Lei Miao
,
Sakae Tanemura
,
Thi Hue Nguyen
,
Li Luo
,
Masaki Tanemura
,
Shoichi Toh
,
Kenji Kaneko
,
Masahiro Kawasaki
材料科学技术（英）
An alternative sol-gel method has been applied to fabricate anatase and rutile TiO2 coatings uniformly on Al scale fibers with very thin naturally oxidized layer from mixed precursors of Ti tetraisopropoxide, acetyl acetone, deionizer water and ethanol in different molar ratios. The crystal structure of TiO2 coatings on Al scale fiber was confirmed by both XRD and TEM. The surface morphology of the coatings was observed by SEM and the chemical composition of the grown TiO2 was analyzed by EDS in TEM. Anatase coating, having a fine crystalline structure, was grown at 450℃ while rutile was being done at 670℃. The TEM results indicated that the fabricated TiO2 coatings consisted of anatase/rutile polycrystalline structures. The optimal fabrication conditions for TiO2 coatings with about 400 nm in thickness on Al scale fibers were established through the characterization results.
关键词:
Sol-gel method
,
null
,
null
,
null
,
null
Lei Miao
,
Sakae Tanemura
,
Shoichi Toh
,
Kenji Kaneko
,
Masaki Tanemura
材料科学技术（英）
The controlled growth of densely assembled single-phase rutile-TiO2 nanorods was demonstrated by a heating-sol-gel template process with about $\sim$300~nm in diameter and several micrometers in length. Transmission electron microscopic observation reveals these rutile-TiO2 nanorods are the aggregates of many nanocrystallites grown preferentially to the [110] zone axis direction with about 10~30 nm in diameter. The calculation and comparison of d-spacing values with those of bulk values suggest the crystal structure of nanorods close to bulk materials. Selected area electron diffraction and energy dispersive X-ray spectroscopy measurements confirm that the obtained nanorods are rutile-TiO2 nanorods with good compositional uniformity and consist of distinct shape of nanocrystallites with 10～30 nm diameter.
关键词:
Rutile-TiO2
,
null
,
null
,
null
,
null
邹俭鹏
,
阮建明
,
黄伯云
,
周忠诚
材料研究学报
doi:10.3321/j.issn:1005-3093.2005.03.007
制备了HA(ZrO2)/316L不锈钢纤维对称功能梯度材料(FGM),316L不锈钢纤维的含量(体积分数)按20%→10%→0→10%→20%呈轴向对称梯度变化.分析了材料的微观结构和微区元素含量,研究了材料的性能与316L不锈钢纤维含量的关系.结果表明,在HA(ZrO2)/316L不锈钢纤维对称FGM中,316L不锈钢纤维在微观上呈无序和均匀分布状态,它被包裹于HA(ZrO2)基体中,两者紧密结合.316L不锈钢纤维与HA(ZrO2)基体间的界面表现为部分凹凸不平,紧紧地咬合在一起.在FGM基体中发生了微量的韧化相Fe元素扩散,在韧化相316L不锈钢纤维不发生基体相Ca、P元素的扩散,基体与韧化相之间不发生化学反应.随着316L不锈钢纤维含量的增加,HA(ZrO2)/316L不锈钢纤维复合材料的断裂韧性和弹性模量逐渐增加,体现了FGM中各梯度层的力学性能缓和设计.按Miao模型计算HA(ZrO2)/316L不锈钢纤维FGM中的残余热应力为515 MPa,FGM的增韧机理主要为纤维的拔出增韧和层间的裂纹偏转增韧.
关键词:
复合材料
,
功能梯度材料
,
生物材料
,
羟基磷灰石
,
316L不锈钢纤维
,
热等静压
