材料期刊网

R. erythropolis对赤铁矿和石英的吸附?捕收作用

杨慧芬 , 唐琼瑶 , 王传龙 , 张露 , 李甜

中国有色金属学报

为考察红城红球菌(Rhodococcus erythropolis,R. erythropolis)作为赤铁矿捕收剂使用的可能性及效果,对R. erythropolis形貌、细胞壁成分及其吸附前后赤铁矿、石英表面电性、疏水性进行分析,对赤铁矿、石英单矿物以及赤铁矿与石英矿1:1(质量比)混合矿进行浮选实验,对其在赤铁矿表面的吸附状况及吸附机理进行研究.结果表明,杆状R. erythropolis表面既含有非极性基团,又含有极性基团,使得其表面具有较高的负电性和较强的疏水性,因而对赤铁矿的吸附作用明显大于对石英的吸附作用.当以此细菌为捕收剂、在溶液 pH 值为6、R. erythropolis用量为75 mg/L时,赤铁矿的回收率为89.68%,而石英的回收率仅为26.25%.混合矿经过一次浮选,可获得铁品位和回收率分别为50.08%和76.41%的铁精矿.R. erythropolis在赤铁矿表面发生复杂的化学吸附且使赤铁矿颗粒形成疏水絮团,从而证实R. erythropolis可作为赤铁矿的捕收剂使用.

关键词: R. erythropolis , 微生物 , 赤铁矿 , 石英 , 吸附 , 絮团 , 捕收剂

干滑动摩擦条件下Al?Si3N纳米复合材料及 Al?Gr?Si3N4混杂复合材料摩擦磨损性能的优化

R. AMBIGAI , S. PRABHU

中国有色金属学报(英文版) doi:10.1016/S1003-6326(17)60116-X

研究含石墨(Gr)和氮化硅纳米颗粒金属型搅拌铸造LM16合金的摩擦学性能.在干滑动摩擦条件下分别制备Al?Gr?Si3N4混杂复合材料、Al?Si3N4和Al?Gr纳米复合材料.采用EDS测试技术确保Si3N4纳米颗粒和石墨在铸件中的均匀分布.采用L9正交实验方法进行实验以研究应用载荷(20,30和40 N)和滑动距离(1,2和3 km)对合金摩擦磨损性能的影响.结果表明:与Al?Si3N4纳米复合材料相比,Al?Gr?Si3N4混杂复合材料的磨损率和摩擦因数(COF)分别降低了25%和15%,而Al?Gr纳米复合材料的磨损率和COF很小.混杂复合材料的显微维氏硬度比普通复合材料的提高了14%,而Al?Gr和Al?Si3N4纳米复合材料的显微硬度无明显变化.用扫描电镜对合金磨损表面和次表面的组织进行观察.结果表明,纳米复合材料的主要磨损机理为磨粒磨损,而混杂复合材料的主要磨损机理为磨粒磨损和粘着磨损.方差分析(AVOVA)和F检验用于验证模型的有效性及确定影响磨损率的显著性参数.

关键词: 磨粒磨损 , Si3N4 , 石墨 , 混杂复合材料 , 载荷 , 滑动距离 , 方差分析

Subsolidus phase relations and crystal structures of R-Ca-Cu-O (R = Nd, Sm, Gd, Tm) systems

Journal of Solid State Chemistry

The subsolidus phase relations of R2O3-CaO-CuO ternary systems (R = Nd, Sm, Gd, Tm) have been investigated by X-ray powder diffraction. All samples were synthesized at about 950degrees in air. There exists a ternary compound Ca14-xRxCu24O41 (x = 4 for R = Nd, Gd and x = 5 for R = Sm) and a ternary solid solution Ca2+xR2-xCu5O10 (R = Nd, Sm, Gd, Tm) with a wide composition range Deltax of about 0.6. The compound Ca14-xRxCu24O41 possesses a layered orthorhombic structure and is isostructural to Sr14-xCaxCu24O41. The lattice parameters a and c of the compound are basically independent of the ionic radius of R, while the lattice parameter b and unit-cell volume V decrease substantially with the decrease of the ionic radii of R. The Ca2+xR2-xCu5O10 solid solution is isostructural to Ca2+xY2-xCu5O10, the structure of which is based on an orthorhombic "NaCuO2-type" subcell containing infinite one-dimensional chains of edge-shared square planar cuprate groups crosslinked by the layered cations Ca and R that locate in the inter-chain tunnels. (C) 2002 Elsevier Science (USA). All rights reserved.

关键词: R2O3-CaO-CuO (R = Nd, Sm, Gd, Tm) systems;phase relations;Ca10R4Cu24O41 (R = Nd, Sm, Gd) structure;Ca2+xR2-xCu5O10 (R = Nd, Sm,;Gd, Tm) structure;ternary-system;approximately 950-degrees-c;high-pressure;superconductivity;diagram;air;er;compatibilities;property;oxide

R-line thermal shift and thermal broadenings of R, R' and B lines for ruby

Communications in Theoretical Physics

The unified theoretical calculation of thermal shifts (TS) of R-1 and R-2 lines and thermal broadenings (TB) of R, R' and B lines for ruby was carried out for the first time. The calculated results are in very good agreement with a great number of experimental data. Especially by using quantum theory and taking into account all the admixtures of wavefunctions within d(3) electronic configuration, all the Gamma M in electron-phonon interaction (EPI), the electronic energy spectrum and lattice-vibration Spectrum, the very important contributions to TS and TB from single-phonon direct process were theoretically calculated in detail. The microscopic essentials of various contributions are revealed, and the mistakes in previous work are remedied.

关键词: diamond anvil cell;pressure measurement;spectroscopy;temperatures

Theoretical calculations of thermal broadenings and transition probabilities of R, R ' and B line-groups for ruby

Communications in Theoretical Physics

On the basis of the unified calculation of the thermal shifts of R-1 line, R-2 line and ground-state-splitting as well as the thermal broadenings of R, R' and B line-groups for ruby, by taking into account all the levels and admixtures of wavefunctions within d(3) electronic configuration and all the GammaM in electron-phonon interaction, the transition probabilities of direct and Raman processes have theoretically been calculated. The thermal broadenings, of R, R' and B line-groups have successfully been interpreted in terms of the direct and Raman processes of acoustic phonons. The theoretically predicted transition probabilities are in good agreement with the experimental ones.

关键词: crystal fields;electron-phonon interaction;thermal broadening;transition probability;direct and Raman processes;shifts

Phase diagram of R-Fe-Co pseudoternary system with R <= 33.3% (mole fraction, R = Sm0.5Dy0.5)

Transactions of Nonferrous Metals Society of China

Phase equilibria of the R-Fe-Co pseudoternary system with R less than or equal to 33.3% ( mole fraction, R = Sm0.5Dy0.5) were determined in an isothermal section at 1073 K and a vertical section of RFe2-RCo2 by using OM, X-ray diffractometer, EP-MA DTA techniques. There are seven intermetallic phases: (Sm, Dy) (Fe, Co)(2), (Sm, Dy) (Fe, Co)(3), (Sm, Dy)(6) (Fe, Co)(23), (Sm, Dy)(2) (Fe, Co)(7), (Sm, Dy) (Fe, Co)(5), Th2Ni17-type and Th2Zn17-type (Sm, Dy)(2)(Fe, Co)(17). The (Sm, Dy)(6)(Fe, Co)(23) phase dissolves 36% Co(mole fraction) at 1073 K. However, the (Sm, Dy)(2)(Fe, Co)(7) phase in R-2(Fe1-xCox)(7) alloys dissolves about 19% Fe(mole fraction) at 1073 K.

关键词: rare earth-iron-cobalt;phase diagram;structure;compounds;sm-co;magnetic-properties;binary-system;magnetostriction

NEUTRON DIFFRACTION STUDY ON R_2Fel_(17)N_x(R=Y,Dy,Nd)

YANG Jilian ZHANC Baisheng DINC Yongfan China Institute of Atomic Engergy , Beijing , ChinaYANG Yingchang ZHANG Xiaodong Peking University , Beijing , ChinaPAN Shuming General Research Institute for Non-Ferrous Metals , Beijing , China associate professor , P.O.Box 275 , Branch No.30 , Beijing 102413 , China

金属学报(英文版)

The N occupying sites and magnetic structures in R_2Fe_(17)N_x(R=Y,Dy,Nd)are de- termined by neutron diffraction.The effects of the site occupation of N on magnetic properties are discussed primarily.

关键词: neutron diffraction , null , null , null , null , null

SPIN REORIENTATION AND EXCHANGE INTERACTIONS IN (ND, R)2FE14B (R = Y, GD)

Journal of Magnetism and Magnetic Materials

Exchange fields in both (Nd, Y)2Fe14B and (Nd, Gd)2Fe14B series are determined by analyzing spin reorientation. Results calculated for the two systems suggest that the R-R exchange interactions between R ions are comparable with the crystal-field interaction and that their effect might be taken into account for reproducing the spin-reorientation temperature.

关键词: magnetization process;crystal;nd2fe14b;r2fe14b;transition

R&D STATUS ON INTERMETALLICS IN CHINA

CHEN Guoliang(State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing Beijing 100083 , China)SHI Changxu (Academia Sinica , Beijing 100864 , China)

金属学报(英文版)

This paper briefiy introduces the R&D of intermetallics in China. R&D on intermetallics in a national scale in China began near ten years ago. The investigation in past years focused on the fundamental research and materials development. A significant progress has been made. Various components that made of Ti3Al Ni3Al, TiAl and Fe3Al have been successfully manufactured Some of them have been evaluted. It is expected that some intermetallic alloys will be produced in an industrial scale in the near future.

关键词: :intermetallic alloys , null , null , null

R & D ACTIVITIES ON AEROSPACE MATERIALS IN KOREA

H.M. Kim(Korea Institute of Machinery and Materials , Korea Manuscript received 26 August 1996)

金属学报(英文版)

This paper briefly reviews research and development programs in Korean aerospace industry,with an emphasis on aircraft materials technology. International collaborations in these areas are outlined and the R & D activities are highlighted against the　background of the national economy.It is shown that the investment from government agencies and large enterprises has led to healthy development of aerospace materials industries in Korea.

关键词: :R & D , null , null , null