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CORROSION BEHAVIOR OF A ZIRCONIUM-TITANIUM BASED PHOSPHONIC ACID CONVERSION COATING ON AA6061 ALUMINIUM ALLOY

S.H. Wang

金属学报(英文版)

The conversion coating was formed by dipping AA6061 in a fluorotitanate/zirconate acid and amino trimethylene phosphonic acid (ATMP) solution at room temperature. The formation process and the anti-corrosion performance of the conversion coating were investigated using electrochemical test and salt spray test (SST), respectively. The electrochemical test shows that the Zr/Ti and ATMP coating improves the corrosion resistance of AA6061 as good as the chromate (VI) coating. But the results of SST show that the corrosion resistance of Zr/Ti and ATMP coating is not as good as the chromate (VI) coating. The corrosion area is less than 2% after 72h.

关键词: Corrosion resistance , null , null

Amino-Tris-(Methylenephosphonic Acid) Layers Adsorption On Aa6061 Aluminum Alloy

S.H. Wang , C.S. Liu , F.J.Shan , G.C. Qi

金属学报(英文版)

The amino-tri-(methylenephosphonic acid) layers were adsorbed on the surface of AA6061 aluminum alloy for improving the lacquer adhesion and corrosion inhibition as a substitute for chromate coatings. The surface structure and characteristic of the amino-tri-(methylenephosphonic acid) layers on AA6061 aluminum alloy were investigated by means of XPS and ATR-FTIR analysis. The analyzed results showed that the amino-tri-(methylenephosphonic acid) adsorption layers adsorb on the surface of aluminium alloy $via$ acid-base interaction in a bi-dentate conformation. After the amino-tri-(methylenephosphonic acid) layers were coated with epoxy resin, the layers showed good adhesive strength and favorable corrosion resistance in contrast to chromate coatings.

关键词: Amino-tri-(methylenephosphonic acid)Layer , null , null , null

H2S应力腐蚀试验用H2S气通设计

孙耀峰

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.2001.z1.007

在满足H2S应力腐蚀试验的试验条件下,设计了H2S应力腐蚀实验室中H2S气体的通气装置.设计方案切实易行,安全可靠;实现了出口H2S气体的吸收再利用,减少了对环境的污染.

关键词: H2S气体 , 设计方案 , H2S应力腐蚀试验 , 环境保护

炼油工业中H_2S的腐蚀

郦建立

腐蚀学报(英文)

综述了含H2 S介质中材料的各种腐蚀形态 ,阐述了H2 S腐蚀发生的机理和影响因素 (外部环境 ,材料条件等 ) .介质温度和浓度对腐蚀有较大的影响 ;腐蚀过程中析出的H是引起SSCC的重要因素 ;硬度、夹杂和带状组织降低材料对H2 S腐蚀开裂的阻力 .

关键词: 硫化物应力腐蚀 , hydrogen induced cracking

H2S分压对油管钢CO2/H2S腐蚀的影响

张清 , 李全安 , 文九巴 , 白真权

腐蚀学报(英文)

1974-),男,硕士研究生,研究方向为腐蚀与防护.〖ZK)〗 Tel:0379-4231846〓E-mail:FQ)〗〖HT〗〖HJ〗〖HT5”SS〗 〖JZ(〗〖HT2H〗〖STHZ〗〖WTHZ〗 采用高温高压釜,辅以失重法和扫描电镜,对不同H2S分压下(1.4 kPa,20 kPa,60 kPa,120 kPa)油管钢N80、P110的CO2/H2S腐蚀进行了研究.结果表明,在试验H2S分压范围内,随着H2S分压的升高,两种钢的腐蚀速率先增后降,且都在H2S分压为20 kPa时取得最大值. 

关键词: H2S分压 , null , null , null

C-S-H 凝胶及其研究方法

杨南如

硅酸盐通报 doi:10.3969/j.issn.1001-1625.2003.02.011

在分析C-S-H凝胶的复杂性和特征的基础上,就测定它的化学组成、C-S-H凝胶中[SiO4]4-四面体的聚合度及其结构的化学和物理的方法作了简要介绍.现代各种测试方法的出现和使用,对C-S-H凝胶的组成和集中[SiO4]4-四面体的聚合结构有了较为完整的概念.

关键词: C-S-H凝胶 , 化学组成 , 凝胶结构 , 测定方法

H2S分压对油管钢CO2/H2S腐蚀的影响

张清 , 李全安 , 文九巴 , 白真权

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.2004.06.015

采用高温高压釜,辅以失重法和扫描电镜,对不同H2S分压下(1.4 kPa,20 kPa,60 kPa,120kPa)油管钢N80、P110的CO2/H2S腐蚀进行了研究.结果表明,在试验H2S分压范围内,随着H2S分压的升高,两种钢的腐蚀速率先增后降,且都在H2S分压为20 kPa时取得最大值.

关键词: H2S分压 , N80钢 , P110钢 , CO2/H2S腐蚀速率

HCl-H2S-H2O体系中HCl与H2S对20碳钢腐蚀的交互作用

郭金彪 , 李艳

材料保护

目前有关HCl-H2S-H2O体系中HCl与H2S对碳钢腐蚀的交互作用的试验数据较少.利用电化学方法测试了20碳钢在90℃,不同浓度的HCl,H2S单一腐蚀液及HCl和H2S混合腐蚀液中的腐蚀速率,分析了HCl-H2S-H2O体系中HCl与H2S对20碳钢腐蚀的交互作用.结果表明:20碳钢在单一的HCl或H2S腐蚀液中的腐蚀速率随HCl或H2S浓度的增大而增大;在HCl-H2S-H2O体系中,不论H2S浓度高低,HCl的存在均会促进H2S对20碳钢的腐蚀;只有当HCl的浓度较低(≤248.72 mg/L)时,H2S的存在才会促进HCl对20碳钢的腐蚀;而当HCl浓度较高(≥499.16 mg/L)时,H2S的存在不仅不会促进HCl对20碳钢的腐蚀,还会在一定程度上起阻碍作用.

关键词: 20碳钢 , HCl , H2S , 腐蚀 , 交互作用

Sulfidation behavior of Fe-40Al sheet in H-2-H2S mixtures at high temperatures

Intermetallics

The sulfidation behavior of a 200 mum thick Fe-40at.%Al sheet has been investigated at temperatures between 973 K and 1273 K in H-2-H2S mixtures with H,S contents of 0.052-9.7vol%. The Fe-40Al sheet exhibited excellent sulfidation resistance at temperatures below 1073 K in all the H2S-H-2 mixtures. This may be attributed to the formation of a thin alumina film on the surface of the Fe-40Al sheet during sulfidation, identified by AES analysis. At temperatures higher than 1173 K, the Fe-40Al sheet also exhibited good sulfidation resistance in the 0.052%H2S-H-2, mixture. and there was only a slight increase in mass gain with tempe rat Lire. This compares favorably with Fe-200-11Al (in at.%) foil which was severely sulfidized even at 973 K in the 0.052% H2S-H-2 mixture, and showed markedly increased mass gain with increased H2S content and temperature. (C) 2004 Elsevier Ltd. All rights reserved.

关键词: iron aluminides (based on FeAl);corrosion;fe-al alloys;corrosion behavior;oxidation behavior;iron aluminides;sulfur vapor;al2o3 scales;1273 k;atmospheres

H_2S石油套管钢的设计

褚武扬 , 王燕斌 , 关永生 , 阎应龙

金属学报

理论研究表明,为满足高强度抗H2S套管钢的使用要求,可选用C,Mn,Cr和Mo为合金元素,要求S,P和Si的含量尽量低,回火温度尽量高.本文用正交设计来确定C,Mn,Cr和Mo的范围.用国外同类钢种的数据代管实验室试验进行正交分析.按设计的成分直接进行批量生产,获得成功,在两年内完成了新钢种的设计,开发和使用.

关键词: H_2S , C90 tubular steel , alloy design

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