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SOLVENT EXTRACTION OF LANTHANIDES IN AQUEOUS NITRITE MEDIA BY CYANEX 302

YUAN Meng , LUO Aiqing , WANG Chun , LI Deqian (Changchun Institute of Applied Chemistry , Chinese Academy of Sciences , Changchun. China Manuscript received 7 November , 1994)

金属学报(英文版)

Solvent extraction of trivalent lanthanides (except for Pm with Cyanex 302 [Bis (2,4,4-trimethylpentyl)monothiophosphinic acid] in heptane was studied at various aqueous pH values, extractant concentrations and different temperatures. Cyanex 302 shows pretty good behaviours on the extraction of lanthanides, especially when extracting heavy lanthanides. However,purified Cyanex 302 exhibits signi ficantly lower extractability to lanthanides than raw extractant. The roles ofdifferent components ofraw Cyanex 302 were discussed to understand the reason of good extractability of the raw extractant. The lanthanides extraction stoichiometry is discussed on the basis ofexperimental results, which can be expressed as follows:

关键词: : Bis(2 , null , null , null , null

两种气液两相流模型的应用和比较

杨立新 , 巴黎明 , 李星

工程热物理学报

本文应用MUSIG模型[1]和均一直径模型对某溶液堆台架模型堆芯内气液流动传热进行了数值模拟.在MUSIG模型中堆芯内离散相气泡被分为5组不同直径的气泡,用于分析堆芯内气泡的流动变化和大小分布,采用Luo and Svendsen[2]和Prince and Blanch[3]模型描述不同直径气泡组间的破裂和聚合.在均一直径模型中,堆芯内的气体被考虑为同一直径的组分,并且不考虑其破裂与聚合现象.计算得到采用两个模型的模拟结果并且对其进行了对比研究.结果显示应用MUSIG模型的计算结果与台架实验结果吻合更好.

关键词: MUSIG , 均一直径 , 两相流 , 溶液堆

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