ZHOU Qianli DU Ting Central Iron and Steel Research Institute
,
Ministry of Metallurgical Industry
,
Beijing
,
China DU Ting Senior Engineer
,
Laboratory No.16
,
Central Iron and Steel Research Institute
,
Ministry of Metallurgical Industry
,
No.76 Xueyuannanlu
,
Beijing
,
China
金属学报(英文版)
The influence of Sb on the C solubility in liquid Fe was measured under 1300,1400 and 1500℃.The C solubility decreases with the increase of Sb content in liquid Fe.The tem- perature dependences of the first order interaction coefficients in C-saturated liquid Fe were determined as follows: *e_C~(Sb)=11.309/T+0.0025 *e_(Sb)~C=128.023/T-0.0219 The temperature dependences of interaction coefficients between Sb and C in dilute liquid Fe were given to be: e_C~(Sb)=14.204/T+0.025 e_(Sb)~C=120.541/T+0.227 ε_C~(Sb)=ε_(Sb)~C=6026.75/T+11.958 The interaction coefficients at 1600℃ are *e_C~(Sb)=0.0085,e_C~(Sb)=0.033,*e_(Sb)~C=0.295, ε_C~(Sb)=ε_(Sb)~C=15.36.The first order interaction coefficients vary slightly with the temperature.
关键词:
Fe-C-Sb solution
,
null
,
null
,
null
Journal of Applied Physics
The effect of Co substitution on structure, phase transformation, and magnetic properties of R(16)Fe(76-x)Co(x)C(8) (R equivalent to Nd, Dy; 0 <= x <= 76) alloys prepared by a remilling process has been studied systematically. The process of remilling and subsequent annealing is more beneficial for the formation of Nd(2)(Fe,Co)(14)C compound in Nd(16)Fe(76-x)Co(x)C(8) alloys than in Dy(16)Fe(76-x)Co(x)C(8) alloys. The R(2)(Fe,Co)(14)C phase is obtained for Nd(16)Fe(76-x)Co(x)C(8) alloys with 0 <= x <= 20 and Dy(16)Fe(76-x)Co(x)C(8) alloys with 0 <= x <= 25. Higher Co content results in the formation of Nd(2)(Fe,Co)(17)C(delta)-type phase and Dy(Fe,Co)(7) phase for Nd(16)Fe(76-x)Co(x)C(8) and Dy(16)Fe(76-x)Co(x)C(8) alloys, respectively. The high coercivity, (i)H(c)=48.5 kOe, is achieved for Dy(16)Fe(51)Co(25)C(8) alloy. (C) 2008 American Institute of Physics.
关键词:
permanent-magnets;r2fe14c;carbides;carbon
全裕霞
,
孙乾耀
,
刘植昌
,
徐春明
,
硅酸盐通报
doi:10.3969/j.issn.1001-1625.2007.05.034
利用廉价的水玻璃为二氧化硅前驱体,在三嵌段高分子EO76PO29EO76/正丁醇/乙醇/水的乳液体系中,能够使二氧化硅快速沉降,缩聚并形成中空的氧化硅巨球,球径达30～40 μm左右,用SEM、TEM、BET、光学显微镜、SAXS、29Si MAS NMR详细考察了产物的形貌特点以及形成过程.
关键词:
空心球
,
多级形貌
,
硅酸盐
,
嵌段聚合物
Wenli PEI
,
Fazeng LIAN
,
Guiqin ZHOU
材料科学技术（英文）
In this paper, the technology, structures and magnetic properties of Nd4.5Fe76Co1B18.5 nanocomposite magnets were investigated. The effect of crystallizing treatment temperature and time on structures and magnetic properties of Nd4.5Fe76Co1B18.5 amorphous ribbons was studied. The results show that Nd4.5Fe76Co1B18.5 containing more analogue metals is easy to form a morphous. The magnetic properties of 16 m/s quenched ribbon for 710 degrees Cx900 s crystallizing treatment reach H-i(c)=242.1 kA/m, B-r=0.9410 T and (BH)(max)=59.64 kJ/m(3). The even grain size is about D-Fe3B=34 nm and D-Nd2Fe14B=23 nm.
关键词:
International Journal of Hydrogen Energy
Mg76T12Fe12-xNix (x = 0, 4, 8, 12) alloys were prepared by mechanical alloying and the hydrogen storage properties were investigated C systematically. In Mg76Ti12Fe12 and Mg76Ti12Ni12Ti12 alloys, the main binary alloy phase is Fe2Ti and Mg2Ni, respectively. There are same binary alloy phase structures included Fe2Ti, Mg2Ni and NiTi in Mg(76)Ti(12)Fc(8)Ni(4) and Mg76Ti12Fe4Ni8 alloys. For Mg76Ti12Fe12-xNix (x = 0, 4, 8, 12) alloys, the hydrogen storage capacity is 2.88, 3.31, 3.12 and 2.24 wt%, respectively. The hysteresis between hydrogen absorption and desorption decreases gradually with increasing the amount of substitution Ni for Fe. Mg76Ti12Fe8Ni4 shows the highest hydrogen absorption and desorption rate among Mg76Ti12Fe12-xNix (x = 0, 4, 8, 12) alloys. Fe and Ni coexistence is favorable to improve hydrogen storage properties. For Mg76Ti12Fe8Ni4 alloy, the amorphous degree increase with the milling time, and the amorphous degree increase is unfavorable to improve hydrogen storage capacity. (C) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
关键词:
hydrogen storage alloy;thermodynamic performances;hydrogen storage;properties;mg-ni;hydriding properties;ti;atmosphere;systems;mn
Journal of the Less-Common Metals
The influence of partial C substitution for B on structural and magnetic properties of Nd17Fe76(B(1-x)C(x))7 alloys has been studied. It has been discovered that the stable hard magnetic phase Nd2Fe14(B,C) with the tetragonal structure can be formed if x < 0.9. As the C content increases, the lattice constant a is nearly constant whereas c decreases linearly. Furthermore, with increasing C content , the microstructure of cast alloys and sintered magnets varies. The temperature dependence of the anisotropy field H(A) and the coercivity i(H)c of the Nd17Fe76(B(1-x)C(x)7 alloys was measured from room temperature up to about 300-degrees-C. The anisotropy field H(A) increases whereas the coercivity i(H)c decreases greatly with increasing C content.
关键词:
r2fe14c
Journal of Physics-Condensed Matter
The x-ray photoelectron spectrum (XPS) and the superconducting critical temperature T-c have been measured for the metallic glass Zr-76(FexCu1-x) with x = 0.1, 0.2, 0.4, 0.6, 0.8 and 1.0. The results show that the density of electron states at the Fermi level increases while T-c decreases as the amount of Fe increases. This implies the spin fluctuation role depresses T-c effectively. The McMillan equation including the spin fluctuation effect has been used to estimate the T-c behaviour. The doping effects of elemental Fe in this system are discussed.
关键词:
fe-zr;alloys
赵广军
,
曾雄辉
,
徐军
,
徐月泉
,
周永宗
人工晶体学报
doi:10.3969/j.issn.1000-985X.2003.04.008
首次采用温度梯度法(TGT)成功生长了直径为76mm高光学质量的Ce:YAG高温闪烁晶体,采用ICP-AES测试了Ce离子在Ce:YAG晶体中的分凝系数约为0.082.在室温下,测试了原生态Ce:YAG晶体的吸收光谱和X射线激发发射光谱(XEL).吸收光谱显示了Ce3+离子的3个特征吸收带,对应的中心波长分别为223nm,340nm及460nm;XEL发射谱表明Ce:YAG的发射峰为550nm,能与硅光二极管有效地耦合.
关键词:
无机闪烁晶体
,
Ce:YAG
,
温度梯度法
,
光谱测量
WANG Ruikun SUN Lihong LI Dongpei YING Qiming T.Takeyama General Research Institute for Non-Ferrous Metals
,
Beijing
,
China [Originally published in ACTA METALL SIN (CHINESE EDN) 24 (5) 1988 pp B353—B358
,
received 6 May 1987
,
in revised form 6 February 1988] T.Takeyama is an emeritus professor of HOKKAIDO University
,
Japan
,
and now is a technical adviser of GRINFM
金属学报(英文版)
The magnetic domain structure and related magnetic properties of (NdPr)_(16)Fe_(76)B_8 permanent magnet have been studied by colloid-SEM method.In thermally demagnetized state,the ma- trix grains in the magnet generally exhibit multidomain structure,i.e.,180° plate-like indi- vidual domain and a few spike-like or maze-like domains.The average width of the domain measured was 1.5μm.Grain size of single-domain was observed to be generally about 1μm and only a few up to 3μm.The results calculated are:the domain wall energy γ=36 MJ/m~2,the exchange constant A=4.5×10~(-11)J/m,the domain wall width δ=15.7nm, and the critical grain diameter of single-domain D_c=0.5μm.The dependence of high magnet- ic field gradient at grain boundaries in different magnetization directions in the adjacent mag- netic domains located on both sides of grain boundaries and the effect of microstructure on the values of K,A and δ were discussed.
关键词:
Nd-Fe-B permanent magnet
,
null
,
null
