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WIDE-BAND LASER CLADDING: WEAR AND CORROSION RESISTANCE OF A Ni-BASED ALLOY

Q. Y Pan , WD. Huang , YM. Li , X. Lin , YH. Zhou and X.C. Yan( State Key Lab. of Solidification Processing , Northwestern Polytechnical University , Xi'an 710072 , China ( Laser Processing Center , Tianjin College of Textile Technology , Tianjin 300160 , China )

金属学报(英文版)

A novel wide-band laser cladding system, with high rate of cladding, has been developed in the present work. The system mainly consisted of a 5kW CO2 laser, an automatic Fowder feeder and a wide-band scanning rotative polygon mirmr which can produce a linear or rectangular focused laser beam. Using this system, a Ni-Cr-Si-B alloy powder was cladded on the sudece of tgpe 321 austenitic stainless steel in onder to improve its wear and cormsion resistance. The pitting cormsion, high temperuture oxidation and wear tests were conducted in onder to evaluate the propertles of the laser cladded layer. The results demonstrated that the cladded layer can significantly improtte the adhesive wear and pitting cormsion resistance of the substmte. Moreover,the cladded layer exhibited good oxidafion resistance, which is almost the same as that of GMR-235D N-based superalloy.

关键词: austenitic stainless steel , null , null , null

Q235钢基体LZAS微晶玻璃/Y-TZP梯度涂层接触应力的数值模拟

龚伟 , 周黎明 , 王恩泽 , 白朝中

材料工程 doi:10.11868/j.issn.1001-4381.2014.09.004

运用有限元软件对Hertz接触状态下Q235钢基体LZAS微晶玻璃/Y-TZP梯度涂层的接触应力进行了分析.讨论了梯度层厚度、梯度层层数和物性参数渐变方式(3Y TZP体积组分差)对涂层接触应力分布情况的影响.结果表明:涂层的径向接触应力和Mises应力的最大值位于接触中心处,最大剪切应力则位于涂层表层下方靠近接触中心处;涂层表面径向应力、整体最大Mises应力和涂层/基体界面剪应力与涂层的层数、厚度以及3Y-TZP体积组分差均有密切关系.

关键词: 功能梯度涂层 , 接触应力 , 有限元分析 , 应力分布

聚苯胺链段含量对PAn-g-PEG/LiClO4电流变性能的影响

马会茹 , 官建国 , 袁润章

功能材料

用化学氧化共聚法制备了聚乙二醇-接枝-聚苯胺(PAn-g-PEG)纳米粒子,并将其与LiClO4形成的络合物粒子分散到硅油中得到了无水电流变(ER)液.研究了PAn-g-PEG中的聚苯胺链段含量(y/x)对ER液性能的影响.结果表明PAn-g-PEG在水溶液中能自组装形成核壳结构,PAn-g-PEG/LiClO4络合物ER液的流变性能对电场能产生显著和快速的响应.随着y/x的增加,ER液的电致剪切应力在y/x=64时出现最大值,漏电流单调降低.

关键词: 聚乙二醇-接枝-聚苯胺 , 核壳粒子 , 电流变液

PAN基炭纤维经济规模分析

夏春霞 , 闫亚明 , 邓蜀平 , 白光君 , 蒋云峰 , 宋惠森 , 王钰

新型炭材料 doi:10.3969/j.issn.1007-8827.2001.04.013

聚丙烯腈(Polyacrylonitrile缩写为PAN)基炭纤维市场需求旺盛,但由于我国PAN基炭纤维生产企业规模小、产品性能低,产品占领不了市场,企业效益欠佳.通过经济规模方法的分析,就国内现有技术状况和两个样本生产线,用工程技术法对PAN基炭纤维的经济规模进行分析,为我国炭纤维产业化发展提供参考.分析表明,国内PAN基炭纤维经济规模的起点为200t/a~275t/a.

关键词: PAN基炭纤维 , 经济规模 , 工程技术法

PAN/PI复合纤维的结构

李常清 , 袁姗 , 罗荣 , 郭雅明 , 徐樑华

高分子材料科学与工程

将聚酰亚胺(PI)加入丙烯腈-衣康酸-二甲基亚砜体系进行聚丙烯腈(PAN)溶液聚合,湿法纺丝制备了PAN/PI复合纤维.利用流变仪、红外光谱、X射线衍射仪、扫描电镜、差示扫描量热仪等研究了PAN/PI溶液的性质和复合纤维的结构特点.研究发现,加入PI后,聚合物溶液的稳态黏度降低,弹性和粘性模量在低剪切速率区降低;PI作为成核剂,引起初生纤维结晶度增大、晶粒尺寸减小;PI与PAN的溶解性差异导致凝固加快,初生纤维形成皮芯结构;引起原丝体密度减小.PAN/PI纤维在N2下放热量较少,在空气中由于结构疏松放热量较大.

关键词: 聚丙烯腈纤维 , 聚酰亚胺 , 原液改性 , 晶态结构

PAN初生纤维拉伸性能试验研究

谢奔 , 朱波 , 王政 , 井敏 , 王进军 , 张春雷 , 吴益民

功能材料

为了提高聚丙烯腈(PAN)初生纤维的可拉伸性能,将溶液纺丝得到的初生纤维进行不同时间的恒温干燥处理,研究其拉伸性能随干燥时间的变化规律。结果表明,干燥处理可以大幅度提升PAN初生纤维的力学性能,其拉伸强力可达10.3cN,断裂伸长可达263.5%;随着干燥时间的延长,纤维的可拉伸性能增强,经过10h干燥后的初生纤维具有最佳可牵伸性能;而拉伸速率的提高可以有效促进未干燥初生纤维的拉伸变形,而对干燥处理后纤维的拉伸性能的影响不大。用SEM观察纤维断裂形貌发现,PAN纤维的致密性随牵伸比的增加而提高。

关键词: 聚丙烯腈 , 初生纤维 , 干燥 , 拉伸性能 , 断裂形貌

Effect of carbonization atmosphere on the structure changes of PAN carbon membranes

Journal of Porous Materials

PAN carbon membranes were prepared by carbonizing the initial PAN membranes in vacuum and Ar at different temperatures. FTIR, Raman and XRD were applied to study the influence of carbonization atmosphere on the structure changes of PAN carbon membranes. The variations in adsorption peaks of FTIR, the intensity, position and FWHM of the Raman peaks, and microcrystallite parameters from XRD (e.g., d(002), Lc and La) are correlated with the structure change of PAN carbon membranes. Analyses results reveal that vacuum atmosphere can produce PAN carbon membranes with higher order degree than those in Ar atmosphere, although the structures of PAN carbon membranes prepared in the two atmospheres are both amorphous. In addition, vacuum atmosphere can significantly accelerate the degradation reaction of PAN membranes and favors the preparation of carbon membranes with smaller pore size.

关键词: Carbonization;Atmosphere;Carbon membranes;PAN;Structure;molecular-sieve membranes;gas separation membranes;phenolic resin;pyrolysis conditions;thermal-degradation;polyimide;polyacrylonitrile;deposition;graphite;kapton

New Evaluation on the Preoxidation Extent of Different PAN Precursors

Wangxi ZHANG , Jie LIU , Jieying LIANG , null , null , null

材料科学技术(英文)

Structural changes in carbon fibers at each stage of, especially, preoxidation process are well known to play a great role in achieving the ultimate product quality. Differential scanning calorimetry (DSC), scanning electron microscope (SEM), density method and optical microscope were used to characterize the preoxidation extent. A conventional approach, e:g., density aim, to evaluate the extent of preoxidation is not very exact. A DSC curve of a PAN precursor only can provide general information, major in the temperature regime of preoxidation reaction. However, the evaluation of a preoxidation extent, especially from conventional preoxidation temperature with a great span regime of 200~400℃, is put forward in this paper, in which the evolution of core/shell morphological structure is a kind of straightforward evidence.

关键词: Preoxidation , null , null

UHMW-PAN中空纤维膜的研制及应用(Ⅰ)--UHMW-PAN的合成

沈新元 , 朱新远 , 郝建斌 , 王庆瑞

膜科学与技术 doi:10.3969/j.issn.1007-8924.1998.03.007

为制备强度较高、适合反冲洗的中空纤维膜,以水相悬浮聚合法制备得到UHMWPAN,研究了引发剂用量、单体浓度、聚合温度、聚合时间、搅拌速度和聚合釜大小对聚合物分子量的影响,在此基础上确定了制备所需UHMW-PAN的合适工艺条件.

关键词: 中空纤维膜 , 超高分子量 , 聚丙烯腈 , 水相悬浮聚合

粒子增强PAN支撑膜的研究

葛继均 , 周花 , 崔永芳 , 张志英

高分子材料科学与工程

对无机粒子填充的PAN渗透蒸发支撑膜进行了初步的研究.考察了不同填充量和填充体系及拉伸热定型的后处理工艺对膜通量和粘弹性的影响.结果表明,不同填充量和填充体系对膜通量及粘弹性的影响不明显;而拉伸和热定型的后处理工艺条件对膜通量和粘弹性有较大的影响.随拉伸比的提高,膜通量迅速增大,膜的稳定性变好,具有很好的耐热性,而膜的截流率却几乎不变.此外,还就膜的耐热机理进行了初步探讨.

关键词: 聚丙烯腈 , 无机粒子 , 支撑膜 , 耐热性机理

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