{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"研究了阳离子和自由基引发剂对混杂体系<span style=\"color:red\">动力学</span>以及丙烯酸酯种类和含量对混杂体系光固化膜<span style=\"color:red\">力学</span>性能的影响.结果表明,在阳离子<span style=\"color:red\">聚合</span>体系中,引发剂6976具有较高的引发活性,双键的转化率随其质量分数的增加而提高,而环氧转化率在其质量分数为3%时存在一个最优值;混杂体系自由基引发剂以651的增感作用最为明显,随着651质量分数的增加,环氧的转化平衡时间减少,当其质量分数为0.5%时,环氧转化平衡时间为8 min,双键转化率达到100%,双键的最大转化速率达到11.5 min-1.动态<span style=\"color:red\">力学</span>热分析和静态<span style=\"color:red\">力学</span>性能测试表明,改变丙烯酸酯单体的含量和官能度,可有效改善固化膜的<span style=\"color:red\">力学</span>性能,当,m(CER-170):m(TPGDA)为2:1～1:4时,混杂体系玻璃化温度为34～44℃,固化膜拉伸模量为25～90 MPa,柔韧性为7,硬度为3H～6H.","authors":[{"authorName":"葛春丽","id":"e37be9a0-12b8-4b89-ba60-ec4aeee9adf1","originalAuthorName":"葛春丽"},{"authorName":"何勇","id":"ca06c7d3-4437-40ad-a532-d05e2dd7016f","originalAuthorName":"何勇"},{"authorName":"聂俊","id":"aba0b5e7-2674-4b59-96e4-3d1e71ba4fd8","originalAuthorName":"聂俊"}],"doi":"","fpage":"65","id":"614b51df-472e-49f0-9cb5-7a26b7b4129f","issue":"9","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰   "},"keywords":[{"id":"8641c0f8-5bdc-4053-a46e-3dc7e47ef9e9","keyword":"环氧-丙烯酸酯混杂体系","originalKeyword":"环氧-丙烯酸酯混杂体系"},{"id":"802cdc04-cf2f-41bf-95ee-f33518a3c6d1","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"a17a901c-7754-4143-963c-e6df4c43d485","keyword":"<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>","originalKeyword":"光聚合动力学"},{"id":"aa9f277b-ce0a-443b-a088-6a3e7128aa9e","keyword":"引发剂","originalKeyword":"引发剂"},{"id":"e694a6f2-ee0a-4f96-8350-dcdf994b6349","keyword":"单体","originalKeyword":"单体"}],"language":"zh","publisherId":"ddyts200909018","title":"环氧-丙烯酸酯混杂体系<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>及其<span style=\"color:red\">力学</span>性能的研究","volume":"28","year":"2009"},{"abstractinfo":"利用实时红外对由<span style=\"color:red\">光</span>引发剂2,2′,5-三(2-氟苯基)-4-(3,4-二甲氧基苯基)-4′,5′-二苯基-1,1′-二咪唑(WJ-HABI)、增感剂4,4—二(N,N′—二甲基氨基)苯甲酮(EMK)及供氢体N-苯基甘氨酸(NPG)组成的复合引发体系进行<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>研究.探讨了复合引发体系的浓度、不同配比、紫外<span style=\"color:red\">光</span>的强度及不同官能度单体等因素对光<span style=\"color:red\">聚合动力学</span>的影响.结果表明,增感剂(EMK)的加入能使WJ-HABI复合体系的紫外吸收波长向长波移动；随着引发体系浓度的增大、紫外光强度升高,双键转化率及<span style=\"color:red\">聚合</span>速率增大,且<span style=\"color:red\">聚合</span>体系达到最高转化率所需时间越少.","authors":[{"authorName":"彭呈","id":"61b02c7e-e731-4d14-a04c-6e73e778058b","originalAuthorName":"彭呈"},{"authorName":"王克敏","id":"0abe6940-fa35-40fc-97bd-262eefdf0944","originalAuthorName":"王克敏"},{"authorName":"路健","id":"e29693a3-d616-4674-99ce-fe25f8d09212","originalAuthorName":"路健"},{"authorName":"钱晓春","id":"a62cb695-98fb-4186-a8fc-d3d2d96a6b66","originalAuthorName":"钱晓春"},{"authorName":"蒋姗","id":"ef6d2949-7e76-4c40-aabd-70ebf781ce1a","originalAuthorName":"蒋姗"},{"authorName":"聂俊","id":"d8320599-bbd9-4d2f-b774-5f2d0f53e83a","originalAuthorName":"聂俊"},{"authorName":"马贵平","id":"108cf1b3-5216-4297-98dd-cab90f8d2f08","originalAuthorName":"马贵平"}],"doi":"","fpage":"299","id":"860fe932-4899-4a04-b4cd-f2f53275eeb5","issue":"4","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"ed044138-0d4e-4149-bed4-59f01323aa56","keyword":"<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>","originalKeyword":"光聚合动力学"},{"id":"96af9506-1ca1-4d86-8d58-7a0bda823113","keyword":"<span style=\"color:red\">光</span>引发剂","originalKeyword":"光引发剂"},{"id":"d7aeaf32-819c-43b2-b3c8-bcff3da44140","keyword":"增感剂","originalKeyword":"增感剂"},{"id":"222ab4eb-b138-4f96-8109-f265d40db04d","keyword":"供氢体","originalKeyword":"供氢体"},{"id":"6cf06a14-e166-47c6-9cdb-80edacef40a9","keyword":"实时红外","originalKeyword":"实时红外"}],"language":"zh","publisherId":"ggkxyghx201204007","title":"2,2′,5-三(2-氟苯基)-4-(3,4-二甲氧基苯基)-4′,5′-二苯基-1,1′-二咪唑复合引发体系<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>性能研究","volume":"30","year":"2012"},{"abstractinfo":"采用偶氮二异丁脒盐酸盐(AIBA)作为<span style=\"color:red\">光</span>引发剂,<span style=\"color:red\">光</span>引发<span style=\"color:red\">聚合</span>并研究了阳离子表面活性单体--甲基丙烯酰氧乙基二甲基苄基氯化铵(DMBAC)的均聚及其与丙烯酰胺(AM)共<span style=\"color:red\">聚合</span>反应的<span style=\"color:red\">动力学</span>行为,<span style=\"color:red\">聚合</span>反应均在高于DMBAC临界胶束浓度(CMC)的条件下进行.研究结果显示DMBAC均<span style=\"color:red\">聚合</span>反应速率与引发剂浓度的0.29次方以及单体浓度的0.89次方成正比,均<span style=\"color:red\">聚合</span>反应的表观活化能约为13.74 kJ/mo1;DMBAC与AM共<span style=\"color:red\">聚合</span>反应速率与引发剂浓度的0.82次方以及单体总浓度的0.83次方成正比,共<span style=\"color:red\">聚合</span>反应的表观活化能约为10.97 kJ/mo1;同时测得DMBAC与AM共<span style=\"color:red\">聚合</span>反应的单体竞聚率为r1=0.27(AM)、r2=2.00(DMBAC),说明AM趋向于形成共聚物,而DMBAC更趋向于形成均聚物.","authors":[{"authorName":"李万刚","id":"9e33bfa9-e22e-45d5-9bf1-1a03ceb0db97","originalAuthorName":"李万刚"},{"authorName":"王桂霞","id":"62522826-1171-4dc9-9acb-afc70e7680c0","originalAuthorName":"王桂霞"},{"authorName":"张玉玺","id":"0bbce2e6-ca5e-4b29-9aa5-e9c06ce6ff87","originalAuthorName":"张玉玺"},{"authorName":"李振泉","id":"1d372f33-75a7-475a-964e-c7645db61f15","originalAuthorName":"李振泉"},{"authorName":"曹绪龙","id":"133f28d6-659e-4247-9a7f-a38b42f3ae59","originalAuthorName":"曹绪龙"},{"authorName":"宋新旺","id":"e683d190-179a-4604-a58e-361441134bec","originalAuthorName":"宋新旺"},{"authorName":"吴飞鹏","id":"b5e284a1-d125-445a-9c87-88b7fa8bcece","originalAuthorName":"吴飞鹏"}],"doi":"","fpage":"351","id":"c6fa585c-2f87-418a-bfe4-8c421b67d7df","issue":"5","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"012ddc9b-d059-4d1a-9cb6-b7eac37f465d","keyword":"<span style=\"color:red\">光</span><span style=\"color:red\">聚合</span>","originalKeyword":"光聚合"},{"id":"f35033cd-3171-4ec5-bc84-cdb3ad22ed5c","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"},{"id":"67e7bba4-339e-43dc-adc8-20d3f30fb1f6","keyword":"表观活化能","originalKeyword":"表观活化能"},{"id":"5abb0162-7734-4df4-aa01-584b68159b3d","keyword":"竞聚率","originalKeyword":"竞聚率"},{"id":"f48c8827-f741-420a-bbba-986e34d112cf","keyword":"胶体滴定法","originalKeyword":"胶体滴定法"}],"language":"zh","publisherId":"ggkxyghx200905005","title":"表面活性单体DMBAC<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>研究","volume":"27","year":"2009"},{"abstractinfo":"采用实时红外技术对所合成的活性稀释剂吡咯烷基-N-甲酸-丙烯酸乙二醇酯的<span style=\"color:red\">聚合动力学</span>进行了测试.研究了光强、引发剂浓度及引发剂种类对其<span style=\"color:red\">光</span><span style=\"color:red\">聚合</span>的影响.结果表明:光强越强、引发剂浓度越大,<span style=\"color:red\">聚合</span>速率越高,但是反应的最终双键转化率基本不变,均能达到100%左右.引发剂种类对其<span style=\"color:red\">光</span><span style=\"color:red\">聚合</span>的最终双键转化率的影响不是特别明显,但对<span style=\"color:red\">聚合</span>速率有一定的影响.","authors":[{"authorName":"李振风","id":"44ab7b09-2dd4-40a8-b8b7-8c7356f3f165","originalAuthorName":"李振风"},{"authorName":"聂俊","id":"ab51fddb-9ab3-4a47-878f-81bfa32fc6e2","originalAuthorName":"聂俊"}],"doi":"","fpage":"206","id":"7c081632-7dd0-4d81-b2fe-e48c0ebaee16","issue":"3","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"25f10f16-7ba3-46d4-86cd-b9f14dd2a474","keyword":"活性稀释剂","originalKeyword":"活性稀释剂"},{"id":"98b307c4-03c9-4c96-a599-71a52b3aa5b9","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"},{"id":"5d8bff11-dd6a-4d52-bed7-1572aa70cb91","keyword":"光强","originalKeyword":"光强"},{"id":"64a05949-6ee3-45d7-aca9-034e129fe3d6","keyword":"引发剂浓度","originalKeyword":"引发剂浓度"},{"id":"17f69e38-6b73-4d05-9b5c-e986eb3c2c0f","keyword":"引发剂种类","originalKeyword":"引发剂种类"}],"language":"zh","publisherId":"ggkxyghx200803005","title":"吡咯烷基-N-甲酸-丙烯酸乙二醇酯<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>的研究","volume":"26","year":"2008"},{"abstractinfo":"本文研究了对2,2′-二邻甲氧基苯基-4,4′,5,5′-四苯基-l,2′-二咪唑(BMOIM)复合<span style=\"color:red\">光</span>引发体系引发<span style=\"color:red\">聚合动力学</span>过程.采用紫外光谱仪对引发剂、供氢体、增感剂在紫外区的吸收谱图进行了表征.利用实时红外光谱仪对复合<span style=\"color:red\">光</span>引发体系引发<span style=\"color:red\">聚合动力学</span>过程进行实时监测,考察了不同光强、引发剂浓度以及不同官能度单体对反应速率及最终双键转化率的影响.结果表明,在引发剂浓度为0.6％(质量分数)时,20s内双键转换率达到96％,随着引发剂浓度的提高,<span style=\"color:red\">聚合</span>速率增大.<span style=\"color:red\">聚合</span>速率以及最终双键转化率随着光强增大而增大；双官能团单体的最终双键转化率比三官能团单体的最终双键转化率要高.","authors":[{"authorName":"陈洁","id":"890d2882-5af2-4489-a01c-d2e298f62131","originalAuthorName":"陈洁"},{"authorName":"王克敏","id":"7d3d1a19-1074-47d8-8e77-3156cbe4a396","originalAuthorName":"王克敏"},{"authorName":"路健","id":"6a8df524-d805-4f29-958f-2d928f10f789","originalAuthorName":"路健"},{"authorName":"蒋姗","id":"8f22a1b2-536b-4087-840d-b83812e32c6b","originalAuthorName":"蒋姗"},{"authorName":"聂俊","id":"68ea77e4-dc84-4332-bd67-b48404924620","originalAuthorName":"聂俊"},{"authorName":"马贵平","id":"4b64ee57-0072-4aca-80ed-bbcc1a0aeedd","originalAuthorName":"马贵平"},{"authorName":"钱晓春","id":"ce5d2f12-1390-4b81-a9e3-f60ba96ddd2b","originalAuthorName":"钱晓春"}],"doi":"","fpage":"210","id":"0e74cbf0-c140-4026-a878-498bfb3c08ff","issue":"3","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"6c6365d4-4641-4466-b396-8c829d6f35c0","keyword":"<span style=\"color:red\">光</span>引发剂","originalKeyword":"光引发剂"},{"id":"0ac04022-fc7a-4bc4-9f75-f67da0ec3bcb","keyword":"<span style=\"color:red\">光</span><span style=\"color:red\">聚合</span>","originalKeyword":"光聚合"},{"id":"a615f6d6-b27b-4f8b-a839-16fd6905c50e","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"},{"id":"405153e1-c19d-4286-9eec-6a4887fd1560","keyword":"实时红外","originalKeyword":"实时红外"}],"language":"zh","publisherId":"ggkxyghx201203006","title":"2,2′-二邻甲氧基苯基-4,4′,5,5′-四苯基-1,2′-二咪唑复合<span style=\"color:red\">光</span>引发体系的<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>研究","volume":"30","year":"2012"},{"abstractinfo":"研究了功能性单体MAA的加入方式、乳化剂量和单体的加料速率等因素对MAA存在下VAc／BA核壳乳液<span style=\"color:red\">聚合动力学</span>的影响，同时探讨了<span style=\"color:red\">动力学</span>对胶粒形态变化和羧基分布的影响。研究表明，功能性单体MAA的加入方式不同会影响到壳层<span style=\"color:red\">聚合</span>阶段的溶胀，因而，使形成壳层的机理不同。乳化剂量和加料速率分别通过影响胶粒数和总体反应速率系数而对胶粒溶胀和壳层<span style=\"color:red\">聚合</span>反应产生影响。由于胶粒内<span style=\"color:red\">聚合</span>物浓度高、粘度大，因而胶粒形态变化受<span style=\"color:red\">动力学</span>影响甚大，羧基分布主要是由<span style=\"color:red\">动力学</span>确定的。","authors":[{"authorName":"陈志明","id":"c321342e-ecf0-4a0f-a253-704c15e3d9d4","originalAuthorName":"陈志明"},{"authorName":"邵利","id":"147629b8-bb05-40ac-aed5-521861a8c98a","originalAuthorName":"邵利"},{"authorName":"马全红","id":"73657239-28af-4d3e-9946-868eabcb2df4","originalAuthorName":"马全红"}],"doi":"","fpage":"75","id":"7826c51b-e5f5-4096-ad84-c2c5b4cb7268","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"d72fe416-c5bc-4808-8009-5e0479732720","keyword":"核壳乳液<span style=\"color:red\">聚合</span>","originalKeyword":"核壳乳液聚合"},{"id":"b300fc10-1b4e-4e22-8ffa-6ccc0c10665f","keyword":"甲基丙烯酸","originalKeyword":"甲基丙烯酸"},{"id":"490b845b-0fb9-4a5e-90ba-850942beb245","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"},{"id":"59a186e7-cfc6-4b43-91e1-0084cfd1b218","keyword":"羧基分布","originalKeyword":"羧基分布"}],"language":"zh","publisherId":"gfzclkxygc200103019","title":"MAA存在下VAc／BA核壳乳液<span style=\"color:red\">聚合动力学</span>研究","volume":"17","year":"2001"},{"abstractinfo":"用十二烷基硫酸钠(SDS)为乳化荆,十六醇(CA)为难溶助荆,以偶氮二异丁腈(AIBN)引发醋酸乙烯酯(VAC)进行细乳液<span style=\"color:red\">聚合</span>.在<span style=\"color:red\">聚合</span>体系中预先引入了<span style=\"color:red\">聚合</span>物,研究了<span style=\"color:red\">聚合</span>物、温度、引发剂浓度对细乳液转化率的影响,得出<span style=\"color:red\">聚合</span>物的引入可以显著加快<span style=\"color:red\">聚合</span>反应速率,<span style=\"color:red\">聚合</span>物用量宜控制在单体用量的2%,反应的表观活化能为38.6 kJ/mol,<span style=\"color:red\">聚合</span>速率与引发剂浓度的0.24次方成正比.","authors":[{"authorName":"乔晋忠","id":"ac397bd7-66c6-4993-8929-be5358839026","originalAuthorName":"乔晋忠"},{"authorName":"王通","id":"cb99f969-419f-4649-8e0d-88b91ab0f7e7","originalAuthorName":"王通"},{"authorName":"詹茂盛","id":"35c47ca0-26bd-40be-86c3-aed9123ba331","originalAuthorName":"詹茂盛"}],"doi":"","fpage":"13","id":"c4e537e5-0999-4d5d-9605-5c03fd618015","issue":"11","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"60b232c6-a207-4f88-8c0f-fae862254eef","keyword":"细乳液","originalKeyword":"细乳液"},{"id":"6587acda-7b6a-4a67-977f-d957ad4937de","keyword":"醋酸乙烯","originalKeyword":"醋酸乙烯"},{"id":"e439e4a8-7c9d-4f8c-b30b-0dbce83a4bf2","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"}],"language":"zh","publisherId":"gfzclkxygc200911004","title":"醋酸乙烯细乳液<span style=\"color:red\">聚合动力学</span>","volume":"25","year":"2009"},{"abstractinfo":"以2,2'-偶氮(2-脒基丙烷)二氢氯化物(V-50)为光敏引发剂,丙烯酰胺为原料,采用毛细管膨胀计法,研究了丙烯 酰胺水溶液<span style=\"color:red\">聚合动力学</span>规律;在紫外光照射下探讨了单体浓度、光敏引发剂浓度、反应温度对光敏引发丙烯酰胺(AM)<span style=\"color:red\">聚合</span>反应速率的影响.结果表明,<span style=\"color:red\">聚合</span>反应的表观活化能为21.21 kJ/mol,反应表观速率常数表达式为k=2.688×103exp(-21.21/RT),光敏引发AM<span style=\"color:red\">聚合</span>速率的<span style=\"color:red\">动力学</span>方程式表示为Rp=k[AM]1.088[I]0.4989,通过实验验证了该<span style=\"color:red\">动力学</span>关系式.","authors":[{"authorName":"李万捷","id":"c04c732c-d1b8-4260-9e46-6406688463a8","originalAuthorName":"李万捷"},{"authorName":"李春","id":"f9459a13-1f9c-476e-bcd6-89b2c13d3fa1","originalAuthorName":"李春"},{"authorName":"陈庆柏","id":"69d70d81-9089-4a12-b877-5b5653f1610c","originalAuthorName":"陈庆柏"}],"doi":"","fpage":"5","id":"4e461312-940e-4dcb-ac75-91723f61ab16","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"c34c3372-2848-4625-a492-448fe6912736","keyword":"膨胀计","originalKeyword":"膨胀计"},{"id":"96d747c5-62c5-4f6c-bf56-ac1e006b9ee7","keyword":"光敏引发<span style=\"color:red\">聚合</span>","originalKeyword":"光敏引发聚合"},{"id":"e6d3c39e-309a-4530-b037-7b9410298701","keyword":"丙烯酰胺","originalKeyword":"丙烯酰胺"},{"id":"6d51ffe6-b973-40c2-845a-5c67ad2da747","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"}],"language":"zh","publisherId":"gfzclkxygc201104002","title":"紫外光照射下光敏引发丙烯酰胺<span style=\"color:red\">聚合动力学</span>","volume":"27","year":"2011"},{"abstractinfo":"非病毒基因载体聚乙烯亚胺结构不可控,同时最优结构未知,因此文中采用Core-First的方法,以三氟甲磺酸酯作为引发剂,通过2-乙基-2-恶唑啉阳离子开环<span style=\"color:red\">聚合</span>合成了二臂、四臂、六臂和八臂星形聚乙烯亚胺.利用核磁共振氢谱、凝胶渗透色谱仪对合成的星形<span style=\"color:red\">聚合</span>物的结构、相对分子质量及其分布进行了表征,并对2-乙基-2-恶唑啉的开环<span style=\"color:red\">聚合动力学</span>进行了研究.结果表明,合成得到了结构明确、窄分散的多臂星形聚乙烯亚胺,且该<span style=\"color:red\">聚合</span>反应符合活性<span style=\"color:red\">聚合</span>的特征.","authors":[{"authorName":"何宁","id":"79a95b8a-778b-4f5f-8ab1-64213c77d010","originalAuthorName":"何宁"},{"authorName":"孙贺春","id":"14856cd4-2f4d-4099-9aad-586d7cc10fef","originalAuthorName":"孙贺春"},{"authorName":"董晓曼","id":"edd7db6b-0a36-43ec-b0b9-2aaf9d1e9f88","originalAuthorName":"董晓曼"},{"authorName":"徐欢喜","id":"27b454ab-fb50-4c98-8527-09cea5b60c94","originalAuthorName":"徐欢喜"}],"doi":"","fpage":"35","id":"7b2e5063-320f-4685-bee1-f8190d4e57f4","issue":"7","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4b6cf6b6-d9e1-4c80-8158-68bb9901e00a","keyword":"非病毒基因载体","originalKeyword":"非病毒基因载体"},{"id":"ab9ac884-6928-46ee-b092-7013cba48687","keyword":"聚乙烯亚胺","originalKeyword":"聚乙烯亚胺"},{"id":"31b2c6cd-bac3-493b-83e1-9ba0a9731ce3","keyword":"三氟甲磺酸酯","originalKeyword":"三氟甲磺酸酯"},{"id":"51b8f6c4-7ea0-4bc8-b72c-b8293dacfde6","keyword":"<span style=\"color:red\">聚合动力学</span>","originalKeyword":"聚合动力学"},{"id":"a546cf50-b5f8-4fd9-ac3c-ee84862780f7","keyword":"2-乙基-2-恶唑啉","originalKeyword":"2-乙基-2-恶唑啉"}],"language":"zh","publisherId":"gfzclkxygc201407008","title":"多臂星形聚乙烯亚胺的设计合成及<span style=\"color:red\">聚合动力学</span>","volume":"30","year":"2014"},{"abstractinfo":"以末端含溴原子的<span style=\"color:red\">光</span>引发剂2溴异丁酰氧基-2-甲基-1-苯基甲酮(HMPP-Br)为引发剂,2,2,6,6四甲基哌啶-1-氧自由基(TEMPO)和2,2,6,6-四甲基哌啶醇(TMP)为调控剂,采用光<span style=\"color:red\">聚合</span>方法研究了甲基丙烯酸正丁酯(n-BMA)/十二烷基硫酸钠(SDS)/水/正丁醇O/W型正相微乳液体系的<span style=\"color:red\">光</span><span style=\"color:red\">聚合</span>反应<span style=\"color:red\">动力学</span>.结果表明,改性后的引发剂具有一定的引发活性,且<span style=\"color:red\">聚合</span>微乳液体系较稳定,<span style=\"color:red\">聚合</span>反应获得了良好的ln[M]o/[M]与时间、数均分子量与转化率之间的线性<span style=\"color:red\">动力学</span>关系,制备了分子量分布较窄的Poly(n-BMA)均聚物.","authors":[{"authorName":"张永涛","id":"32950107-3e99-4d23-9b17-e242a04c2d89","originalAuthorName":"张永涛"},{"authorName":"姚永平","id":"599c520d-0cef-482f-8809-4a69216986de","originalAuthorName":"姚永平"},{"authorName":"崔艳艳","id":"36265040-3948-4a1d-ab18-96430fe604dc","originalAuthorName":"崔艳艳"},{"authorName":"董智贤","id":"d1157760-d209-414b-905e-4dbf577bf5e4","originalAuthorName":"董智贤"},{"authorName":"刘晓暄","id":"6a1570eb-f82c-4f4d-8c84-5663bec7d4b6","originalAuthorName":"刘晓暄"}],"doi":"","fpage":"438","id":"0e86228e-51ff-4eb3-9d7e-81594f18b554","issue":"6","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"65cacbe8-f7b9-4775-8762-f47b0ca72163","keyword":"甲基丙烯酸正丁酯","originalKeyword":"甲基丙烯酸正丁酯"},{"id":"433ea906-f096-4edb-82c4-5d6448153d77","keyword":"可控/活性<span style=\"color:red\">光</span><span style=\"color:red\">聚合</span>","originalKeyword":"可控/活性光聚合"},{"id":"e1a9371f-a42d-4280-a5f8-5f1553627689","keyword":"2,2,6,6-四甲基哌啶-1-氧自由基","originalKeyword":"2,2,6,6-四甲基哌啶-1-氧自由基"},{"id":"875111a8-0323-4f97-9f8b-38ec682e08bd","keyword":"2,2,6,6-四甲基哌啶醇","originalKeyword":"2,2,6,6-四甲基哌啶醇"},{"id":"cdbcf56e-01b0-4298-af4c-aee654c00cb6","keyword":"正相微乳液","originalKeyword":"正相微乳液"},{"id":"698063b9-b334-461b-bfed-d5fe8e5992d4","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"}],"language":"zh","publisherId":"ggkxyghx201206005","title":"甲基丙烯酸正丁酯正相微乳液可控/“活性”<span style=\"color:red\">光</span><span style=\"color:red\">聚合动力学</span>研究","volume":"30","year":"2012"}],"totalpage":4402,"totalrecord":44012}