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A Coupling Dynamic Model for Dissolution and Reduction of Chromium Ore in a Smelting Reduction Converter

LIU Yan , JIANG Mao-fa , XU Li-xian , WANG De-yong

钢铁研究学报(英文版)

For describing and resolving the process of chromium ore smelting reduction in a converter preferably, the coupling dynamic model was established based on the kinetic models of chromium ore dissolution and interfacial reducing reaction between the slag and metal. When 150 t stainless steel crude melts with chromium of 12% are produced in a smelting reduction converter with no initial chromium in metal at 1560 ℃, the results of the coupling dynamic model show that the mean reduction rate and injection rate of chromium ore are 0091 %·min-1 and 467 kg·min-1, respectively. The foundation of the coupling dynamic model provides a reference and basis on the constitution of rational processing route for a practical stainless steelmaking.

关键词: coupling dynamic model , smelting reduction , stainless steel crude melt , converter

复合材料层合壳体的三维本构方程

杨宜谦

玻璃钢/复合材料 doi:10.3969/j.issn.1003-0999.1999.04.002

本文推导出了复合材料层合壳体的三维本构方程,修正了Reddy和Liu论文中的错误.

关键词: 复合材料 , 壳体 , 三维本构方程

Cu-Zr/ZrN薄膜体系的电阻率和纳米压入研究

白宣羽 , 汪渊 , 徐可为

稀有金属材料与工程

采用磁控溅射方法在Si(111)基片上沉积Cu-Zr/ZrN薄膜体系作为扩散阻挡层.通过比较Cu-Zr/ZrN薄膜体系和三元非晶(Mo,Ta,W)-Si-N的电阻率,同时比较Cu-Zr/ZrN薄膜体系和Ta,YaN的硬度,说明作为扩散阻挡层的材料的选取,应从整体性能上考虑,而不能仅仅考虑热稳定性等单一指标.

关键词: 非晶 , 电阻率 , 纳米压入 , 硬度

聚醛/蒙脱土纳米复合材料非等温结晶动力学研究

徐卫兵 , 戈明亮 , 何平笙

应用化学 doi:10.3969/j.issn.1000-0518.2001.09.011

用熔融插层法制备聚甲醛/蒙脱土纳米复合材料,用X射线衍射研究聚甲醛及复合材料的微观结构,表明复合材料是纳米复合材料.用DSC法研究其非等温结晶行为,对所得数据分别用Jeziorny法、Ozawa法和Liu法进行处理.结果表明,Jeziorny法和Liu法处理非等温结晶过程比较理想.聚甲醛及聚甲醛/有机蒙脱土纳米复合材料的结晶活化能分别为334.6和196.9 kJ/mol,说明有机蒙脱土的加入,降低了聚甲醛的结晶活化能,且t1/z缩短,起到了异相成核的作用.

关键词: 聚甲醛 , 蒙脱土 , 纳米复合材料 , 非等温结晶动力学

聚丙烯/凹凸棒土纳米复合材料的非等温结晶动力学

王平华 , 徐国永

应用化学 doi:10.3969/j.issn.1000-0518.2004.08.007

用熔融复合法制备聚丙烯/凹凸棒土纳米复合材料,用DSC法研究其非等温结晶行为,对所得的数据分别用Jeziorny法、Ozawa法和Liu法进行处理.结果表明,Jeziorny法和Liu法处理非等温结晶过程比较理想.聚丙烯及聚丙烯/凹凸棒土纳米复合材料的结晶活化能分别为194.1和162.8 kJ/mol,表明凹凸棒土的加入,降低了聚丙烯的结晶活化能,且t1/2缩短,起到了异相成核作用.

关键词: 聚丙烯 , 凹凸棒土 , 纳米复合材料 , 非等温结晶动力学

Studies of the g factors and the local structure for Ni3+in LaAl0.9Ni0.1O3, La0.75Y0.25Al0.99Ni0.01O3 and YAl0.9Ni0.1O3

Radiation Effects and Defects in Solids

The electron paramagnetic resonance g factors and the local structure for Ni3+ in LaAl0.9Ni0.1O3 (LAN), La0.75Y0.25Al0.99Ni0.01O3 (LYAN) and YAl0.9Ni0.1O3 (YAN) are theoretically studied from the perturbation formulas of the g factors for a 3d7 ion of low spin (S = 1/2) in tetragonally elongated octahedra. In these formulas, the contributions to the g factors from the tetragonal distortion, characterized by the tetragonal field parameters Ds and Dt are taken into account. According to the calculations, the ligand octahedra around Ni3+ are suggested to suffer 2% relative elongation along the [001] (or C4) axis due to the Jahn-Teller effect.

关键词: defect structures;electron paramagnetic resonance;crystal-fields and;spin Hamiltonians;Ni3+;LaAlO3;LaYAlO3;YAlO3;atomic screening constants;optical-spectra;paramagnetic-resonance;superconducting tapes;lattice-distortions;superposition model;scf;functions;cr3+ ions;crystals;epr

非微扰QCD和核遮蔽效应对K因子的影响

智海素 , 侯召宇

原子核物理评论 doi:10.3969/j.issn.1007-4627.2006.01.002

考虑非微扰量子色动力学物理真空夸克凝聚效应,计算了碳核与碳核在质心系能量分别为630和200 GeV时碰撞Drell-Yan过程的K因子,以及加入核遮蔽因子后非微扰效应对K因子的影响,并把计算结果与没有考虑夸克凝聚非微扰效应的K值进行了对比.结果表明,非微扰效应和核遮蔽效应对K因子影响很小.

关键词: K因子 , Drell-Yan过程 , 夸克凝聚 , 非微扰量子色动力学 , 核遮蔽效应

Reply to Comments on "Interdiffusion in the beta phase region of the Ni-Al-Cr system"

Scripta Materialia

A recent comment on a previously published paper addressed the invalid explanation of the off diagonal interdiflusion coefficients of the beta-Ni(Al,Cr) phase in the Ni-Cr-Al system according to the symmetric property of the thermodynamic matrix. In this paper, the experimental data presented by Hou et al. was reanalyzed and the interdiffusion coefficient matrix was estimated again. The results of the analysis have been discussed in terms of a brief reply to the comments of Liu and Liang. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: Diffusion;Intermetallic compound;Ni-Cr-Al

PET-PEE/ATO纳米复合材料的非等温结晶动力学

邓超 , 邵玮 , 李春忠

高分子材料科学与工程

采用元机纳米锑掺杂二氧化锡(ATO)和有机聚醚酯(PEE)协同提高聚时苯二甲酸乙二酯(PET)的抗静电性能,合成了聚对苯二甲酸乙二酯-聚醚酯/锑掺杂二氧化锡纳米复合材料(PET-PEE/ATO).使用Czawa方程和Liu-Mo方程研究了PET-PEE/ATO纳米复合材料的非等温结晶过程.Ozawa方程研究发现,在非等温结晶过程中,PET、PET-PEE、PET/ATO、PET-PEE/ATO的成核性能依次提高.Liu-Mo方程发现,ATO和PEE的加入分别促进了异相成核作用和加快了结晶生长,PET-PEE/ATO结晶成核性能最好,结晶速率最快.

关键词: 聚对苯二甲酸乙二酯 , 有机聚醚酯 , 无机纳米锑掺杂二氧化锡 , 纳米复合材料 , 非等温结晶动力学

基于MacPherson-Srolovitz拓扑依赖速率方程的三维晶粒尺寸分布研究

王浩 , 刘国权

金属学报 doi:10.3321/j.issn:0412-1961.2008.07.001

以MacPherson-Srolovitz提出的三维个体晶粒长大拓扑依赖速率方程以及三维晶粒组织的晶粒尺寸-晶粒面数间的抛物线型统计关系为基础,导出了相应的描述三维准稳态晶粒尺寸分布的函数族.采用纯Fe实验数据以及顶点法、基元演化法.相场模型和Monte Carlo法进行了验证,结果表明,函数族中峰值左偏的函数适合三维准稳态晶粒尺寸分布的定量表述.将该函数与Liu等提出的2种三维准稳态晶粒尺寸分布函数进行的对比表明:此3种函数的解析表达形式有所不同,但其曲线图在一定条件下相互吻合.此外,MacPherson-Srolovitz三维拓扑依赖速率方程、Hillert三维速率方程及Yu-Liu三维速率方程尽管表达形式不同均能较好地反映三维正常晶粒长大的动力学规律.

关键词: 三维晶粒长大 , 准稳态晶粒尺寸分布 , 长大速率方程 , 计算机仿真

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