周晓华
,
SφrensenO．Toft
,
曹全喜
,
徐毓龙
无机材料学报
本文着重讨论了掺镁SrTiO3陶瓷的电导与温度和环境氧分压之间的关系．在SrTiO3中镁的含量分别选为10、20、30、40和50mol％，所有样品均在20～900℃的温度区间和3．8×10－4～2．6×10－1atm的氧分压范围被测试．结果表明，所有样品均呈现p型半导体的导电特征，样品在不同温度下的R∝P-1/mO2关系中的m与镁的含量和温度有关．根据X光衍射图和缺陷化学理论，实验结果得到适当的解释．
关键词:
钛酸锶陶瓷缺陷化学非化学计量电导率
Ting DU Longmei WANG Yeming WU Yuqing ZHANG Aisheng LIU Central Iron and Steel Research Institute
,
Beijing
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100081
,
China
材料科学技术（英文）
The temperature dependences of the equilibrium constants for the reactions RES_((S))=[RE]+[S]. (RE=Ce,La,Nd,Sm,Y),of the standard Gibbs energies for the RES formed and of the interaction coefficients between RE elements and S for the Fe-base,Ni-base and Cu-base solutions are sum- marized.
关键词:
thermodynamics
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null
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null
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null
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null
Applied Physics Letters
Transport in S(2) molecules sandwiched between Au electrodes is investigated with a combination of density functional theory and the non-equilibrium Green's function method. We consider four different configurations and find that their conductances are related to the details of the bonding geometry. When S(2) connects to pyramidal-shaped electrodes at the top site, the transmission is governed by a resonance and is strongly affected by the bias. In contrast, the transport of the remaining three configurations is through several closely spaced broad molecular orbitals, and the transmission coefficient is almost flat around the Fermi level. (C) 2012 American Institute of Physics. [doi:10.1063/1.3665614]
关键词:
conductance;molecule
YUE Kexiang DONG Yuanchi East China Institute of Metallurgy
,
Ma'anshan
,
China
金属学报(英文版)
The equilibrium constants between Sr-O,Ba-O and Sr-S,Ba-S in liquid iron at 1570℃ and the interaction coefficients concerning these elements have been determined as follows: K_(Sro)=1.897×10~(-7),e_O~(Sr)=-43.8 K_(BaO)=8.204×10~(-8),e_O~(Ba)=-98.0 K_(SrS)=8.356×10~(-7),e_S~(Sr)=-3.9 K_(BaS)=4.083×10~(-7),e_S~(Ba)=-3.5
关键词:
equilibrium
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null
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null
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null
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null
Zeitschrift Fur Metallkunde
Young's equation is discussed on a thermodynamic basis. The result shows that the equation is a thermodynamic equilibrium of the wetting system rather than a force balance. The equilibrium satisfies the general equilibrium condition, that is, Gibbs free energy should be minimum when the wetting equilibrium is reached. The validity of Young's equation is only limited to some special cases, namely if the droplet shape is an exact sphere sector. It implies that Young's equation can only be used in the case without the action of gravity. If the curve of the liquid surface changes, the term of cos theta in Young's equation should be replaced by another functional form of the contact angle theta. In the discussion, the author suggests that, in the case of a solid, the surface energy should be considered rather than the surface tension, and the concept of a solid surface tension should be reconsidered based on the difference between a liquid surface and a solid surface.
关键词:
J.X. Zhou
,
R.X. Liu
,
L.L. Chen
,
D.M. Liao
,
H.S. Wei
金属学报(英文版)
Numerical simulation of casting's mold filling process is the main and the most important aspect of the foundry CAE technology. But it is time-consuming; it may take dozens of hours or several days. While with the development of computer hardware, numerical simulation of casting's mold filling process has made rapid progress. The simulation results, therefore, have become more and more practical. This study tries to find some clues of the computational time of mold filling process. Firstly, this paper introduces mathematic model and the basic route of numerical simulation of casting's mold filling process. Then the computational time of mold filling process has been carefully studied, and some new and useful results have been gained from the study of the computational time. Finally, this paper has given some real applications of numerical simulation of casting's mold filling process.
关键词:
numerical simulation
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null
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null
