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INFLUENCE OF GEOMETRICAL CONFIGURATION OFSUPERCONDUCTING MATERIAL ON GROWTH OF Nb_3 Sn

LUO Le HU Suhui Shanghai Institute of Metallurgy , Academia Sinica.Shanghai , China [Originally published in ACTA METALL SIN (CHINESE EDN) 24 (5) 1988 pp B340—B347 , received 4 August 1986 , in revised form 1 November 1986]

金属学报(英文版)

Boundary conditions constructed by two typical geometrical configurations related to the manufacturing methods of bronze process and tin-rich Nb tube method have been considered in a diffusion model in which the diffusion of Sn in CuSn matrix plays a major role is as- sumed.The dependence of thickness of Nb_3Sn layer on reaction time has been derived.It is shown that the growth rate of Nb_3Sn relates to the configuration of the superconductor,the geometrical parameters of Nb filaments and CuSn matrix.The theory is qualitatively con- sistent with the experimental results.

关键词: superconducting material Nb_3Sn , null , null , null

Effect of Doping and High-Temperature Annealing on the Structural and Electrical Properties of Zn1-XNiXO(0≤X≤0.15) Powders

Hakan Colak

材料科学技术(英文)

This paper reported the synthesis, crystal structure and electrical conductivity properties of Ni-doped ZnO powders (i.e. Zn1-XNiXObinary system, X=0, 0.0025, 0.005, 0.0075 and in the range 0.01≤X≤0.15). I-phase samples, which were indexed as single phase with a hexagonal (wurtzite) structure in the Zn1-XNiXObinary system, were determined by X-ray diffraction (XRD). The widest range of the I-phase was determined as 0≤X≤0.03 at 1200°C; above this range the mixed phase was observed. The impurity phase was determined as NiO when compared with standard XRD data, using the PDF program. We focused on single I-phase ZnO samples which were synthesized at 1200°C because of the widest range of solubility limit at this temperature. It was observed that the lattice parameters a and c of the I-phase decreased with Ni doping concentration. The morphology of the I-phase samples was analyzed with a scanning electron microscope. The electrical conductivity of the pure ZnO and single I-phase samples were studied by using the four-probe dc method at temperatures between 100 and 950°C in air atmosphere. The electrical conductivity values of pure ZnO and 3 mol% Ni-doped ZnO samples at 100°C were 2×10-6 and 4.8×10-6Ω-1?cm-1, and at 950°C they were 1.8 and 3.6Ω-1?cm-1, respectively. In other words, electrical conductivity increased with Ni doping concentration.

关键词: II-VI semiconductors

Application of Microwave Radiation to Extractive Metallurgy

LIU Chunpeng XU Yousheng HUA Yixin Kunming Institute of Technology , Kunming , 650093 , China.

材料科学技术(英文)

In applying the microwave radiation to extractive me- tallurgy,it is essential first of all to find the extent of microwave energy absorbed by various minerals experi- mentally.In this paper,more than 25 kinds of common useful minerals have been individually irradiated by a 500 W,2450 MHz microwave source in an enclosed quartz crucible to ascertain their heating temperature in a definite time.In addition,the reduction and cbloridization tests were also carried out on the titanomagnetite concentrate and pentlandite with microwave heating,respectively. These experiments indicate potential applications of util- izing microwave energy in extractive metallurgy.

关键词: microwave radiation , null , null , null

116HU聚酯亚胺无挥发浸渍树脂的性能及其在风电上的模拟结构试验

王君 , 邹家桂 , 陈政标 , 高建武 , 刘彦坤 , 张杰元 , 宋莎

绝缘材料

  为解决苯乙烯和甲基苯乙烯在VPI浸渍树脂应用于风力发电机中的不足,采用不饱和聚酯亚胺、引发剂和无挥发活性稀释剂研制出116HU聚酯亚胺无挥发浸渍树脂,并对其各项性能进行了研究。结果表明:116HU聚酯亚胺无挥发浸渍树脂的常规性能满足风力发电机的要求,其耐热等级可达H级。用该树脂浸渍的风电模拟线棒具有优异的介电性能、耐湿热交变和高低温循环冲击性能及耐盐雾性能等,能满足风力发电机在极端环境运行的要求。

关键词: 聚酯亚胺 , 无挥发 , VPI , 风力发电机 , 耐湿热 , 耐盐雾

Acoustic emission inspection of Portevin-Le Chatelier effect and deformation mechanisms of two Mg-Li-Al alloys

Journal of Materials Science

In this paper, Portevin-Le Chatelier (PLC) effect of LA41 magnesium alloy is reported. With increasing strain rate, both ultimate tensile stresses (sigma(b)) and 0.2% proof (sigma(0.2)) stresses increase, while serrations become less severe. Major acoustic emission (AE) peaks appear at the end of elastic region, and transform to burst type signals in the plastic range. In another alloy containing less Li (LA11), serrations are absent and major AE peak values are considerably lowered. Additionally, PLC effect disappears in LA41 after annealing. The role of twins is discussed in details. Actual causes for AE activity during deformation are also proposed.

关键词: tensile deformation;magnesium alloys;bands;az31

OXIDE METALLURGY-ITS PURPOSES AND PRACTICAL APPROACHES

Z. T. Ma and D. Janke(Institute of Iron and Steel Technology , Freiberg University of Mining and Technology , Germany)

金属学报(英文版)

Useder certain conditions, nonmctallic inclusions such as oxides, sulfides, nitrides and carbides are no longer harmful to sted service properties. With the new concept of oxide metallurgy, these properties can be improved by generating fine oxide inclusions which serve as heterogeneous nuclei for sulfide and fine ferrite[1-4]. A novel continuous casting (CC) process is expected to be created with the utilization of oxide metallurgy. This is also useful for the forthcoming technologies of direct rolling and near-net-shape casting. The main idea of oxide metallurgy consists of an alternative oxidation technology. It is based on steels treated by complex metals such as Ti, Zr, Ti-Zr alloys and rare earth metals. The selected deoxidants should follow the required conditions which are concluded in this paper.

关键词: oxide , null , null , null

Improvement of Ductility of Powder Metallurgy Titanium Alloys by Addition of Rare Earth Element

Yong LIU , Lifang CHEN , Weifeng WEI , Huiping TANG , Bin LIU

材料科学技术(英文)

Ti-4.5Al-6.0Mo-1.5Fe, Ti-6Al-1Mo-1Fe and Ti-6Al-4V alloys were prepared by blended elemental powder metallurgy (PM) process, and the effects of Nd on the microstructures and mechanical properties were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). It was found out that the addition of Nd increased the density of sintered titanium alloys slightly by a maximum increment of 1% because small amount of liquid phase occurred during sintering. The addition of Nd shows little effect on the improvement of tensile strength, while the elongation is significantly improved. For example, the elongation of Ti-4.5Al-6.0Mo-1.5Fe can be increased from 1% without addition of Nd to 13% at a Nd content of 1.2 wt pct.

关键词: Powder metallurgy titanium alloy , null , null , null

SYNTHESIS OF NANO-ZnO PARTICLES FOR ALUMINUM METALLURGY AS INERT ANODE MATERIAL

A.A.A. Saleh , Y. Fu , X.J. Zhai

金属学报(英文版)

Nano-ZnO particle was produced by evaporating zinc powders in air at air °ow-rate from 0.2 to 0.6m3/h. Nano-ZnO particles was formed by the oxidation of the evapo- rated zinc vapor. X-ray di®raction shows the powders to be ZnO with lattice parame- ters of a=0.3249nm and c=0.5205nm. The particle size is dependent upon the transit time from the source to the collection area. The size of particles was ranged between 81 to 103nm. The average density resulted was 4.865g/cm3. Normal ZnO and nano-ZnO were investigated to use them in aluminum metallurgy as an inert anode material. A certain amount of both oxides were molded subsequently inserted to the molten cryolite-aluminum oxide to investigate the corrosive behavior of both oxides. When the sintering temperature increased up to 1300±C, the weight loss ratio rose to 5.01%{7.33% and up to 7.67%{10.18% for nano-ZnO and normal ZnO, respectively. However, when the samples in the molten cryolite aluminum oxide were put for long time, the corrosive rate was found to be higher. It was found that the corrosive loss weight ratio of nano-ZnO anode was much lower than the normal one made from ordinary-ZnO providing that the nano-ZnO is more possible to be use inert anode material.

关键词: reactive evaporation method , null , null

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