ZHENG Yunrong RUAN Zhongci Institute of Aeronautical Materials
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Beijing
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China ZHENG Yunrong
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Senior Engineer
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Laboratory No.4 Institute of Aeronautical Materials
金属学报(英文版)
In consideration of the envelopment of γ dendrites by the Hf-rich melts at the late period of solidification of the cast Ni-base superalloys containing Hf,a heat of brazing filler alloy composed of Ni-18.6Co-4.5Cr-4.7 W-25.6Hf(wt-%)was prepared.This alloy is hypereutectic.γ phase is the leading phase in eutectic γ+Ni_5Hf and γ bars are surrounded by Ni_5Hf phase.At the section perpendicular or parallel to the γ growing direction,the eutectic morphology is cellular or laminar respectively.The content of Ni_5Hf in the alloy is 68.7v.-%. The compositions of primary and eutectic Ni_5Hf are very similar.Ni,Co and Hf are the main elements and solubility of Cr and W in Ni_5Hf is very low.This alloy is an ideal brazing filler suitable to the directional or single crystal superalloy,and the elements are beneficial to superalloys properties.This filler alloy is of low melting point and of good fluidity.After braz- ing at 1240℃,5 min+1190℃,I h in 10~(-3) Pa vacuum,the microstructure of bond is the same as that of Hf-bearing superalloy.No Si and B contamination is involved.
关键词:
Ni-Hf brazing alloy
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null
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null
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Xingzhong ZHAO
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Jiajun LIU and Baoliang ZHU (Tsinghua University
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Beiing 100084
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China)Cuiyuen WANG (Zhengzhou Research Institute of Mechanical Engineering
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Zhengzhou 450002
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China)
材料科学技术（英文）
The antiwear properties of two wheel/rail lubricating oils were tested and compared on an Amsler machine. Under same testing conditions, oil A (developed by authors) showed much better wear resistance and higher load-carrying capacity than oil B (imported from abroad). The X-ray diffraction (XRD) analyses of the worn surfaces showed that different extreme pressure (EP) lubricating films were formed on the surfaces when the rollers were lubricated with different oils under boundary Iubrication condition. The EP film of oil A was a composite film containing three compounds, FeO, FeSx and FeP, while oil B formed only a simple EP film of FePO4. The composite EP film showed lower shear strength and better antiwear property than the simple EP film,which brought about different wear resistance of the two wheel/rail lubricating oils.
关键词:
Corrosion Science
The early stages of the evolution of atmospheric corrosion of carbon steels exposed in both a laboratory simulated and a natural atmosphere environment in Shenyang have been observed by in situ scanning electron microscopy. In the case of laboratory cyclic wet-dry tests, even though the chloride content level is very low, filiform corrosion is initiated in the early stage. The filiform corrosion grows in random directions, forming a network of ridges. White nodules nucleate and grow on the ridges during continued corrosion and eventually connect with each other to form the initial corrosion scale. Pits were also found on the surface beneath corrosion products. In the case of a natural atmospheric environment, both filiform corrosion and other localized corrosion, such as pitting and inter-granular attack take place in the initial stage. It is obvious that there is variety of localized corrosion in the initial stage of atmospheric corrosion. (C) 2007 Elsevier Ltd. All rights reserved.
关键词:
steel;atmospheric corrosion;initial stage;localized corrosion;in-situ;iron;electrolyte;thickness
Mustafa BOZ
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Adem KURT
材料科学技术（英文）
Friction-wear properties of the ZrSiO4 reinforced samples were measured and compared with those of plain bronze based ones. For this purpose, density, hardness, friction coefficient wear behaviour of the samples were tested. Microstructures of samples before and after sintering and worn surfaces were also investigated by scanning electron microscopy (SEM), and the wear types were determined. The optimum friction-wear behaviour was obtained in the sample compacted at 500 MPa and sintered at 820oC. Density of the final samples decreased with increasing the amount of reinforcing elements (ZrSiO4) before pre-sintering. However after sintering, there is no change in density of the samples including reinforcing elements (ZrSiO4). With increasing friction surface temperature, a reduction in the friction coefficient of the samples was observed. However, the highest reductions in the friction coefficients were observed in the as-received samples containing 0, 5% reinforced ZrSiO4. The SEM images of the sample indicated that while bronze-based break lining material without ZrSiO4showed abrasive wear behaviour, increasing the amount of ZrSiO4resulted a change in abrasive to adhesive wear mechanism. All samples exhibited friction-wear values, which were within the values shown in SAE-J661 standard. With increasing the amount of reinforcing ZrSiO4, wear resistance of the samples was increased. However samples reinforced with 5% and 6% ZrSiO4showed the best results.
关键词:
Friction materials
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null
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International Journal of Electronics
Fe3O4-polyaniline composites have been prepared in which the concentrations of Fe3O4 are 10%, 15%, 20%, 30% and 40% by weight. Microwave chiral composites are then prepared employing copper helices as chiral inclusions and the Fe3O4-polyaniline composites as the matrix. The electromagnetic parameters of the chiral Fe3O4-polyaniline composites are measured using a circular waveguide method at 9.5 GHz, and the normal reflectance from a perfect conductor-backed chiral slab is calculated. The microwave absorption characteristics of the chiral Fe3O4-polyaniline composites are studied and compared with those of a non-chiral Fe3O4-polyaniline composite matrix. The results show that the addition of the chiral inclusions to the non-chiral matrix improves both the dielectric and the magnetic losses. As well as this improvement in losses, the chiral materials have higher microwave absorption. The optimal concentration of Fe3O4 in the matrix is about 15% to obtain the lowest reflectance of chiral Fe3O4-polyaniline composites.
关键词:
Junming LIU Zhiguo LIU Zhuangchun WU National Lab.of Solid State Microstructures
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Nanjing University
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Nanjing 210008
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China
材料科学技术（英文）
As a simulation of surface solidification of materials,quasi-two dimensional dendritic deposition of ammonium chloride(NH_4Cl)crystals from an aqueous solution film with free surface by vapourization was investigated by the in- situ observation technique.The depositing morphologies of NH_4Cl crystals are faceted and of growth laws differing from the three-dimensional case.Under low supersaturation,faceted dendrites formed,whereas the anisotropy in growth kinetics decreases with the increase of supersaturation.When vapourizing rate(supersaturation)is not very low, oscillations of growth rate.tip-radius and second arm spacing of the dendrites were observed.It is suggested that this dynamic phenomenon is attributed to the correlation between the convection-transfer effect induced by the surface tension gradient of solution film.and the driving force for deposition.
关键词:
surface deposition
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null
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Surface & Coatings Technology
Using a halide-activated pack-cementation method but at a temperature (600 degrees C) noticeably lower than normal, an eta-Fe(2)Al(5) coating and two delta-Ni(2)Al(3) coatings with and without dispersions of CeO(2) nanoparticles were developed respectively on a low-carbon steel and the steel pretreated with an electrodeposited film of Ni or Ni-CeO(2). The erosion-corrosion (E-C) performance of the three aluminide coatings during 100 h exposure at similar to 600 degrees C in a coal-firing laboratory-scale fluidized-bed combustor (FBC) was investigated, by mounting the aluminized samples onto a rig which maintained rotation for accelerating the relative impacting speed of flying solid particles (mainly SiO(2) bed materials). The eta-Fe(2)Al(5) and the CeO(2)-free delta-Ni(2)Al(3) coatings experienced an unacceptable recession rate. Compared to the two CeO(2)-free aluminide coatings, the CeO(2)-dispersed delta-Ni(2)Al(3) coating offered profoundly improved E-C resistance, because the latter coating was not only strengthened by the CeO(2) dispersion and grain refinement, it also could grow a more adherent alumina scale. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
Erosion-corrosion;CeO(2)-dispersion-strengthening;Aluminizing coating;Grain refinement;Hardening;Reactive element effect;oxidation resistance;reactive elements;alloy-steels;water-vapor;power-plant;nickel;combustion;mechanisms;additions;behavior
