stress-corrosion cracking;aluminide intermetallic alloys;high-purity;water;mechanical-properties;crevice corrosion;solid particles;wear;behavior;microstructure;deformation;steam

水平轴风力机专用翼型性能评估方法

李星星 , 杨科 , 张磊 , 刘强

工程热物理学报

本文提出了风力机翼型完整的性能参数体系和相应的评估方法,并以此评估了CAS-W1翼型与DU翼型的性能特征.对翼型性能的评估侧重于失速特性、非设计点特性和翼型气动性能的稳定性.评估结果表明,相对于DU翼型,CAS-W1翼型系列设计点性能和非设计点性能较好,但是失速特性和性能稳定性需要优化.

关键词: 风力机专用翼型 , 气动性能评价 , 失速特性 , 稳定性参数

液晶显示用新型偏光片紫外光谱特性研究

欧阳艳东 , 黄翀 , 余云鹏 , 林舜辉

功能材料与器件学报 doi:10.3969/j.issn.1007-4252.2003.04.020

通过测量ITO玻璃及偏光片对各波段紫外光的光谱特性,分析比较一般偏光片和防紫外偏光片F1225DU的紫外透射光谱,从而说明新型偏光片的防紫外特性.F1225DU对紫外线有比较好的吸收,能挡住各种波长的紫外光,起防止紫外光破坏液晶显示器件的作用.

关键词: 偏光片 , 紫外光 , 液晶显示器 , 透射光谱

150t RH装置内钢液的流动和混合特性及吹气管直径的影响

蒋兴元 , 魏季和 , 温丽娟 , 李波

上海金属 doi:10.3969/j.issn.1001-7208.2007.02.008

在几何相似比为1∶4的水模型上研究了150t RH装置内钢液的流动和混合特性及吹气管直径的影响.模型的吹气管内径分别为0.10、0.15和0.2 cm.所得结果表明,该装置的环流量计算式为:Qlp=0.0291Qg0.323Du0.65Dd0.84(t/min),式中Qg-提升气体流量, Nl/min;Du和Dd-上升管和下降管内径,cm.在给定的Qg、Du和Dd下,吹气管直径din的变化对液体的流态没有显著影响,环流量则略有改变,在(0.40~0.80)cm的范围内,Qlp=0.0304Qg0.322Du0.651Dd0.839din0.07.在Du和Dd均为53 cm、din为0.60 cm的情况下,该装置内钢液的最大("饱和")环流量约为135.1 t/min,相应的Qg为2500 Nl/min.钢包内钢液的混合效果随Qg的增大迅速提高.增大din使混合时间τm(s)略有缩短,对应于0.10,0.15和0.20 cm的孔径,τm与搅拌功率密度ε(W/t)的关系分别为:τm ∞ε-0.497,τm ∞ε-0.493和Tm∞ε-0.476.

关键词: 150t RH装置 , 水模型 , 流动特性 , 混合特性 , 物理模拟 , 吹气管直径

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

Cavitation erosion and jet impingement erosion mechanism of cold sprayed Ni-Al(2)O(3) coating

Nuclear Engineering and Design

A composite coating was deposited on Inconel 600 substrate by cold spray method using pure Ni powder (60 wt.%) blended with alpha-Al(2)O(3) (40 wt.%) as feedstock. It is expected to be applied to repair the bellows eroded by the liquid droplet erosion (LDE). Microstructure of the coating was observed using optical microscope (OM) and scanning electron microscopy (SEM). Microhardness of the coating was determined by Vickers hardness tester. Cavitation erosion (CE) experiments were carried out in the distilled water. Jet impingement erosion (JIE) experiments were performed in slurry containing 1 wt.% quartz particle with the flow velocity of 15 m/s at impingement angles of 30 degrees, 60 degrees and 90 degrees, respectively. Cumulative mass loss vs. testing time was used to evaluate the erosion rate of the coating. The erosion mechanism was analyzed by OM, SEM, X-ray diffraction (XRD) and the microhardness measurement. The results show that the composite coating has compact microstructure and relatively high hardness. The resistance to CE of the coating is not as good as that of Inconel 600 substrate due to the weak bonds of the Al(2)O(3) particles. However, the results of the JIE test indicate that the slurry erosion resistance of the coating is better than that of Inconel 600 at the impact angles of 30 degrees and 60 degrees, but not at the normal impact angle. (C) 2011 Elsevier B.V. All rights reserved.

关键词: large powder particles;composite coatings;slurry erosion;kinetic;spray;liquid impact;alloy;microstructure;steels;deposition;resistance

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