材料期刊网

ASTUDY OF VALENCE OF YTTRIUM IN Y_2O_3 Mo CATHODE

J.S.Wang1 , 2) , M.L.Zhou2) , J.X.Zhang2) , Z.R.Nie2) T.Y.Zuo2) and G.J.Zhang2) 1) State Key Laboratory of Materials Chemistry and Applications , Peking University , Beijing 100871 , China2) Schoolof Materials Science and Engineering , Beijing Polytechnic University , Beijing 100022 , China

金属学报(英文版)

The valenceofelementyttrium of Y2 O3 Mocathode materialhasbeenstudied by usingther mal weight analysis, X ray diffraction analysis, Scanning electron microscopy and X rayphotoelectronspectrum . It hasbeen provedthatyttrium oxidecan bereduced by molybdenum carbide. Thereaction between powdered Y2 O3 and Mo2 Ccan happen at 1173 , and Y2 O3may bereduced to metallicyttrium . Afterthepowder mixtureof Y2 O3 and Mo2 Cwasheat treated at1873 K, Yttrium existsin two kinds of chemicalstate- yttrium of zero valence and yttrium ofthreevalences.

关键词: valence , null , null , null

FeMoB Enhanced Sintering of P/M 316L Stainless Steel

YANG Xia , GUO Shiju

钢铁研究学报(英文版)

Liquidphase enhanced sintering of powder metallurgy (P/M) 316L stainless steel by addition of sintering aids was studied. 2%-8% of prealloyed FeMoB powder with two different particle sizes was added as sintering aids, and the specimens were sintered in vacuum at 1 200-1 350 ℃. The results show that the fine FeMoB powder (5-10 μm) has stronger activated effect. The sintered density increases with the increase in sintering aid content or sintering temperature. Warm compaction has a better effect on the control of dimensional precision of compacts. The prealloyed FeMoB powder deviated from Mo2FeB2 component can also be sintering aid of P/M 316L stainless steel.

关键词: P/M 316L stainless steel;liquidphase sintering;activated sintering;FeMoB;sintering aid

试棒的w_0/l_0值对Zn-5%Al合金超塑性m-δ关系的影响

刘勤 , 裔式珙

材料研究学报

在250℃以■=0.025min~(-1)测到的Zn-5%Al 合金的超塑性m-δ曲线均属式。w_0/l_0值加大使m_0,m_L 和δ_F 值增大,但对δ_L 和m_F 值无大影响。试样厚度的加大(由1增大到2mm)仅使δ_L 和δ_F 值增大,考虑w_0/l_0比值的影响,C_3~((m_0-m_L))-(m_L=m_(mas))型C.L.m-δ方程式规划为:或其中,m′_0(W_0/l_0)=m_0,m′_0>m_0;m′_L(w_0/l_0)=m_L,m′_L>m。w_0/l_0=0.15—0.39。当w_O/l_0=1时,缺口效应消失,δ(或δ_F)值为最大。

关键词: Zn-5%Al合金 , mechanics of superplasticity , C.L.m-δequation

Ni64Al21V15沉淀过程DO22向L10(M=1)结构转变的微观相场模拟

常秀丽 , 王永欣 , 陈铮 , 张静 , 程立维

稀有金属材料与工程

基于微观相场模型,研究了Ni64Al21V15合金在1150 K时效过程中相结构演化.结合微观组织演化图像和各个格点上原子占位几率的演化,分析了DO22结构向L10 (M=1)结构转变机制.合金沉淀中期,在相界处析出L10(M=1)结构.研究发现,L10 (M=1)结构形成可分为3类:在DO22与L12相界处形核,沿[001]方向排列,向DO22相扩张;在DO22结构90°有序畴界处形核,沿[001]方向排列,向DO22扩张;在2个[100]向排列的DO22结构交界处形核,沿[100]方向排列,向DO22结构扩张.DO22相中,V主要占据β位,Ni主要占据α2和α3位,Al主要占据α1位;随后,V向α2位跃迁,在(002)面富聚且发生有序化,逐渐占据β和α2位,Ni原子发生面间跃迁,由α2位跃迁至α1位,逐渐占据α1和α3位,Al原子向相外扩散.DO22结构最终转变为高度有序的L10(M=1)结构.

关键词: 结构转变 , L10(M=1)结构 , 序参数 , Ni-Al-V合金 , 微观相场

M/HgI2接触特性分析

许岗 , 李高宏 , 介万奇 , 查刚强

材料导报

利用不同的电极材料和制备方法制备了3种M/HgI2.采用热电子发射模型计算了相应的接触势垒.采用比接触电阻法、电极系数法和欧姆系数法对比了M/HgI2的欧姆接触特性.结果表明,C/HgI2、AuCl3/HgI2和Au/HgI2的接触势垒均约为0.9eV;C/HgI2和AuCl3/HgI2具有良好的欧姆特性,Au/HgI2的欧姆特性相对较差.分析认为,HgI2晶体表面费米能级的钉扎导致了相近的接触势垒.但由于电极制备工艺没有显著影响AuCl3/HgI2和C/HgI2晶体表面质量,因而具有良好的欧姆接触特性.由于溅射Au电极在制备工艺中的温度升高和真空度造成Au/HgI2晶体表面质量下降,因此其欧姆接触特性较差.

关键词: 碘化汞 , 电极 , 接触势垒 , 费米能级 , 钉扎 , 表面质量 , 欧姆特性

Synthesis and Characterization of Some Transition Metal Chelates of 5-(1-Hydroxy-6-Naphthylazo-3-Sodium Sulphonate) Thiobarbituric (L1) and Barbituric (L2) Acids

Nabil S. Youssef , K.H.Hegab

材料科学技术（英文）

Some transition metal chelates of two ligands L1 and L2 were prepared and characterized by elemental analysis. The IR and 1H NMR spectra of several chelates of two ligands L1 and L2 showed the involvement of the azo group in chelation with the transition metal ions, in most of the studied chelates, and that the two ligands L1 and L2 showed the involvement of the azo group in chelation with the transition metal ions, in most of the studied chelates, and that the two ligands L1 and L2 were coordinated either in the enol or the keto form. IR spetra also showed that Fe(III)-, Ni(II)-, Mn(II)-, VO(II)-L1 and Cu(II)-L2 chelates behaved in a bidentate manner, in contrast with the two (1:1) M:L cobalt chelates with the two ligands are tridentate. TG analysis indicated the presence of three to twelve water molecules of hydration eliminated on heating up to 150°C and one or two coordinated water molecules removed at 150-180°C. The octahedral structure is proposed for all the chelates, except Cu(II)-L2 and Ni(II)-L1 chelates which have square planar geometry, based on their electronic spectra.

关键词:

Stable M(2)AlC(0001) surfaces (M = Ti, V and Cr) by first-principles investigation

Journal of Physics-Condensed Matter

We investigated the stable (0001) surfaces of M(2)AlC (M = Ti, V and Cr) using the first-principles plane-wave pseudopotential total energy method. Four possible (0001) terminations were considered by breaking the M-Al and M-C bonds. The corresponding surface energies were calculated and compared. The Al-and M(C)-terminated (0001) surfaces demonstrated better stability than the C- and M(Al)-terminated surfaces by their much lower surface energies. In addition, the stability of surfaces was predicted under various chemical environments as a function of chemical potentials. We further investigated the character of surface relaxations. The electronic structures of the stable Al- and M(C)-terminated surfaces were analyzed.

关键词: ab-initio calculations;ti3sic2 thin-films;electronic-structure;elastic stiffness;al;deposition;cr2alc;simulation;adhesion;solids

异材焊接件A508/52M/316L在高温水环境中的应力腐蚀破裂

李光福李冠军方可伟彭君杨武张茂龙孙志远

金属学报 doi:10.3724/SP.J.1037.2011.00316

采用慢应变速率实验(SSRT)方法, 研究了先进的异材焊接件A508/52M/316L在模拟压水堆一回路290 ℃高温水环境中的应力腐蚀破裂(SCC)特性. 实验在-780 mV至+200 mV范围的电位下进行, 模拟一回路水化学从低O含H的理想低电位状态到溶解O$_{2}$明显超标的高电位状态的服役环境. 该焊接件显微组织和化学成分分布较复杂, 显著的变化发生在A508/52M和52M/316L 2个界面附近. 在SSRT拉伸试样的典型位置处加工了同样尺寸的尖锐缺口, 以模拟应力集中和加速实验, 并比较这些典型位置的SCC 敏感性. 结果表明, 当电位位于-780 mV至-300 mV范围时, SSRT试样总是以韧性断裂形式在镍基合金焊缝中部发生断裂. 当电位升到-200 mV至+200 mV范围时, 试样发生显著的SCC脆断, A508/52M界面区周围是该焊接件最脆弱的部位, 在该界面和附近的A508热影响区发生穿晶应力腐蚀破裂(TGSCC), 在紧邻界面的镍基合金焊缝薄层发生沿晶应力腐蚀破裂(IGSCC). 讨论了破裂机理和实验结果的工程意义.

关键词: 压水堆核电站 , primary water , dissimilar metal weld , stress corrosion cracking , electrode potential , water chemistry

异材焊接件A508/52M/316L在高温水环境中的应力腐蚀破裂

李光福 , 李冠军 , 方可伟 , 彭君 , 杨武 , 张茂龙 , 孙志远

金属学报 doi:10.3724/SP.J.1037.2011.00316

采用慢应变速率实验(SSRT)方法,研究了先进的异材焊接件A508/52M/316L在模拟H压水堆一回路290℃高温水环境中的应力腐蚀破裂(SCC)特性.实验在-780 mV至+200 mV范围的电位下进行,模拟一回路水化学从低O含H的理想低电位状态到溶解O2明显超标的高电位状态的服役环境.该焊接件显微组织和化学成分分布较复杂,显著的变化发生在A508/52M和52M/316L 2个界面附近.在SSRT拉伸试样的典型位置处加工了同样尺寸的尖锐缺口,以模拟应力集中和加速实验,并比较这些典型位置的SCC敏感性.结果表明,当电位位于-780mV至-300mV范围时,SSRT试样总是以韧性断裂形式在镍基合金焊缝中部发生断裂.当电位升到-200mV至+200 mV范围时,试样发生显著的SCC脆断,A508/52M界面区周围是该焊接件最脆弱的部位,在该界面和附近的A508热影响区发生穿晶应力腐蚀破裂(TGSCC),在紧邻界面的镍基合金焊缝薄层发生沿晶应力腐蚀破裂(IGSCC).讨论了破裂机理和实验结果的工程意义.

关键词: 压水堆核电站 , 一回路水环境 , 异材焊接件 , 应力腐蚀破裂 , 电位 , 水化学

316L纤维尺寸和含量对HA-ZrO₂(CaO)/316L纤维复合生物材料性能的影响

邹俭鹏 , 阮建明 , 周忠诚 , 黄伯云 , 陈启元

无机材料学报 doi:10.3724/SP.J.1077.2007.01001

研究了316L纤维的长度、直径与含量对HA-ZrO₂(CaO)/316L纤维生物复合材料的力学性能的影响规律. 结果表明: 纤维直径为40μm的复合材料力学性能优于纤维直径为50μm的复合材料; 纤维长度为0.8～1.2mm的复合材料力学性能优于纤维长度为2～3mm的复合材料; 随着纤维体积分数增大, 纤维之间相互接触而导致在复合材料中形成的微孔增多, 并成为微裂纹源, 导致材料力学性能下降. 含20vol%直径为40μm、长度为0.8～1.2mm的316L纤维的HA-ZrO₂(CaO)/316L纤维生物复合材料的综合力学性能最佳, 其抗弯强度、杨氏模量、断裂韧性和相对密度分别为140.1MPa、117.8GPa、5.81MPa·m ^1/2和87.1%. 复合材料微观组织随HA粉末和316L纤维成分的变化呈规律性变化, 没有出现明显的裂纹或孔隙, 316L纤维与HA-ZrO₂(CaO)基体紧紧地咬合在一起, 其结合主要靠基体对316L纤维的物理附着力所致. 基体中发生微量Fe元素扩散, 但在316L纤维中不发生基体Ca、P元素的扩散. 含5%316L纤维复合材料表现为脆性断裂, 而含10%、20%、40%316L纤维复合材料均表现为韧性断裂, 且韧性程度随316L纤维含量的增加而增大.

关键词: 316L不锈钢纤维(316L纤维) , biomaterials , microstructure , mechanical properties , fracture properties