K.SOORYAPRAKASH
,
TITUSTHANKACHAN
,
R.RADHAKRISHNAN
中国有色金属学报(英文版)
doi:10.1016/S1003-6326(17)60070-0
利用实验、统计学及人工神经网络方法研究粉末冶金法制备的多壁碳纳米管增强铜基金属复合材料的磨损行为,并探讨多壁碳纳米管含量的影响.测定和分析复合材料样品的显微硬度,设计L16正交实验,采用销盘式摩擦计测定样品的磨损量随载荷和滑动距离的变化.结果表明:铜基金属复合材料的硬度随多壁碳纳米管含量的增加而增加.Taguchi法工艺参数优化结果表明多壁碳纳米管的引入对复合材料磨损量产生较大影响.利用ANOV统计学方法分析和验证了复合材料的抗磨损性能.多壁碳纳米管含量对复合材料磨损量的影响最大(贡献率为76.48%),其次为所加载荷(贡献率为12.18%),最后为滑动距离(贡献率为9.91%).采用具有可变隐含节点的人工神经网络模型对复合材料的磨损过程进行模拟,所得结果的平均误差(MAE)值较低,3-7-1网络拓扑结构的适应性强,所得数据可靠.人工神经网络预测值(相关系数R值为99.5%)与ANOVA统计结果吻合良好,且能用于研究各参数对多壁碳纳米管增强的铜基金属复合材料磨损行为的影响.
关键词:
铜
,
多壁碳纳米管(MWCNT)
,
粉末冶金
,
磨损
,
Taguchi法
,
方差分析(ANOVA)
,
人工神经网络
Communications in Theoretical Physics
The unified theoretical calculation of thermal shifts (TS) of R-1 and R-2 lines and thermal broadenings (TB) of R, R' and B lines for ruby was carried out for the first time. The calculated results are in very good agreement with a great number of experimental data. Especially by using quantum theory and taking into account all the admixtures of wavefunctions within d(3) electronic configuration, all the Gamma M in electron-phonon interaction (EPI), the electronic energy spectrum and lattice-vibration Spectrum, the very important contributions to TS and TB from single-phonon direct process were theoretically calculated in detail. The microscopic essentials of various contributions are revealed, and the mistakes in previous work are remedied.
关键词:
diamond anvil cell;pressure measurement;spectroscopy;temperatures
Communications in Theoretical Physics
On the basis of the unified calculation of the thermal shifts of R-1 line, R-2 line and ground-state-splitting as well as the thermal broadenings of R, R' and B line-groups for ruby, by taking into account all the levels and admixtures of wavefunctions within d(3) electronic configuration and all the GammaM in electron-phonon interaction, the transition probabilities of direct and Raman processes have theoretically been calculated. The thermal broadenings, of R, R' and B line-groups have successfully been interpreted in terms of the direct and Raman processes of acoustic phonons. The theoretically predicted transition probabilities are in good agreement with the experimental ones.
关键词:
crystal fields;electron-phonon interaction;thermal broadening;transition probability;direct and Raman processes;shifts
Transactions of Nonferrous Metals Society of China
Phase equilibria of the R-Fe-Co pseudoternary system with R less than or equal to 33.3% ( mole fraction, R = Sm0.5Dy0.5) were determined in an isothermal section at 1073 K and a vertical section of RFe2-RCo2 by using OM, X-ray diffractometer, EP-MA DTA techniques. There are seven intermetallic phases: (Sm, Dy) (Fe, Co)(2), (Sm, Dy) (Fe, Co)(3), (Sm, Dy)(6) (Fe, Co)(23), (Sm, Dy)(2) (Fe, Co)(7), (Sm, Dy) (Fe, Co)(5), Th2Ni17-type and Th2Zn17-type (Sm, Dy)(2)(Fe, Co)(17). The (Sm, Dy)(6)(Fe, Co)(23) phase dissolves 36% Co(mole fraction) at 1073 K. However, the (Sm, Dy)(2)(Fe, Co)(7) phase in R-2(Fe1-xCox)(7) alloys dissolves about 19% Fe(mole fraction) at 1073 K.
关键词:
rare earth-iron-cobalt;phase diagram;structure;compounds;sm-co;magnetic-properties;binary-system;magnetostriction
YANG Jilian ZHANC Baisheng DINC Yongfan China Institute of Atomic Engergy
,
Beijing
,
ChinaYANG Yingchang ZHANG Xiaodong Peking University
,
Beijing
,
ChinaPAN Shuming General Research Institute for Non-Ferrous Metals
,
Beijing
,
China associate professor
,
P.O.Box 275
,
Branch No.30
,
Beijing 102413
,
China
金属学报(英文版)
The N occupying sites and magnetic structures in R_2Fe_(17)N_x(R=Y,Dy,Nd)are de- termined by neutron diffraction.The effects of the site occupation of N on magnetic properties are discussed primarily.
关键词:
neutron diffraction
,
null
,
null
,
null
,
null
,
null
Journal of Solid State Chemistry
The subsolidus phase relations of R2O3-CaO-CuO ternary systems (R = Nd, Sm, Gd, Tm) have been investigated by X-ray powder diffraction. All samples were synthesized at about 950degrees in air. There exists a ternary compound Ca14-xRxCu24O41 (x = 4 for R = Nd, Gd and x = 5 for R = Sm) and a ternary solid solution Ca2+xR2-xCu5O10 (R = Nd, Sm, Gd, Tm) with a wide composition range Deltax of about 0.6. The compound Ca14-xRxCu24O41 possesses a layered orthorhombic structure and is isostructural to Sr14-xCaxCu24O41. The lattice parameters a and c of the compound are basically independent of the ionic radius of R, while the lattice parameter b and unit-cell volume V decrease substantially with the decrease of the ionic radii of R. The Ca2+xR2-xCu5O10 solid solution is isostructural to Ca2+xY2-xCu5O10, the structure of which is based on an orthorhombic "NaCuO2-type" subcell containing infinite one-dimensional chains of edge-shared square planar cuprate groups crosslinked by the layered cations Ca and R that locate in the inter-chain tunnels. (C) 2002 Elsevier Science (USA). All rights reserved.
关键词:
R2O3-CaO-CuO (R = Nd, Sm, Gd, Tm) systems;phase relations;Ca10R4Cu24O41 (R = Nd, Sm, Gd) structure;Ca2+xR2-xCu5O10 (R = Nd, Sm,;Gd, Tm) structure;ternary-system;approximately 950-degrees-c;high-pressure;superconductivity;diagram;air;er;compatibilities;property;oxide